Base-induced reversible H2 addition to a single Sn(ii) centre

Oxidative Addition and Reductive Elimination at Main-Group Element Centers

(2018) Terry Chu et al.   CHEMICAL REVIEWS

Synthesis and Reactivity of Donor-Stabilized Bis(pentafluoroethyl)stannylene [Sn(C2 F5 )2 (D) n ] (D=THF, DMAP, PMe3 , [Sn(C2 F5 )3 ]− )

(2018) Johannes Klösener et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reversible Coordination of H2 by a Distannyne

(2018) Shuai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Twist of a Silicon–Silicon Double Bond: Selective Anti-Addition of Hydrogen to an Iminodisilene

(2017) Daniel Wendel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Si(II) to Si(IV) and Back: Reversible Intramolecular Carbon–Carbon Bond Activation by an Acyclic Iminosilylene

(2017) Daniel Wendel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable Push–Pull Disilene: Substantial Donor–Acceptor Interactions through the Si═Si Double Bond

(2017) Tomoyuki Kosai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the concept of frustrated Lewis pairs

(2017) Frédéric-Georges Fontaine et al.   PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES

Metal-Free Activation of Hydrogen, Carbon Dioxide, and Ammonia by the Open-Shell Singlet Biradicaloid [P(μ-NTer)]2

(2016) Alexander Hinz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Catalytic Hydrogenation Using A Simple Tin(IV) Lewis Acid

(2016) Daniel J. Scott et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of Dihydrogen by Masked Doubly Bonded Aluminum Species

(2016) Koichi Nagata et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple Graphical Method to Determine the Order in Catalyst

(2016) Jordi Burés   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible Dihydrogen Activation by Reduced Aryl Boranes as Main-Group Ambiphiles

(2016) Esther von Grotthuss et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to Base Adducts of Low-Valent Organotin-Hydride Compounds by Controlled, Stepwise Hydrogen Abstraction from a Tetravalent Organotin Trihydride

(2016) Christian P. Sindlinger et al.   CHEMISTRY-A EUROPEAN JOURNAL

New Insight into the Nature of Bonding in the Dimers of Lappert’s Stannylene and Its Ge Analogs: A Quantum Mechanical Study

(2016) Robert Sedlak et al.   Journal of Chemical Theory and Computation

Enabling and Probing Oxidative Addition and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E–H Bonds by a Bis(boryl)stannylene

(2016) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A stable heavier group 14 analogue of vinylidene

(2016) Arnab Rit et al.   Nature Chemistry

The broadening reach of frustrated Lewis pair chemistry

(2016) D. W. Stephan   SCIENCE

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Main Group Lewis Acids in Frustrated Lewis Pair Chemistry: Beyond Electrophilic Boranes

(2015) Sarah A. Weicker et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

A nitrogen-base catalyzed generation of organotin(ii) hydride from an organotin trihydride under reductive dihydrogen elimination

(2015) Christian P. Sindlinger et al.   Chemical Science

Hydrogen abstraction from organotin di- and trihydrides by N-heterocyclic carbenes: a new method for the preparation of NHC adducts to tin(ii) species and observation of an isomer of a hexastannabenzene derivative [R6Sn6]

(2014) Christian P. Sindlinger et al.   Chemical Science

Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene

(2013) Adrian Y. Houghton et al.   CHEMICAL COMMUNICATIONS

Probing the Association of Frustrated Phosphine–Borane Lewis Pairs in Solution by NMR Spectroscopy

(2013) Luca Rocchigiani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interaction of Multiple Bonded and Unsaturated Heavier Main Group Compounds with Hydrogen, Ammonia, Olefins, and Related Molecules

(2011) Philip P. Power   ACCOUNTS OF CHEMICAL RESEARCH

Metal-Free Catalytic Hydrogenation of Polar Substrates by Frustrated Lewis Pairs

(2011) Douglas W. Stephan et al.   INORGANIC CHEMISTRY

The Role of Intermolecular Hydrogen Bonding and Proton Transfer in Proton-Coupled Electron Transfer

(2011) Timothy M. Alligrant et al.   Journal of Physical Chemistry C

Fast Production of Highly Reactive No-Carrier-Added [18F]Fluoride for the Labeling of Radiopharmaceuticals

(2010) Christian F. Lemaire et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Addition of Hydrogen or Ammonia to a Low-Valent Group 13 Metal Species at 25 °C and 1 Atmosphere

(2009) Zhongliang Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination

(2009) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rationalizing the Reactivity of Frustrated Lewis Pairs: Thermodynamics of H2Activation and the Role of Acid−Base Properties

(2009) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Turning Frustration into Bond Activation: A Theoretical Mechanistic Study on Heterolytic Hydrogen Splitting by Frustrated Lewis Pairs

(2008) Tibor András Rokob et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addition of H2 to distannynes under ambient conditions

(2008) Yang Peng et al.   CHEMICAL COMMUNICATIONS

Basicity of organic bases and superbases in acetonitrile by the polarized continuum model and DFT calculations

(2008) Zoran Glasovac et al.   NEW JOURNAL OF CHEMISTRY

Heterolytic H2 Activation by Nonmetals

(2007) Alyson L. Kenward et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION