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Title
Molecular Main Group Metal Hydrides
Authors
Keywords
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Journal
CHEMICAL REVIEWS
Volume -, Issue -, Pages -
Publisher
American Chemical Society (ACS)
Online
2021-08-28
DOI
10.1021/acs.chemrev.1c00278
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- Neutral, Cationic and Hydride-substituted Siloxygermylenes
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- Matrix-Infrared Spectra and Structures of HM–SiH3 (M = Ge, Sn, Pb, Sb, Bi, Te Atoms)
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- Se–C Cleavage of Hexane Selenol at Steps on Au(111)
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- Synthesis and Structural Characterization of Tris(isopropylbenzimidazol-2-ylthio)methyl Zinc Complexes, [TitmPriBenz]ZnX: Modulation of Transannular Zn–C Interactions
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- Purification of tellurium through thermal decomposition of plasma prepared tellurium hydride
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- Cu 2 ZnSnSSe 4 solar cells with 9.6% efficiency via selenizing Cu-Zn-Sn-S precursor sputtered from a quaternary target
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- Syntheses and Structures of Ruthenium Complexes Containing a Ru-H-Tl Three-Center-Two-Electron Bond
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- Direct Synthesis of Six-Monolayer (1.9 nm) Thick Zinc-Blende CdSe Nanoplatelets Emitting at 585 nm
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- Reversible Coordination of Boron–, Aluminum–, Zinc–, Magnesium–, and Calcium–Hydrogen Bonds to Bent {CuL2} Fragments: Heavy σ Complexes of the Lightest Coinage Metal
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- Organosilicon Radicals with Si–H and Si–Me Bonds from Commodity Precursors
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- Low-Valent Lead Hydride and Its Extreme Low-Field 1H NMR Chemical Shift
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- A [HN(BH═NH)2]2– Dianion, Isoelectronic with a β-Diketiminate
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- Synthesis of picolinohydrazides and their evaluation as ligands in the zinc-catalyzed hydrosilylation of ketones
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- Hydride oxidation from a titanium–aluminum bimetallic complex: insertion, thermal and electrochemical reactivity
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- Reactivity of a coordinated inorganic acetylene unit, HBNH, and the azidoborane cation [HB(N3)]+
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- Uncovering active precursors in colloidal quantum dot synthesis
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- Triamidoamine thorium-arsenic complexes with parent arsenide, arsinidiide and arsenido structural motifs
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- Efficient Reduction of Carbon Dioxide to Methanol Equivalents Catalyzed by Two-Coordinate Amido–Germanium(II) and −Tin(II) Hydride Complexes
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- New Tricks for an Old Dog: Aluminum Compounds as Catalysts in Reduction Chemistry
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- Reaction of sterically encumbered phenols, TEMPO-H, and organocarbonyl insertion reactions with L-AlH2 (L = HC(MeCNDipp)2, Dipp = 2,6-diisopropylphenyl)
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- Sterically bulky amido magnesium methyl complexes: syntheses, structures and catalysis
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- Bond dissociation energy controlled σ-bond metathesis in alkaline-earth-metal hydride catalyzed dehydrocoupling of amines and boranes: a theoretical study
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- Dimeric magnesium(I) β-diketiminates: a new class of quasi-universal reducing agent
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- Hollow Cobalt Selenide Microspheres: Synthesis and Application as Anode Materials for Na-Ion Batteries
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- Potassium Hydroxide-Catalyzed Chemoselective Reduction of Cyclic Imides with Hydrosilanes: Synthesis of ω-Hydroxylactams and Lactams
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- Highly Selective Fluorescent Probe for Imaging H2Se in Living Cells and in Vivo Based on the Disulfide Bond
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- Isomerization of Cyclooctadiene to Cyclooctyne with a Zinc/Zirconium Heterobimetallic Complex
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- Tailored Cyclic and Linear Polycarbosilazanes by Barium-Catalyzed N−H/H−Si Dehydrocoupling Reactions
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- Metal-Free Activation of Hydrogen, Carbon Dioxide, and Ammonia by the Open-Shell Singlet Biradicaloid [P(μ-NTer)]2
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- Synthesis of 1, 6-Bis(trimethylsilylamino)benzene-Substituted Aluminum Hydrides: The Characterization of a Product from Ring-Opening Reaction of Tetrahydrofuran
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- Solution-Based Silicon in Thin-Film Solar Cells
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- Well-Defined, Nanometer-Sized LiH Cluster Compounds Stabilized by Pyrazolate Ligands
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- Activation of H2by a Multiply Bonded Amido-Digermyne: Evidence for the Formation of a Hydrido-Germylene
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- Bespoke synthesis of unsymmetrical diaminoboranes by alkaline earth catalysis
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- Catalytic Reduction of Graphene Oxide Nanosheets by Glutathione Peroxidase Mimetics Reveals a New Structural Motif in Graphene Oxide
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- Activation of Isocyanates and Carbon Dioxide by a Monomeric Aluminium Hydrazide as an Active Lewis Pair
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- Reactivity of Yttrium Carboxylates Toward Alkylaluminum Hydrides
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- Base-Catalyzed Hydrosilylation of Ketones and Esters and Insight into the Mechanism
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- Dinuclear Zinc Hydride Supported by an Anionic Bis(N-Heterocyclic Carbene) Ligand
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- Synthesis, characterization and reactivity of an imidazolin-2-iminato aluminium dihydride
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- N-Acyl- andN-Sulfonylformamidines from Cyanamides and Carbodiimides by Hydroalumination and Subsequent Treatment with Electrophiles
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- Cs10H[Ga3H8]3: A Hydrogenous Zintl phase Containing Propane-Like Polyanions [Ga3H8]3– and Interstitial Hydrogen
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- Synthesis and Mössbauer Spectroscopy of Formal Tin(II) Dichloride and Dihydride Species Supported by Lewis Acids and Bases
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- Dehydrocoupling of amine boranes via tin(IV) and tin(II) catalysts
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- Group-13 carbenoid ligands at tungsten: Coordination and C–H activation
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- Indium hydride catalyzed chemo- and diastereoselective reductive aldol reactions
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- A Dihydrodisilene Transition Metal Complex from an N-Heterocyclic Carbene-Stabilized Silylene Monohydride
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- Theoretical Study of Reactivity of Ge(II)-hydride Compound: Comparison with Rh(I)-Hydride Complex and Prediction of Full Catalytic Cycle by Ge(II)-hydride
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- Aluminum–Ligand Cooperative N–H Bond Activation and an Example of Dehydrogenative Coupling
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- Electron-Rich N-Heterocyclic Silylene (NHSi)–Iron Complexes: Synthesis, Structures, and Catalytic Ability of an Isolable Hydridosilylene–Iron Complex
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- Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials
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- Nickel-Catalyzed Cyclopolymerization of Hexyl- and Phenylsilanes
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- Versatile Reactivity of Bridged Pentelidene Complexes toward Secondary and Tertiary Phosphines
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- Aluminum–Amido-Mediated Heterolytic Addition of Water Affords an Alumoxane
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- Synthesis and Characterization of Primary Aluminum Parent Amides and Phosphides
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- Comparison of the Mechanism of Borane, Silane, and Beryllium Hydride Ring Insertion into N-Heterocyclic Carbene C–N Bonds: A Computational Study
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- Heavier Main Group Dimetallene Reactivity: Effects of Frontier Orbital Symmetry
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- Carbene-Bound Borane and Silane Adducts: A Comprehensive DFT Study on Their Stability and Propensity for Hydride-Mediated Ring Expansion
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- Stable Complexes of Parent Digermene: An Inorganic Analogue of Ethylene
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- Alkyl mercury compounds: an assessment of DFT methods
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- Molecular Structures of Dimeric and Trimeric Dineopentylaluminum Hydride and Trimeric Diphenylaluminum Hydride
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- Formation of a [4.3.0]-Bicyclic Aluminum-Phosphorus Compound with Annulated C3P2and Al2C2PH Heterocycles and a 3c-2e Al-H-Al Bond
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- Hydroalumination versus Deprotonation of Alkynes with Sterically Demanding Substituents
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- Coordination of N-Heterocyclic Carbene to H2SiX2 (X = Cl, OTf) and H3SiOTf (OTf = OSO2CF3): Synthesis of Donor-stabilized Parent Silylium Salts with Four- and Five-coordinate Silicon Atoms
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- Formation of sub-valent carbenoid ligands by metal-mediated dehydrogenation chemistry: coordination and activation of H2Ga{(NDippCMe)2CH}
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- Hetero-dehydrocoupling of silanes and amines by heavier alkaline earth catalysis
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- Germanium(iii) corrole complex: reactivity and mechanistic studies of visible-light promoted N–H bond activations
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- Magnesium-catalyzed hydroboration of esters: evidence for a new zwitterionic mechanism
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- Unexpected Role of Zinc Hydride in Catalytic Hydrosilylation of Ketones and Nitriles
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- Fundamental experimental and theoretical aspects of high-order Ge-hydride chemistry for versatile low-temperature Ge-based materials fabrication
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- Unusual reaction pathways of gallium(III) silylamide complexes
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- Solution-Based Synthesis of Crystalline Silicon from Liquid Silane through Laser and Chemical Annealing
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- Control of PbSe Quantum Dot Surface Chemistry and Photophysics Using an Alkylselenide Ligand
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- Zirconocene Dichloride Catalyzed Hydrodefluorination of C sp 2F bonds
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- A Hydrocarbon-Soluble Lithium Hydride Complex
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- A Cationic Calcium Hydride Cluster Stabilized by Cyclen-Derived Macrocyclic N,N,N,N Ligands
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- CN Bond Cleavage and Ring Expansion of N-Heterocyclic Carbenes using Hydrosilanes
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- A Generic One-Pot Route to Acyclic Two-Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene
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- Low-Coordinate Iron(I) and Manganese(I) Dimers: Kinetic Stabilization of an Exceptionally Short FeFe Multiple Bond
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- Binding of Molecular Magnesium Hydrides to a Zirconocene-Enyne Template
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- A Phosphorus/Aluminum-Based Frustrated Lewis Pair as an Ion Pair Receptor: Alkali Metal Hydride Adducts and Phase-Transfer Catalysis
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- H2 Activation and Hydride Transfer to Olefins by Al(C6F5)3-Based Frustrated Lewis Pairs
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- Beryllium-Induced CN Bond Activation and Ring Opening of an N-Heterocyclic Carbene
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- Next generation of Ge1−ySny (y = 0.01-0.09) alloys grown on Si(100) via Ge3H8 and SnD4: Reaction kinetics and tunable emission
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- Compositional dependence of the absorption edge and dark currents in Ge1−x−ySixSny/Ge(100) photodetectors grown via ultra-low-temperature epitaxy of Ge4H10, Si4H10, and SnD4
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- Monomeric Sn(ii) and Ge(ii) hydrides supported by a tridentate pincer-based ligand
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- Donor–acceptor stabilized silaformyl chloride
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- Molecular early main group metal hydrides: synthetic challenge, structures and applications
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- Magnesium-catalysed hydroboration of aldehydes and ketones
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- Ultra-Low-Temperature Epitaxy of Ge-based Semiconductors and Optoelectronic Structures on Si(100): Introducing Higher Order Germanes (Ge3H8, Ge4H10)
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- Versatile Conversion ofN-Heterocyclic Silylene to Silyl Metal Compounds by Insertion of Divalent Silicon into Metal-Carbon and Metal-Hydrogen Bonds
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- Selective Dimerization of Lewis-Acid/Base-Stabilized Phosphanylalanes
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- Selective Synthesis and Derivatization of Alkali Metal Silanides MSi(SiH3)3
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- Preparation of Stable Low-Oxidation-State Group 14 Element Amidohydrides and Hydride-Mediated Ring-Expansion Chemistry of N-Heterocyclic Carbenes
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- Main group coordination chemistry at low temperatures: A review of matrix isolated Group 12 to Group 18 complexes
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- Functional group chemistry at intramolecular frustrated Lewis pairs: substituent exchange at the Lewis acid site with 9-BBN
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- Salt metathesis for the synthesis of M–Al and M–H–Al bonds
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- Stoichiometric and catalytic reactions of LiAlH4 with Me2NHBH3
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- Synthesis of Molecular Gallium Hydrides by Means of Low-Temperature Catalytic Dehydrogenation
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- New Routes to Soluble Magnesium Amidoborane Complexes
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- Synthesis of Kinetically Stabilized 1,2-Dihydrodisilenes
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- A Stable Two-Coordinate Acyclic Silylene
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- (2011) Michael S. Hill et al. DALTON TRANSACTIONS
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- (2010) Hendrik F. T. Klare et al. DALTON TRANSACTIONS
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- (2010) Philip P. Power NATURE
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- Microwave Spectrum and Intramolecular Hydrogen Bonding of 2-Propene-1-selenol (H2C═CHCH2SeH)
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- Addition of Amines and Hydroborane to the Disilyne RSi≡SiR (R = SiiPr[CH(SiMe3)2]2) Giving Amino- and Boryl-Substituted Disilenes
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- cis/trans Isomerism of Hydroalumination and Hydrogallation Products-Reflections on Stability and Rearrangement Mechanism
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- A Persistent Alkylaluminum Peroxide: Surprising Stability of a Molecule with Strong Reducing and Oxidizing Functions in Close Proximity
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- Bis(trimethylsilyl)methyl Derivatives of Calcium, Strontium and Barium: Potentially Useful Dialkyls of the Heavy Alkaline Earth Elements
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- (2008) Beatriz Cordero et al. DALTON TRANSACTIONS
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- Reduction of Ketones with Hydrocarbon-Soluble Calcium Hydride: Stoichiometric Reactions and Catalytic Hydrosilylation
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- Reactions of Hydrazines with AlH3·NMe2Et - Formation of Aluminum-Nitrogen Heterocycles
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- Functionalized Tellurols: Synthesis, Spectroscopic Characterization by Photoelectron Spectroscopy, and Quantum Chemical Study
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- (2008) On-Yi Lee et al. JOURNAL OF ORGANIC CHEMISTRY
- Syntheses of a stable tristibine and of related antimony compounds with the 2,6-dimesitylphenyl (Dmp) substituent
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- Reactions of β-diketiminatoaluminum hydrides with tert-butyl hydrogenperoxide – Facile formation of dialuminoxanes containing Al–O–Al groups
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- Time-Resolved Cavity Ringdown Measurements and Kinetic Modeling of the Pressure Dependences of the Recombination Reactions of SiH2with the Alkenes C2H4, C3H6, andt-C4H8
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- A Microwave Spectroscopic and Quantum Chemical Study of 3-Butyne-1-selenol (HSeCH2CH2C⋮CH)
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- Homogeneous Decomposition Mechanisms of Diethylzinc by Raman Spectroscopy and Quantum Chemical Calculations
- (2008) Young Seok Kim et al. JOURNAL OF PHYSICAL CHEMISTRY A
- Influence of Acid on Luminescence Properties of Thioglycolic Acid-Capped CdTe Quantum Dots
- (2008) Abhijit Mandal et al. Journal of Physical Chemistry C
- Alkylaluminum-Complexed Zirconocene Hydrides: Identification of Hydride-Bridged Species by NMR Spectroscopy
- (2008) Steven M. Baldwin et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Dicarbollylamine Ligand as a Tunable Template for σ,σ- and π,σ-Bonding Modes: Syntheses, Structures, and Theoretical Studies of η5:η1-Coordinated Constrained-Geometry Group 13 Metal Complexes
- (2008) Jong-Dae Lee et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Mechanism of Growth of the Ge Wetting Layer Upon Exposure of Si(100)-2 × 1 to GeH4
- (2008) Chie-Sheng Liu et al. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
- Ions Related to Silynes and Disilynes: Computational Studies
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- Reactions of Terminal Alkynes with a Bulky Dialkylaluminum Hydride: Hydroalumination versus Deprotonation
- (2008) Werner Uhl et al. ORGANOMETALLICS
- Synthesis and Characterization of the Monomeric Vicinal Dianion Li2(THF)3[ArNC(SiMe3)2] and the Aluminum and Lithium Derivatives of the Amido Ligand [ArNCH(SiMe3)2]−
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- A Stable Silicon(0) Compound with a Si=Si Double Bond
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- Hypervalent hydridosilicates: synthesis, structure and hydride bridging
- (2007) Paul D. Prince et al. DALTON TRANSACTIONS
- Formation and Characterization of the Cationic Gallane Derivatives [(RH2N)2GaH2]Cl (R = Me oriPr) and [{(iPrH2N)GaH2NHiPr}2GaH2]Cl
- (2007) Christina Y. Tang et al. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
- Growth of γ-In2Se3 films on Si substrates by metal-organic chemical vapor deposition with different temperatures
- (2007) Yen-Chin Huang et al. JOURNAL OF CRYSTAL GROWTH
- Indium(III) Acetate-Catalyzed Intermolecular Radical Addition of Organic Iodides to Electron-Deficient Alkenes
- (2007) Katsukiyo Miura et al. ORGANIC LETTERS
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