Extremely bulky amide ligands in main group chemistry

Two-coordinate hydrido-germylenes

(2015) Terrance J. Hadlington et al.   CHEMICAL COMMUNICATIONS

Utilisation of a lithium boryl as a reducing agent in low oxidation state group 15 chemistry: synthesis and characterisation of an amido-distibene and a boryl-dibismuthene

(2015) Deepak Dange et al.   CHEMICAL COMMUNICATIONS

Synthesis of Elusive Chloropnictenium Ions

(2015) Christian Hering-Junghans et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tuning Coordination in s-Block Carbazol-9-yl Complexes

(2015) Fabrizio Ortu et al.   CHEMISTRY-A EUROPEAN JOURNAL

The role of the bis-trimethylsilylamido ligand, [N{SiMe3}2]−, in main group chemistry. Part 2: Structural chemistry of the metallic p-block elements

(2015) Martyn P. Coles   COORDINATION CHEMISTRY REVIEWS

The role of the bis-trimethylsilylamido ligand, [N{SiMe3}2]−, in main group chemistry. Part 1: Structural chemistry of the s-block elements

(2015) Martyn P. Coles   COORDINATION CHEMISTRY REVIEWS

Protonolysis and Amide Exchange Reactions of a Three-Coordinate Cobalt Amide Complex Supported by an N-Heterocyclic Carbene Ligand

(2015) Christopher B. Hansen et al.   INORGANIC CHEMISTRY

Amido Analogues of Nonbent Lanthanide (II) and Calcium Metallocenes. Heterolytic Cleavage of π-Bond Ln–Carbazolyl Ligand Promoted by Lewis Base Coordination

(2015) Alexander N. Selikhov et al.   ORGANOMETALLICS

Synthesis of Molybdenum and Tungsten Alkylidene Complexes That Contain the 2,6-Bis(2,4,6-triisopropylphenyl)phenylimido (NHIPT) Ligand

(2015) Jonathan C. Axtell et al.   ORGANOMETALLICS

A singly bonded amido-distannyne: H2 activation and isocyanide coordination

(2014) Terrance J. Hadlington et al.   CHEMICAL COMMUNICATIONS

Formation of Novel T-Shaped NNN Ligands via Rare-Earth Metal-Mediated Si–H Activation

(2014) Denis Bubrin et al.   INORGANIC CHEMISTRY

Reaction Mechanisms of Small-Molecule Activation by Amidoditetrylynes R2N–EE–NR2 (E = Si, Ge, Sn)

(2014) Markus Hermann et al.   INORGANIC CHEMISTRY

Divalent Heteroleptic Ytterbium Complexes – Effective Catalysts for Intermolecular Styrene Hydrophosphination and Hydroamination

(2014) Ivan V. Basalov et al.   INORGANIC CHEMISTRY

A Two-Coordinate Manganese(0) Complex with an Unsupported Mn–Mg Bond: Allowing Access to Low Coordinate Homo- and Heterobimetallic Compounds

(2014) Jamie Hicks et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds

(2014) Terrance J. Hadlington et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable GaX2, InX2 and TlX2 radicals

(2014) Andrey V. Protchenko et al.   Nature Chemistry

Activation of H2by a Multiply Bonded Amido-Digermyne: Evidence for the Formation of a Hydrido-Germylene

(2013) Terrance J. Hadlington et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Arsenic-Nitrogen Biradicaloid: Synthesis, Properties, and Reactivity

(2013) Serhiy Demeshko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Germanium-centered free radicals studied by muon spin spectroscopy

(2013) Robert West et al.   CANADIAN JOURNAL OF CHEMISTRY

Synthesis and characterization of extremely bulky amido-germanium(II) halide complexes

(2013) Terrance J. Hadlington et al.   CANADIAN JOURNAL OF CHEMISTRY

Selective functionalization of a bis-silylene

(2013) Rajendra S. Ghadwal et al.   CHEMICAL COMMUNICATIONS

Amidinates, guanidinates and iminopyrrolidinates: Understanding precursor thermolysis to design a better ligand

(2013) Seán T. Barry   COORDINATION CHEMISTRY REVIEWS

Synthesis and Characterization of the Titanium Bisamide Ti{N(H)AriPr6}2 (AriPr6 = C6H3-2,6-(C6H2-2,4,6-iPr3)2 and Its TiCl{N(H)AriPr6}2 Precursor: Ti(II) → Ti(IV) Cyclization

(2013) Jessica N. Boynton et al.   INORGANIC CHEMISTRY

Structural Diversity in Alkali Metal Complexes of Sterically Demanding Carbazol-9-yl Ligands

(2013) Rhiannon S. Moorhouse et al.   INORGANIC CHEMISTRY

Synthesis of 1,3-Dichloro-cyclo-1,3-diphosphadiazanes from Silylated Amino(dichloro)phosphanes

(2013) Axel Schulz et al.   INORGANIC CHEMISTRY

Linear and Nonlinear Two-Coordinate Vanadium Complexes: Synthesis, Characterization, and Magnetic Properties of V(II) Amides

(2013) Jessica N. Boynton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction Pathways for Addition of H2 to Amido-Ditetrylynes R2N–EE–NR2 (E = Si, Ge, Sn). A Theoretical Study

(2013) Markus Hermann et al.   ORGANOMETALLICS

Cyclic Distiba- and Dibismadiazenium Cations

(2012) Mathias Lehmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Facile Reduction of Carbon Dioxide to Carbon Monoxide with an Amido-Digermyne

(2012) Jiaye Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Weak Arene Stabilization of Bulky Amido-Germanium(II) and Tin(II) Monocations

(2012) Jiaye Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chlorine/Methyl Exchange Reactions in Silylated Aminostibanes: A New Route To Stibinostibonium Cations

(2012) Christian Hering et al.   INORGANIC CHEMISTRY

Stable Silaimines with Three- and Four-Coordinate Silicon Atoms

(2012) Prinson P. Samuel et al.   INORGANIC CHEMISTRY

Monomeric Group 13 Metal(I) Amides: Enforcing One-Coordination Through Extreme Ligand Steric Bulk

(2012) Deepak Dange et al.   INORGANIC CHEMISTRY

A Non-Heme Iron(III) Complex with Porphyrin-like Properties That Catalyzes Asymmetric Epoxidation

(2012) Takashi Niwa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Computational Insights into the Stabilization of Low-Valent Main Group Elements Using Crown Ethers and Related Ligands

(2012) Charles L. B. Macdonald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Utilizing Steric Bulk to Stabilize Molybdenum Aminogermylyne and Aminogermylene Complexes

(2012) Jamie Hicks et al.   ORGANOMETALLICS

Chemistry of Soluble β-Diketiminatoalkaline-Earth Metal Complexes with M−X Bonds (M = Mg, Ca, Sr; X = OH, Halides, H)

(2011) Sankaranarayana Pillai Sarish et al.   ACCOUNTS OF CHEMICAL RESEARCH

[P(μ-NTer)]2: A Biradicaloid That Is Stable at High Temperature

(2011) Torsten Beweries et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms

(2011) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly sensitive and selective cyanide detection via Cu2+ complex ligand exchange

(2011) Hyuk-Chan Gee et al.   CHEMICAL COMMUNICATIONS

Tuning Main Group Redox Chemistry through Steric Loading: Subvalent Group 13 Metal Complexes of Carbazolyl Ligands

(2011) Hassanatu B. Mansaray et al.   CHEMISTRY-A EUROPEAN JOURNAL

Amido analogues of zincocenes and cadmocenes

(2011) Alexander J. Blake et al.   DALTON TRANSACTIONS

Extremely bulky amido-group 14 element chloride complexes: Potential synthons for low oxidation state main group chemistry

(2011) Jiaye Li et al.   DALTON TRANSACTIONS

Stable dimeric magnesium(i) compounds: from chemical landmarks to versatile reagents

(2011) Andreas Stasch et al.   DALTON TRANSACTIONS

The N,N-Bis(terphenyl)aminophosphenium Cation - A Sensitive Probe for Interactions with Different Anions

(2011) Fabian Reiß et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Digermyne with a Ge–Ge Single Bond That Activates Dihydrogen in the Solid State

(2011) Jiaye Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dichlorocyclodibismadiazane

(2010) Dirk Michalik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structurally Engineered Deprotonation/Alumination of THF and THTP with Retention of Their Cycloanionic Structures

(2010) Elaine Crosbie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible complexation of isocyanides by the distannyne Ar′SnSnAr′ (Ar′ = C6H3-2,6(C6H3-2,6-iPr2)2)

(2010) Yang Peng et al.   CHEMICAL COMMUNICATIONS

Synthesis of sterically encumbered 2,4-bis-m-terphenyl-1,3-dichloro-2,4-cyclo-dipnictadiazanes [m-TerNPnCl]2, (Pn = P, As)

(2010) Fabian Reiß et al.   DALTON TRANSACTIONS

Recent developments in transition metal diaryl chemistry

(2010) Deborah L. Kays   DALTON TRANSACTIONS

Synthesis and Characterization of 1,3-Dihalogeno-2,4-bis(2,4,6-tri-tert-butylphenyl)-cyclo-1,3-distiba-2,4-diazanes, [X-Sb(μ-NR)]2 (X = F, Cl, Br, and I)

(2010) Mathias Lehmann et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and Structural Characterization of a Series of Dimeric Metal(II) Imido Complexes {M(μ-NAr#)}2[M = Ge, Sn, Pb; Ar#= C6H3-2,6-(C6H2-2,4,6-Me3)2] and the Related Monomeric Primary Amido Derivatives M{N(H)Ar#}2(M = Ge, Sn, Pb): Spectroscopic Manifestations of Secondary Metal−Ligand Interactions

(2010) William A. Merrill et al.   INORGANIC CHEMISTRY

Hydrogen-Atom Abstraction from Ni(I) Phosphido and Amido Complexes Gives Phosphinidene and Imide Ligands

(2010) Vlad M. Iluc et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene Stabilized Dichlorosilaimine IPr·Cl2Si═NR

(2010) Rajendra S. Ghadwal et al.   ORGANOMETALLICS

Substituent effects in ditetrel alkyne analogues: multiple vs. single bonded isomers

(2010) Yang Peng et al.   Chemical Science

Bulky guanidinates for the stabilization of low oxidation state metallacycles

(2009) Cameron Jones   COORDINATION CHEMISTRY REVIEWS

Two-coordinate, homoleptic manganese(ii) primary terphenyl amido complexes: the effects of secondary coordination on geometry and Lewis base complexation

(2009) Chengbao Ni et al.   DALTON TRANSACTIONS

IPr* an easily accessible highly hindered N-heterocyclic carbene

(2009) Guillaume Berthon-Gelloz et al.   DALTON TRANSACTIONS

Synthesis and Characterisation of Low-Coordinate Transition-Metal Complexes Stabilised by Sterically Demanding Carbazolido Ligands

(2009) Andrew E. Ashley et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cyclic Arsenic−Nitrogen Cations

(2009) Axel Schulz et al.   INORGANIC CHEMISTRY

Spin-State Crossover with Structural Changes in a Cobalt(II) Organometallic Species: Low-Coordinate, First Row, Heteroleptic Amido Transition Metal Aryls. Synthesis and Characterization of Ar′MN(H)Ar#(M = Mn, Fe, Co) (Ar′ = C6H3-2,6-(C6H3-2,6-iPr2)2, Ar#= C6H3-2,6-(C6H2-2,4,6-Me3)2)

(2009) Chengbao Ni et al.   INORGANIC CHEMISTRY

A Cationic Cyclic Phosphorus(III) Azide

(2008) Dirk Michalik et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and reactivity of neodymium(III) amido-tethered N-heterocyclic carbene complexes

(2008) Polly L. Arnold et al.   COMPTES RENDUS CHIMIE

Recent developments in the chemistry of low valent Group 14 hydrides

(2008) Eric Rivard et al.   DALTON TRANSACTIONS

Lewis-Acid-Assisted Methyl Exchange Reactions In Silylated Aminodichloroarsanes

(2008) Dirk Michalik et al.   INORGANIC CHEMISTRY

The Chemistry of Aluminum(I), Silicon(II), and Germanium(II)

(2008) Selvarajan Nagendran et al.   ORGANOMETALLICS

Disilyne with a silicon-silicon triple bond: A new entry to multiple bond chemistry

(2008) Akira Sekiguchi   PURE AND APPLIED CHEMISTRY

Bulky aryl functionalized carbazolyl ligands: amido alternatives to the 2,6-diarylphenyl ligand class?

(2007) Natalie D. Coombs et al.   DALTON TRANSACTIONS