An isolable β-diketiminato chlorosilylene

N-heterocyclic silylenes as powerful steering ligands in catalysis

(2017) Saeed Raoufmoghaddam et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

A Bis(silylenyl)pyridine Zero-Valent Germanium Complex and Its Remarkable Reactivity

(2016) Yu-Peng Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From a Phosphaketenyl-Functionalized Germylene to 1,3-Digerma-2,4-diphosphacyclobutadiene

(2016) Shenglai Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pnictogen–Silicon Analogues of Benzene

(2016) Andreas E. Seitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of 7-Silanorbornadienes by N-Heterocyclic Carbenes: A Selective Way to N-Heterocyclic-Carbene-Stabilized Silylenes

(2016) Dennis Lutters et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Can low-valent silicon compounds be better transition metal ligands than phosphines and NHCs?

(2015) Zsolt Benedek et al.   RSC Advances

N-heterocyclic silylene complexes in catalysis: new frontiers in an emerging field

(2014) Burgert Blom et al.   Inorganic Chemistry Frontiers

Silicon(II) Coordination Chemistry: N-Heterocyclic Carbene Complexes of Si2+and SiI+

(2013) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cyclic Silylone (“Siladicarbene”) with an Electron-Rich Silicon(0) Atom

(2013) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First Principles Studies toward the Design of Silylene Superbases: A Density Functional Theory Study

(2013) Abul Kalam Biswas et al.   JOURNAL OF PHYSICAL CHEMISTRY A

The Elusive Silyliumylidene [ClSi:]+and Silathionium [ClSiS]+Cations Stabilized by Bis(Iminophosphorane) Chelate Ligand

(2012) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New Vistas in N-Heterocyclic Silylene (NHSi) Transition-Metal Coordination Chemistry: Syntheses, Structures and Reactivity towards Activation of Small Molecules

(2012) Burgert Blom et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation of Stable Low-Oxidation-State Group 14 Element Amidohydrides and Hydride-Mediated Ring-Expansion Chemistry of N-Heterocyclic Carbenes

(2012) S. M. Ibrahim Al-Rafia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Facile Access to the Functionalized N-Donor Stabilized Silylenes PhC(NtBu)2SiX (X = PPh2, NPh2, NCy2, NiPr2, NMe2, N(SiMe3)2, OtBu)

(2012) Ramachandran Azhakar et al.   ORGANOMETALLICS

Hydrosilylation of Alkynes by Ni(CO)3-Stabilized Silicon(II) Hydride

(2011) Miriam Stoelzel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zwitterionic Si-C-Si-P and Si-P-Si-P Four-Membered Rings with Two-Coordinate Phosphorus Atoms

(2011) Sakya S. Sen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactivity of a Silylsilylene Bearing a Functionalized Diaminochlorosilyl Substituent

(2011) Shu-Hua Zhang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silylation of N-heterocyclic carbene with aminochlorosilane and -disilane: dehydrohalogenation vs. Si–Si bond cleavage

(2011) Haiyan Cui et al.   DALTON TRANSACTIONS

Formation of a Donor-Stabilized Tetrasilacyclobutadiene Dication by a Lewis Acid Assisted Reaction of anN-Heterocyclic Chloro Silylene

(2011) Shigeyoshi Inoue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

Synthesis and Structure of a Base-Stabilized C-Phosphino-Si-Amino Silyne

(2010) David Gau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene

(2010) Sakya S. Sen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Aromatic C−F and C−H Bond Activation with Silylenes of Different Coordinate Silicon

(2010) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

SiBr2(Idipp): A Stable N-Heterocyclic Carbene Adduct of Dibromosilylene

(2009) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

Twice silicon-induced C–H activation and tautomerisation of a β-diketiminato ligand and formation of new types of N-heterocyclic silanes

(2008) Yun Xiong et al.   DALTON TRANSACTIONS