Reaction of a P/Al-Based Frustrated Lewis Pair with Ammonia, Borane, and Amine-Boranes: Adduct Formation and Catalytic Dehydrogenation

Computational Evidence for a New Type of η2-H2 Complex: When Main-Group Elements Act in Concert To Emulate Transition Metals

(2012) László Könczöl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Phosphorus/Aluminum-Based Frustrated Lewis Pair as an Ion Pair Receptor: Alkali Metal Hydride Adducts and Phase-Transfer Catalysis

(2012) Christian Appelt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free Catalytic Olefin Hydrogenation: Low-Temperature H2 Activation by Frustrated Lewis Pairs

(2012) Lutz Greb et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine-boronates: efficient bifunctional organocatalysts for Michael addition

(2012) Olivier Baslé et al.   CHEMICAL COMMUNICATIONS

Enantioselective Hydrosilylation with Chiral Frustrated Lewis Pairs

(2012) Dianjun Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

“Spontaneous” Ambient Temperature Dehydrocoupling of Aromatic Amine-Boranes

(2012) Holger Helten et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dihydrogen Generation from Amine/Boranes: Synthesis, FT-ICR, and Computational Studies

(2012) José-Luis M. Abboud et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic metal-free intramolecular hydroaminations of non-activated aminoalkenes: A computational exploration

(2012) Haixia Li et al.   DALTON TRANSACTIONS

Cationic Ti(iv) and neutral Ti(iii) titanocene–phosphinoaryloxide frustrated Lewis pairs: hydrogen activation and catalytic amine-borane dehydrogenation

(2012) Andy M. Chapman et al.   DALTON TRANSACTIONS

Development of a Generic Mechanism for the Dehydrocoupling of Amine-Boranes: A Stoichiometric, Catalytic, and Kinetic Study of H3B·NMe2H Using the [Rh(PCy3)2]+ Fragment

(2012) Laura J. Sewell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Metal-Free Hydrogen Transfer between Amine–Boranes and Aminoboranes

(2012) Erin M. Leitao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Hydrogen and Hydrogenation Catalysis by a Borenium Cation

(2012) Jeffrey M. Farrell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Taking the F out of FLP: Simple Lewis Acid–Base Pairs for Mild Reductions with Neutral Boranes via Borenium Ion Catalysis

(2012) Patrick Eisenberger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Breaking the limits with silylenes

(2012) Matthias Driess   Nature Chemistry

“Frustrated Lewis pair” hydrogenations

(2012) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic versus stoichiometric dehydrocoupling using main group metals

(2012) Robert J. Less et al.   RSC Advances

Green Bipropellants: Hydrogen-Rich Ionic Liquids that Are Hypergolic with Hydrogen Peroxide

(2011) Stefan Schneider et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Geminal Phosphorus/Aluminum-Based Frustrated Lewis Pairs: CH versus CC Activation and CO2Fixation

(2011) Christian Appelt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3

(2011) Hugh J. Cowley et al.   CHEMICAL COMMUNICATIONS

Mechanistic Aspects of Bond Activation with Perfluoroarylboranes

(2011) Warren E. Piers et al.   INORGANIC CHEMISTRY

Metal-Free Catalytic Hydrogenation of Polar Substrates by Frustrated Lewis Pairs

(2011) Douglas W. Stephan et al.   INORGANIC CHEMISTRY

Frustrated Lewis Pairs beyond the Main Group: Cationic Zirconocene–Phosphinoaryloxide Complexes and Their Application in Catalytic Dehydrogenation of Amine Boranes

(2011) Andy M. Chapman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Preorganized Frustrated Lewis Pairs

(2011) Federica Bertini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Group 13 BN dehydrocoupling reagents, similar to transition metal catalysts but with unique reactivity

(2011) Max M. Hansmann et al.   Chemical Science

Coordination and Dehydrogenation of Amine-Boranes at Metal Centers

(2010) Gilles Alcaraz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

(2010) Guido D. Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dehydrogenation of amine–boranes with a frustrated Lewis pair

(2010) Alexander J. M. Miller et al.   CHEMICAL COMMUNICATIONS

Activation of dihydrogen by non-metal systems

(2010) Douglas W. Stephan   CHEMICAL COMMUNICATIONS

Applications and validations of the Minnesota density functionals

(2010) Yan Zhao et al.   CHEMICAL PHYSICS LETTERS

Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules

(2010) Anne Staubitz et al.   CHEMICAL REVIEWS

Ammonia-Borane and Related Compounds as Dihydrogen Sources

(2010) Anne Staubitz et al.   CHEMICAL REVIEWS

Advances in selective activation and application of ammonia in homogeneous catalysis

(2010) Jarl Ivar van der Vlugt   CHEMICAL SOCIETY REVIEWS

Group 2 Promoted Hydrogen Release from NMe2H⋅BH3: Intermediates and Catalysis

(2010) David J. Liptrot et al.   CHEMISTRY-A EUROPEAN JOURNAL

Facile synthesis of dichlorosilane by metathesis reaction and dehydrogenation of dihydrogermane by a frustrated Lewis pair

(2010) Anukul Jana et al.   DALTON TRANSACTIONS

Reactions of Amine- and Phosphane-Borane Adducts with Frustrated Lewis Pair Combinations of Group 14 Triflates and Sterically Hindered Nitrogen Bases

(2010) George R. Whittell et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Theoretical Study on the Possibility of Using Frustrated Lewis Pairs as Bifunctional Metal-Free Dehydrogenation Catalysts of Ammonia−Borane

(2010) Yong Guo et al.   INORGANIC CHEMISTRY

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

(2010) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Ruthenium Bis(σ-BH) Aminoborane Complexes from Dehydrogenation of Amine-Boranes: Trapping of H2BNH2

(2009) Gilles Alcaraz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and structure of a magnesium–amidoborane complex and its role in catalytic formation of a new bis-aminoborane ligand

(2009) Jan Spielmann et al.   CHEMICAL COMMUNICATIONS

Dihydrogen Bonding: Donor-Acceptor Bonding (AH⋅⋅⋅HX) versus the H2Molecule (AH2X)

(2009) David Hugas et al.   CHEMISTRY-A EUROPEAN JOURNAL

On the Possibility of Conversion of Alcohols to Ketones and Aldehydes by Phosphinoboranes R2PBR′R′′: A Computational Study

(2009) Timofei Privalov   CHEMISTRY-A EUROPEAN JOURNAL

Dehydrogenation reactivity of a frustrated carbene–borane Lewis pair

(2009) Dirk Holschumacher et al.   DALTON TRANSACTIONS

Structures and Aggregation of the Methylamine−Borane Molecules, MenH3−nN·BH3(n= 1−3), Studied by X-ray Diffraction, Gas-Phase Electron Diffraction, and Quantum Chemical Calculations

(2009) Simon Aldridge et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H2Activation and the Role of Acid−Base Properties

(2009) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N-Heterocyclic Carbene and B(C6F5)3

(2008) Preston A. Chase et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

B–H Activation by frustrated Lewis pairs: borenium or boryl phosphonium cation?

(2008) Meghan A. Dureen et al.   CHEMICAL COMMUNICATIONS

Heterolytic H2 Activation by Nonmetals

(2007) Alyson L. Kenward et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION