The broadening reach of frustrated Lewis pair chemistry

C−C Coupling of Benzyl Fluorides Catalyzed by an Electrophilic Phosphonium Cation

(2016) Jiangtao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Coupling of Carbon Monoxide with Nitrogen Monoxide at a Frustrated Lewis Pair Template

(2016) Ke-Yin Ye et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphorus Lewis acids: emerging reactivity and applications in catalysis

(2016) J. M. Bayne et al.   CHEMICAL SOCIETY REVIEWS

Selectivity Effects in Bimetallic Catalysis

(2016) Neal P. Mankad   CHEMISTRY-A EUROPEAN JOURNAL

Unexpected Formation of Early Late Heterobimetallic Complexes from Transition Metal Frustrated Lewis Pairs

(2016) Andy M. Chapman et al.   INORGANIC CHEMISTRY

Transition-Metal Oxos as the Lewis Basic Component of Frustrated Lewis Pairs

(2016) Nikola S. Lambic et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable Borocyclic Radicals via Frustrated Lewis Pair Hydrogenations

(2016) Lauren E. Longobardi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free sp2-C–H Borylation as a Common Reactivity Pattern of Frustrated 2-Aminophenylboranes

(2016) Konstantin Chernichenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoexcited Surface Frustrated Lewis Pairs for Heterogeneous Photocatalytic CO2 Reduction

(2016) Kulbir Kaur Ghuman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Frustrated Lewis Pairs Catalyzed Highly Enantioselective Hydrosilylations of 1,2-Dicarbonyl Compounds

(2016) Xiaoyu Ren et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-free electrocatalytic hydrogen oxidation using frustrated Lewis pairs and carbon-based Lewis acids

(2016) Elliot J. Lawrence et al.   Chemical Science

Highly selective catalytic trans-hydroboration of alkynes mediated by borenium cations and B(C6F5)3

(2016) John S. McGough et al.   Chemical Science

Molecular Electrocatalysts for Oxidation of Hydrogen Using Earth-Abundant Metals: Shoving Protons Around with Proton Relays

(2015) R. Morris Bullock et al.   ACCOUNTS OF CHEMICAL RESEARCH

Use of Trifluoromethyl Groups for Catalytic Benzylation and Alkylation with Subsequent Hydrodefluorination

(2015) Jiangtao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electrophilic Fluorophosphonium Cations in Frustrated Lewis Pair Hydrogen Activation and Catalytic Hydrogenation of Olefins

(2015) Thorsten vom Stein et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile Protocol for Catalytic Frustrated Lewis Pair Hydrogenation and Reductive Deoxygenation of Ketones and Aldehydes

(2015) Tayseer Mahdi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogenations at Room Temperature and Atmospheric Pressure with Mesoionic Carbene-Stabilized Borenium Catalysts

(2015) Patrick Eisenberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic reduction of polar substrates without metals: A thermodynamic and kinetic study of heterolytic activation of hydrogen by vacancies in frustrated Lewis pairs

(2015) Sean M. Whittemore et al.   CATALYSIS TODAY

Thermal C–H borylation using a CO-free iron boryl complex

(2015) Thomas J. Mazzacano et al.   CHEMICAL COMMUNICATIONS

Chiral Molecular Tweezers: Synthesis and Reactivity in Asymmetric Hydrogenation

(2015) Markus Lindqvist et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Double FLP-Alkyne Exchange Reactions: A Facile Route to Te/B Heterocycles

(2015) Fu An Tsao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

E-Selective Semi-Hydrogenation of Alkynes by Heterobimetallic Catalysis

(2015) Malkanthi K. Karunananda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pathways to Functionalized Heterocycles: Propargyl Rearrangement using B(C6F5)3

(2015) Lewis C. Wilkins et al.   ORGANOMETALLICS

Diverging Pathways in the Activation of Allenes with Lewis Acids and Bases: Addition, 1,2-Carboboration, and Cyclization

(2015) Rebecca L. Melen et al.   ORGANOMETALLICS

Illuminating CO2 reduction on frustrated Lewis pair surfaces: investigating the role of surface hydroxides and oxygen vacancies on nanocrystalline In2O3−x(OH)y

(2015) Kulbir Kaur Ghuman et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS

Metal-free catalytic C-H bond activation and borylation of heteroarenes

(2015) M.-A. Legare et al.   SCIENCE

A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis

(2015) Jeffrey M. Farrell et al.   Chemical Science

Metal-free dehydrogenation of formic acid to H2 and CO2 using boron-based catalysts

(2015) Clément Chauvier et al.   Chemical Science

Design of Lewis Pair-Functionalized Metal Organic Frameworks for CO2 Hydrogenation

(2015) Jingyun Ye et al.   ACS Catalysis

A Heterobimetallic Mechanism for C–H Borylation Elucidated from Experimental and Computational Data

(2015) Sean R. Parmelee et al.   ACS Catalysis

Frustrated Lewis Pair Activation of anN-Sulfinylamine: A Source of Sulfur Monoxide

(2014) Lauren E. Longobardi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperative Lewis Pairs Based on Late Transition Metals: Activation of Small Molecules by Platinum(0) and B(C6F5)3

(2014) Sebastian J. K. Forrest et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Methylacridinium Salts: Carbon Lewis Acids in Frustrated Lewis Pairs for σ-Bond Activation and Catalytic Reductions

(2014) Ewan R. Clark et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B(C6F5)3-Catalyzed Hydrogenation of Oxime Ethers without Cleavage of the NO Bond

(2014) Jens Mohr et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Hydrogenation of Unsaturated Hydrocarbons Employing Molecular Hydrogen

(2014) Jan Paradies   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B(C6F5)3 promoted cyclisation of internal propargyl esters: structural characterisation of 1,3-dioxolium compounds

(2014) Max M. Hansmann et al.   CHEMICAL COMMUNICATIONS

Ru-η6-Arene Cations [{(Ph2PC6H4)2B(η6-Ph)}RuX]+(X=Cl, H) as Lewis Acids

(2014) Michael P. Boone et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Combined “Electrochemical-Frustrated Lewis Pair” Approach to Hydrogen Activation: Surface Catalytic Effects at Platinum Electrodes

(2014) Elliot J. Lawrence et al.   CHEMISTRY-A EUROPEAN JOURNAL

syn-1,2-Carboboration of Alkynes with Borenium Cations

(2014) Ian A. Cade et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stoichiometric reductions of alkyl-substituted ketones and aldehydes to borinic esters

(2014) Lauren E. Longobardi et al.   DALTON TRANSACTIONS

Reducing CO2 to Methanol Using Frustrated Lewis Pairs: On the Mechanism of Phosphine–Borane-Mediated Hydroboration of CO2

(2014) Marc-André Courtemanche et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Probing Site Cooperativity of Frustrated Phosphine/Borane Lewis Pairs by a Polymerization Study

(2014) Tieqi Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Enantioselective Hydrogenation of Silyl Enol Ethers Catalyzed by Chiral Frustrated Lewis Pairs

(2014) Simin Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functional Model for the [Fe] Hydrogenase Inspired by the Frustrated Lewis Pair Concept

(2014) Kai F. Kalz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enabling Catalytic Ketone Hydrogenation by Frustrated Lewis Pairs

(2014) Tayseer Mahdi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation

(2014) Tzu-Pin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nonmetal Catalyzed Hydrogenation of Carbonyl Compounds

(2014) Daniel J. Scott et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Pyridine- and 2-Oxazoline-Functionalized Vinyl Polymers by Alane-Based Frustrated Lewis Pairs

(2014) Eugene Chen et al.   SYNLETT

Frustrated Lewis pair chemistry of carbon, nitrogen and sulfur oxides

(2014) Douglas W. Stephan et al.   Chemical Science

Facile Carbon Monoxide Reduction at Intramolecular Frustrated Phosphane/Borane Lewis Pair Templates

(2013) Muhammad Sajid et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Reduction of CO2to CO by Using Zinc(II) and In Situ Generated Carbodiphosphoranes

(2013) Roman Dobrovetsky et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Aluminum-Nitrogen Based Lewis Pair as an Effective Catalyst for the Oligomerization of Cyanamides: Formation of Acyclic CN Oligomers Instead of Thermodynamically Favored Cyclic Aromatic Trimers

(2013) Thorsten Holtrichter-Rößmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pair Catalyzed Hydroamination of Terminal Alkynes

(2013) Tayseer Mahdi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Combinations of Ethers and B(C6F5)3Function as Hydrogenation Catalysts

(2013) Lindsay J. Hounjet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cyclisation versus 1,1-Carboboration: Reactions of B(C6F5)3with Propargyl Amides

(2013) Rebecca L. Melen et al.   CHEMISTRY-A EUROPEAN JOURNAL

C–H Bond Activation by Radical Ion Pairs Derived from R3P/Al(C6F5)3 Frustrated Lewis Pairs and N2O

(2013) Gabriel Ménard et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stoichiometric Metal-Free Reduction of CO in Syn-Gas

(2013) Roman Dobrovetsky et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Dienes as “Ligands” for Borane-Catalyzed Metal-Free Asymmetric Hydrogenation of Imines

(2013) Yongbing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Borane-Catalyzed Highly Stereoselective Hydrogenation of Pyridines

(2013) Yongbing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Transition Metal Lewis Acid/Base Triad System for Cooperative Substrate Binding

(2013) Oscar Tutusaus et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic CO2 Activation Assisted by Rhenium Hydride/B(C6F5)3 Frustrated Lewis Pairs—Metal Hydrides Functioning as FLP Bases

(2013) Yanfeng Jiang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Ru−η6-Arene Complex as a C-Based Lewis Acid in the Activation of Hydrogen and Hydrogenation Catalysis

(2013) Michael P. Boone et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity Models of Hydrogen Activation by Frustrated Lewis Pairs: Synergistic Electron Transfers or Polarization by Electric Field?

(2013) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Alkynes with B(C6F5)3 – Boron Allylation Reagents Derived from Propargyl Esters

(2013) Max M. Hansmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A frustrated-Lewis-pair approach to catalytic reduction of alkynes to cis-alkenes

(2013) Konstantin Chernichenko et al.   Nature Chemistry

[(acridine)BCl2]+: A Borenium Cation That Is a Strong Boron- and Carbon-Based Lewis Acid

(2013) Ewan R. Clark et al.   ORGANOMETALLICS

Metal-Free Hydrogenation of N-Based Heterocycles

(2013) Tayseer Mahdi et al.   ORGANOMETALLICS

Ancillary Metal Centers in Frustrated Lewis Pair Chemistry: Ruthenium Acetylide as a Lewis Base in the Activation of CO2, Aldehyde, and Alkyne

(2013) Michael P. Boone et al.   ORGANOMETALLICS

Lewis Acidity of Organofluorophosphonium Salts: Hydrodefluorination by a Saturated Acceptor

(2013) C. B. Caputo et al.   SCIENCE

Gold catalyzed hydrogenations of small imines and nitriles: enhanced reactivity of Au surface toward H2via collaboration with a Lewis base

(2013) Gang Lu et al.   Chemical Science

Frustrated Lewis Pair Inspired Carbon Dioxide Reduction by a Ruthenium Tris(aminophosphine) Complex

(2012) Michael J. Sgro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free hydrogenation catalysis of polycyclic aromatic hydrocarbons

(2012) Yasutomo Segawa et al.   CHEMICAL COMMUNICATIONS

The Role of Pendant Amines in the Breaking and Forming of Molecular Hydrogen Catalyzed by Nickel Complexes

(2012) Simone Raugei et al.   CHEMISTRY-A EUROPEAN JOURNAL

Lewis pair polymerization by classical and frustrated Lewis pairs: acid, base and monomer scope and polymerization mechanism

(2012) Yuetao Zhang et al.   DALTON TRANSACTIONS

Metal-Free Aromatic Hydrogenation: Aniline to Cyclohexyl-amine Derivatives

(2012) Tayseer Mahdi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N,N-Addition of Frustrated Lewis Pairs to Nitric Oxide: An Easy Entry to a Unique Family of Aminoxyl Radicals

(2012) Muhammad Sajid et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Hydrogen and Hydrogenation Catalysis by a Borenium Cation

(2012) Jeffrey M. Farrell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Taking the F out of FLP: Simple Lewis Acid–Base Pairs for Mild Reductions with Neutral Boranes via Borenium Ion Catalysis

(2012) Patrick Eisenberger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis pair-like splitting of aromatic C–H bonds and abstraction of halogen atoms by a cationic [(FPNP)Pt]+species

(2012) Jessica C. DeMott et al.   Chemical Science

Capture of NO by a Frustrated Lewis Pair: A New Type of Persistent N-Oxyl Radical

(2011) Allan Jay P. Cardenas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Hydrogenation with Frustrated Lewis Pairs: Selectivity Achieved by Size-Exclusion Design of Lewis Acids

(2011) Gábor Erős et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alane-Based Classical and Frustrated Lewis Pairs in Polymer Synthesis: Rapid Polymerization of MMA and Naturally Renewable Methylene Butyrolactones into High-Molecular-Weight Polymers

(2010) Yuetao Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Hydrogenation with Chiral Frustrated Lewis Pairs

(2010) Dianjun Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Mechanism of Dihydrogen Activation by Frustrated Lewis Pairs Revisited

(2010) Stefan Grimme et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Non-Metal-Mediated Homogeneous Hydrogenation of CO2 to CH3OH

(2009) Andrew E. Ashley et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Terminal Alkyne Activation by Frustrated and Classical Lewis Acid/Phosphine Pairs

(2009) Meghan A. Dureen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Mechanism of B(C6F5)3-Catalyzed Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration

(2009) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H2Activation and the Role of Acid−Base Properties

(2009) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Turning Frustration into Bond Activation: A Theoretical Mechanistic Study on Heterolytic Hydrogen Splitting by Frustrated Lewis Pairs

(2008) Tibor András Rokob et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free catalytic hydrogenation of imines with tris(perfluorophenyl)borane

(2008) Dianjun Chen et al.   CHEMICAL COMMUNICATIONS

The Crystal Structure of [Fe]-Hydrogenase Reveals the Geometry of the Active Site

(2008) S. Shima et al.   SCIENCE