Metal-Free Activation of Hydrogen, Carbon Dioxide, and Ammonia by the Open-Shell Singlet Biradicaloid [P(μ-NTer)]2

Activation of small molecules by biradicaloids

(2016) Alexander Hinz et al.   PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

Stable Heterocyclopentane-1,3-diyls

(2015) Alexander Hinz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addition of Ethylene or Hydrogen to a Main-Group Metal Cluster under Mild Conditions

(2015) Petra Vasko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Bond Activation and Catalytic Reduction of Carbon Dioxide at a Group 13 Metal Center

(2015) Joseph A. B. Abdalla et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

E-H Bond Activation of Ammonia and Water by a Geometrically Constrained Phosphorus(III) Compound

(2015) Thomas P. Robinson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

P–P σ-bond activation by gold(I) coordination

(2015) Alexander Hinz et al.   CHEMICAL COMMUNICATIONS

Cyclo-Pnicta-triazanes: Biradicaloids or Zwitterions?

(2015) Alexander Hinz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

Small Inorganic Rings in the 21st Century: From Fleeting Intermediates to Novel Isolable Entities

(2014) Gang He et al.   CHEMICAL REVIEWS

A Donor-Stabilized Zwitterionic “Half-Parent” Phosphasilene and Its Unusual Reactivity towards Small Molecules

(2014) Kerstin Hansen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dihydrogen Activation by a Silylium Silylene Frustrated Lewis Pair and the Unexpected Isomerization Reaction of a Protonated Silylene

(2014) Annemarie Schäfer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Activation of Small Molecules by Phosphorus Biradicaloids

(2014) Alexander Hinz et al.   CHEMISTRY-A EUROPEAN JOURNAL

A New Class of Azadipnictiridines Generated by an Unusual Rearrangement Reaction

(2014) Alexander Hinz et al.   INORGANIC CHEMISTRY

Reaction Mechanisms of Small-Molecule Activation by Amidoditetrylynes R2N–EE–NR2 (E = Si, Ge, Sn)

(2014) Markus Hermann et al.   INORGANIC CHEMISTRY

Reversible Intermolecular E–H Oxidative Addition to a Geometrically Deformed and Structurally Dynamic Phosphorous Triamide

(2014) Wei Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides

(2014) Douglas W. Stephan et al.   Chemical Science

An Arsenic-Nitrogen Biradicaloid: Synthesis, Properties, and Reactivity

(2013) Serhiy Demeshko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction of a P/Al-Based Frustrated Lewis Pair with Ammonia, Borane, and Amine-Boranes: Adduct Formation and Catalytic Dehydrogenation

(2013) Christian Appelt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diradicals

(2013) Manabu Abe   CHEMICAL REVIEWS

Activation of Isocyanates and Carbon Dioxide by a Monomeric Aluminium Hydrazide as an Active Lewis Pair

(2013) Frank Hengesbach et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanisms of Reactions of Open-Shell, Heavier Group 14 Derivatives with Small Molecules: n−π* Back-Bonding in Isocyanide Complexes, C–H Activation under Ambient Conditions, CO Coupling, and Ancillary Molecular Interactions†This Award Article summarizes, including more recent results, one of the themes of a lecture presented on March 26th, 2012, at the 243rd Chemical Society National Meeting American in San Diego, CA, in receipt of the 2012 Award in Organometallic Chemistry sponsored by the Dow Corporation.

(2013) Zachary D. Brown et al.   INORGANIC CHEMISTRY

Counterintuitive Mechanisms of the Addition of Hydrogen and Simple Olefins to Heavy Group 13 Alkene Analogues

(2013) Christine A. Caputo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heavier Main Group Dimetallene Reactivity: Effects of Frontier Orbital Symmetry

(2013) Christine A. Caputo et al.   ORGANOMETALLICS

Why the Mechanisms of Digermyne and Distannyne Reactions with H2 Differ So Greatly

(2012) LiLi Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main Group Redox Catalysis: Reversible PIII/PV Redox Cycling at a Phosphorus Platform

(2012) Nicole L. Dunn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

[P(μ-NTer)]2: A Biradicaloid That Is Stable at High Temperature

(2011) Torsten Beweries et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Activation of EH3 (E=P, As) by an Ylide-like Silylene and Formation of a Donor-Stabilized Arsasilene with a HSiAsH Subunit

(2010) Carsten Präsang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

π-Bonding and the Lone Pair Effect in Multiple Bonds Involving Heavier Main Group Elements: Developments in the New Millennium

(2010) Roland C. Fischer et al.   CHEMICAL REVIEWS

Advances in selective activation and application of ammonia in homogeneous catalysis

(2010) Jarl Ivar van der Vlugt   CHEMICAL SOCIETY REVIEWS

Nature of Bonding in Group 13 Dimetallenes: a Delicate Balance between Singlet Diradical Character and Closed Shell Interactions

(2010) Jani Moilanen et al.   INORGANIC CHEMISTRY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

N-heterocyclic carbenes which readily add ammonia, carbon monoxide and other small molecules,

(2010) Ulrich Siemeling et al.   Chemical Science

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Addition of Hydrogen or Ammonia to a Low-Valent Group 13 Metal Species at 25 °C and 1 Atmosphere

(2009) Zhongliang Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular Double-Bond Covalent Radii for Elements Li–E112

(2009) Pekka Pyykkö et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Addition Reactions of Element-Hydrogen Bonds with Different Polarities to a Gallium(I) Compound

(2009) Annekathrin Seifert et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Unsymmetric Oxo/Imido-Bridged Germanium-Centered Singlet Diradicaloid

(2009) Xinping Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Cationic Cyclic Phosphorus(III) Azide

(2008) Dirk Michalik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION