Main group catalysed reduction of unsaturated bonds

Accessing Zinc Monohydride Cations through Coordinative Interactions

(2014) Paul A. Lummis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Transfer Hydrogenation by a Trivalent Phosphorus Compound: Phosphorus-Ligand Cooperation Pathway or PIII/PVRedox Pathway?

(2014) Guixiang Zeng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Concerted Transfer Hydrogenolysis: 1,3,2-Diazaphospholene-Catalyzed Hydrogenation of NN Bond with Ammonia-Borane

(2014) Che Chang Chong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zincocene and Dizincocene N-Heterocyclic Carbene Complexes and Catalytic Hydrogenation of Imines and Ketones

(2014) Phillip Jochmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cesium Carbonate Catalyzed Chemoselective Hydrosilylation of Aldehydes and Ketones under Solvent-Free Conditions

(2014) Mengdi Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Crown ether adducts of light alkali metal triphenylsilyls: synthesis, structure and hydrosilylation catalysis

(2014) Valeri Leich et al.   DALTON TRANSACTIONS

Mechanistic studies of CO2 reduction to methanol mediated by an N-heterocyclic germylene hydride

(2014) Gengwen Tan et al.   DALTON TRANSACTIONS

Syntheses of 2-silicon-substituted 1,3-dienes

(2014) Partha P. Choudhury et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds

(2014) Terrance J. Hadlington et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct observation of a borane–silane complex involved in frustrated Lewis-pair-mediated hydrosilylations

(2014) Adrian Y. Houghton et al.   Nature Chemistry

Experimental and computational studies of borohydride catalyzed hydrosilylation of a variety of CO and CN functionalities including esters, amides and heteroarenes

(2014) Michael G. Manas et al.   NEW JOURNAL OF CHEMISTRY

Catalytic Reductive Dehydration of Tertiary Amides to Enamines under Hydrosilylation Conditions

(2014) Alexey Volkov et al.   ORGANIC LETTERS

Direct reductive amination using triethylsilane and catalytic bismuth(III) chloride

(2014) Takehiko Matsumura et al.   TETRAHEDRON LETTERS

Selective reduction of CO2 to a methanol equivalent by B(C6F5)3-activated alkaline earth catalysis

(2014) Mathew D. Anker et al.   Chemical Science

Reduction of bicarbonate and carbonate to formate in molecular zinc complexes

(2014) Wesley Sattler et al.   Catalysis Science & Technology

Organocatalytic strategies for enantioselective metal-free reductions

(2014) Sergio Rossi et al.   Catalysis Science & Technology

3-Silylated Cyclohexa-1,4-dienes as Precursors for Gaseous Hydrosilanes: The B(C6F5)3-Catalyzed Transfer Hydrosilylation of Alkenes

(2013) Antoine Simonneau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

H2Cleavage, Hydride Formation, and Catalytic Hydrogenation of Imines with Zinc Complexes of C5Me5and N-Heterocyclic Carbenes

(2013) Phillip Jochmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Reduction of Amides to Amines by Boronic Acid Catalyzed Hydrosilylation

(2013) Yuehui Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile and efficient KOH-catalysed reduction of esters and tertiary amides

(2013) José A. Fernández-Salas et al.   CHEMICAL COMMUNICATIONS

Hydrogen activation with perfluorinated organoboranes: 1,2,3-tris(pentafluorophenyl)-4,5,6,7-tetrafluoro-1-boraindene

(2013) Adrian Y. Houghton et al.   CHEMICAL COMMUNICATIONS

Zinc-catalyzed Reduction of Aldehydes with a Hydrosilane Leading to Symmetric Ethers and Silyl Ethers

(2013) Norio Sakai et al.   CHEMISTRY LETTERS

Magnesium Catalysis of Imine Hydroboration

(2013) Merle Arrowsmith et al.   CHEMISTRY-A EUROPEAN JOURNAL

Base-Catalyzed Hydrosilylation of Ketones and Esters and Insight into the Mechanism

(2013) Kseniya Revunova et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organophosphorus Catalysis to Bypass Phosphine Oxide Waste

(2013) Henri A. van Kalkeren et al.   ChemSusChem

Metal-Free Borane-Catalyzed Highly Stereoselective Hydrogenation of Pyridines

(2013) Yongbing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Theoretical Study of Reactivity of Ge(II)-hydride Compound: Comparison with Rh(I)-Hydride Complex and Prediction of Full Catalytic Cycle by Ge(II)-hydride

(2013) Nozomi Takagi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity Models of Hydrogen Activation by Frustrated Lewis Pairs: Synergistic Electron Transfers or Polarization by Electric Field?

(2013) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

TBAF-catalyzed hydrosilylation for the reduction of aromatic nitriles

(2013) Christoph Bornschein et al.   NEW JOURNAL OF CHEMISTRY

Selective Reduction of Carboxylic Acids to Aldehydes Catalyzed by B(C6F5)3

(2013) David Bézier et al.   ORGANIC LETTERS

Metal-Free Hydrogenation of N-Based Heterocycles

(2013) Tayseer Mahdi et al.   ORGANOMETALLICS

Cesium Carbonate-Catalyzed Reduction of Amides with Hydrosilanes

(2013) Weilong Xie et al.   ORGANOMETALLICS

Lewis-base silane activation: from reductive cleavage of aryl ethers to selective ortho-silylation

(2013) Alexey Fedorov et al.   Chemical Science

CO2 as a C1-building block for the catalytic methylation of amines

(2013) Olivier Jacquet et al.   Chemical Science

Magnesium-catalyzed hydroboration of esters: evidence for a new zwitterionic mechanism

(2013) Debabrata Mukherjee et al.   Chemical Science

Unexpected Role of Zinc Hydride in Catalytic Hydrosilylation of Ketones and Nitriles

(2013) Courtney Boone et al.   ACS Catalysis

Rise of the Zinc Age in Homogeneous Catalysis?

(2013) Stephan Enthaler   ACS Catalysis

Computational Evidence for a New Type of η2-H2 Complex: When Main-Group Elements Act in Concert To Emulate Transition Metals

(2012) László Könczöl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cationic Calcium Hydride Cluster Stabilized by Cyclen-Derived Macrocyclic N,N,N,N Ligands

(2012) Phillip Jochmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Deoxygenative Reduction of Carbon Dioxide to Methane, Toluene, and Diphenylmethane with [Et2Al]+ as Catalyst

(2012) Manish Khandelwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Zinc-Catalyzed Deoxygenation of Sulfoxides to Sulfides Applying [B(Pin)]2 as Deoxygenation Reagents

(2012) Stephan Enthaler   CATALYSIS LETTERS

Deoxygenation of Sulfoxides to Sulfides in the Presence of Zinc Catalysts and Boranes as Reducing Reagents

(2012) Stephan Enthaler et al.   CATALYSIS LETTERS

Synthesis of allylic and homoallylic alcohols from unsaturated cyclic ethers using a mild and selective C–O reduction approach

(2012) Daniel J. Mack et al.   CHEMICAL COMMUNICATIONS

Molecular early main group metal hydrides: synthetic challenge, structures and applications

(2012) Sjoerd Harder   CHEMICAL COMMUNICATIONS

Magnesium-catalysed hydroboration of aldehydes and ketones

(2012) Merle Arrowsmith et al.   CHEMICAL COMMUNICATIONS

Enantioselective Hydrosilylation with Chiral Frustrated Lewis Pairs

(2012) Dianjun Chen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Illuminating the Mechanism of the Borane-Catalyzed Hydrosilylation of Imines with Both an Axially Chiral Borane and Silane

(2012) Marius Mewald et al.   CHEMISTRY-A EUROPEAN JOURNAL

Towards a Zinc-Catalyzed Asymmetric Hydrogenation/Transfer Hydrogenation of Imines

(2012) Svenja Werkmeister et al.   Chemistry-An Asian Journal

Non-Redox-Metal-Catalyzed Redox Reactions: Zinc Catalysts

(2012) Xiao-Feng Wu   Chemistry-An Asian Journal

Development of New Hydrogenations of Imines and Benign Reductive Hydroaminations: Zinc Triflate as a Catalyst

(2012) Svenja Werkmeister et al.   ChemSusChem

One-Pot Sequential Synthesis of Ethers from an Aliphatic Carboxylic Acid and an Alcohol by Indium-Catalyzed Deoxygenation of an Ester

(2012) Norio Sakai et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Mechanism and Enantioselectivity of [Zinc(diamine)(diol)]-Catalyzed Asymmetric Hydrosilylation of Ketones: DFT, NMR and ECD Studies

(2012) Jadwiga Gajewy et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 3-Substituted Tetrahydrofuran and 4-Substituted Tetrahydropyran Derivatives by Cyclization of Dicarboxylic Acids with InBr3/TMDS

(2012) Leyla Pehlivan et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Metal-Free Aromatic Hydrogenation: Aniline to Cyclohexyl-amine Derivatives

(2012) Tayseer Mahdi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zinc Catalysts for On-Demand Hydrogen Generation and Carbon Dioxide Functionalization

(2012) Wesley Sattler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Activation of H–H and Si–H Bonds by Boranes

(2012) Georgii I. Nikonov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Chemoselective Metal-Free Reduction of Phosphine Oxides to Phosphines

(2012) Yuehui Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main Group Redox Catalysis: Reversible PIII/PV Redox Cycling at a Phosphorus Platform

(2012) Nicole L. Dunn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Hydrogen and Hydrogenation Catalysis by a Borenium Cation

(2012) Jeffrey M. Farrell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recycling of Carbon and Silicon Wastes: Room Temperature Formylation of N–H Bonds Using Carbon Dioxide and Polymethylhydrosiloxane

(2012) Olivier Jacquet et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric hydrosilylation of ketones catalyzed by complexes formed from trans-diaminocyclohexane-based diamines and diethylzinc

(2012) Jadwiga Gajewy et al.   MONATSHEFTE FUR CHEMIE

Bonsai phosphorus

(2012) Emma E. Coyle et al.   Nature Chemistry

“Frustrated Lewis pair” hydrogenations

(2012) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

Single-Step Thioetherification by Indium-Catalyzed Reductive Coupling of Carboxylic Acids with Thiols

(2012) Norio Sakai et al.   ORGANIC LETTERS

Indium-Catalyzed Reductive Bromination of Carboxylic Acids Leading to Alkyl Bromides

(2012) Toshimitsu Moriya et al.   ORGANIC LETTERS

Reduction of phosphine oxides to phosphines with the InBr3/TMDS system

(2012) Leyla Pehlivan et al.   TETRAHEDRON

Interaction of Multiple Bonded and Unsaturated Heavier Main Group Compounds with Hydrogen, Ammonia, Olefins, and Related Molecules

(2011) Philip P. Power   ACCOUNTS OF CHEMICAL RESEARCH

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Indium-Catalyzed Reductive Esterification of a Carboxylic Acid: Sequential Preparation of an Ester and Symmetrical Ether

(2011) Norio Sakai et al.   ADVANCED SYNTHESIS & CATALYSIS

Heterolytic Cleavage of Dihydrogen by “Frustrated Lewis Pairs” Comprising Bis(2,4,6-tris(trifluoromethyl)phenyl)borane and Amines: Stepwise versus Concerted Mechanism

(2011) Zhenpin Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Diagonal Approach to Chemical Recycling of Carbon Dioxide: Organocatalytic Transformation for the Reductive Functionalization of CO2

(2011) Christophe Das Neves Gomes et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free diastereoselective catalytic hydrogenations of imines using B(C6F5)3

(2011) Zachariah M. Heiden et al.   CHEMICAL COMMUNICATIONS

Reactions of heavier main-group compounds with hydrogen, ammonia, ethylene and related small molecules

(2011) Philip P. Power   CHEMICAL RECORD

N-Heterocyclic Carbene-Catalyzed Hydrosilylation of Styryl and Propargylic Alcohols with Dihydrosilanes

(2011) Qiwu Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Zinc-Catalyzed Chemoselective Reduction of Tertiary and Secondary Amides to Amines

(2011) Shoubhik Das et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triflic Acid Catalyzed Reductive Coupling Reactions of Carbonyl Compounds with O-, S-, and N-Nucleophiles

(2011) Beate A. Gellert et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Axially Chiral, Electron-Deficient Borane: Synthesis, Coordination Chemistry, Lewis Acidity, and Reactivity

(2011) Marius Mewald et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Hydrogenation with Frustrated Lewis Pairs: Selectivity Achieved by Size-Exclusion Design of Lewis Acids

(2011) Gábor Erős et al.   CHEMISTRY-A EUROPEAN JOURNAL

Zinc-Catalyzed Chemoselective Reduction of Esters to Alcohols

(2011) Shoubhik Das et al.   CHEMISTRY-A EUROPEAN JOURNAL

In Situ Phosphine Oxide Reduction: A Catalytic Appel Reaction

(2011) Henri A. van Kalkeren et al.   CHEMISTRY-A EUROPEAN JOURNAL

InBr3-Catalyzed Deoxygenation of Carboxylic Acids with a Hydrosilane: Reductive Conversion of Aliphatic or Aromatic Carboxylic Acids to Primary Alcohols or Diphenylmethanes

(2011) Norio Sakai et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Cationic Ethylzinc Compound: A Benzene Complex with Catalytic Activity in Hydroamination and Hydrosilylation Reactions

(2011) Rudolf J. Wehmschulte et al.   INORGANIC CHEMISTRY

Mechanistic Aspects of Bond Activation with Perfluoroarylboranes

(2011) Warren E. Piers et al.   INORGANIC CHEMISTRY

Metal-Free Catalytic Hydrogenation of Polar Substrates by Frustrated Lewis Pairs

(2011) Douglas W. Stephan et al.   INORGANIC CHEMISTRY

Calcium-mediated hydroboration of alkenes: “Trojan horse” or “true” catalysis?

(2011) Sjoerd Harder et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Nonhydride Mechanism of Metal-Catalyzed Hydrosilylation

(2011) Oleg G. Shirobokov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, Structure, and Reactivity of a Mononuclear Organozinc Hydride Complex: Facile Insertion of CO2into a Zn–H Bond and CO2-Promoted Displacement of Siloxide Ligands

(2011) Wesley Sattler et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Convenient, enantioselective hydrosilylation of imines in protic media catalyzed by a Zn-trianglamine complex

(2011) Jadwiga Gajewy et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Magnesium-Catalyzed Hydroboration of Pyridines

(2011) Merle Arrowsmith et al.   ORGANOMETALLICS

Controlled Hydrosilylation of Carbonyls and Imines Catalyzed by a Cationic Aluminum Alkyl Complex

(2011) Jürgen Koller et al.   ORGANOMETALLICS

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

Metal-Free Transfer Hydrogenation Catalysis by B(C6F5)3

(2011) Jeffrey M. Farrell et al.   ORGANOMETALLICS

InBr3-catalyzed reduction of ketones with a hydrosilane: deoxygenation of aromatic ketones and selective synthesis of secondary alcohols and symmetrical ethers from aliphatic ketones

(2011) Norio Sakai et al.   TETRAHEDRON LETTERS

A straightforward zinc-catalysed reduction of sulfoxides to sulfides

(2011) Stephan Enthaler   Catalysis Science & Technology

Enantioselective Hydrogenation with Chiral Frustrated Lewis Pairs

(2010) Dianjun Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Mechanism of Dihydrogen Activation by Frustrated Lewis Pairs Revisited

(2010) Stefan Grimme et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Practical One-Pot Synthesis of Secondary Amines by Zinc-Catalyzed Reductive Amination

(2010) Stephan Enthaler   CATALYSIS LETTERS

Gallium(III) Triflate Catalyzed Direct Reductive Amination of Aldehydes

(2010) G. K. Surya Prakash et al.   CATALYSIS LETTERS

High Efficiency in Catalytic Hydrosilylation of Ketones with Zinc-Based Precatalysts Featuring Hard and Soft Tridentate O,S,O-Ligands

(2010) Nicolas A. Marinos et al.   ChemCatChem

Metal-free reductions of N-heterocycles via Lewis acid catalyzed hydrogenation

(2010) Stephen J. Geier et al.   CHEMICAL COMMUNICATIONS

The synthesis of chiral N-heterocyclic carbene–borane and –diorganoborane complexes and their use in the asymmetric reduction of ketones

(2010) David M. Lindsay et al.   CHEMICAL COMMUNICATIONS

Activation of dihydrogen by non-metal systems

(2010) Douglas W. Stephan   CHEMICAL COMMUNICATIONS

From Limestone to Catalysis: Application of Calcium Compounds as Homogeneous Catalysts

(2010) Sjoerd Harder   CHEMICAL REVIEWS

N-Heterocyclic Carbene Mediated Activation of Tetravalent Silicon Compounds: A Critical Evaluation

(2010) Matthew J. Fuchter   CHEMISTRY-A EUROPEAN JOURNAL

Facile and Efficient Reduction of Ketones in the Presence of Zinc Catalysts Modified by Phenol Ligands

(2010) Stephan Enthaler et al.   Chemistry-An Asian Journal

Hydrosilylation of Ketones: From Metal-Organic Frameworks to Simple Base Catalysts

(2010) Daniele Addis et al.   Chemistry-An Asian Journal

Magnesium hydride-promoted dearomatisation of pyridine

(2010) Michael S. Hill et al.   DALTON TRANSACTIONS

First-row transition metal catalyzed reduction of carbonyl functionalities: a mechanistic perspective

(2010) Sumit Chakraborty et al.   DALTON TRANSACTIONS

Formamidines - Versatile Ligands for Zinc-Catalyzed Hydrosilylation and Iron-Catalyzed Epoxidation Reactions

(2010) Stephan Enthaler et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Zinc-Catalyzed Reduction of Amides: Unprecedented Selectivity and Functional Group Tolerance

(2010) Shoubhik Das et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

(2010) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Catalytic Role of N-Heterocyclic Carbene in a Metal-Free Conversion of Carbon Dioxide into Methanol: A Computational Mechanism Study

(2010) Fang Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dihydrogen Activation by Antiaromatic Pentaarylboroles

(2010) Cheng Fan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Stereoselective synthesis of ring C-hexasubstituted trianglamines

(2010) Diego Savoia et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

B(C6F5)3-Promoted Tandem Silylation and Intramolecular Hydrosilylation: Diastereoselective Synthesis of Oxasilinanes and Oxasilepanes

(2010) Roman Shchepin et al.   ORGANIC LETTERS

Heterofunctionalization catalysis with organometallic complexes of calcium, strontium and barium

(2010) A. G. M. Barrett et al.   PROCEEDINGS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES

Convenient Enantioselective Hydrosilylation of Ketones Catalyzed by Zinc-Macrocyclic Oligoamine Complexes

(2009) Jadwiga Gajewy et al.   ADVANCED SYNTHESIS & CATALYSIS

Hydrosilylation of Ketone and Imine over Poly-N-Heterocyclic Carbene Particles

(2009) MeiXuan Tan et al.   ADVANCED SYNTHESIS & CATALYSIS

Conversion of Carbon Dioxide into Methanol with Silanes over N-Heterocyclic Carbene Catalysts

(2009) Siti Nurhanna Riduan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions of Tin(II) Hydride Species with Unsaturated Molecules

(2009) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free hydrogen activation and hydrogenation of imines by 1,8-bis(dipentafluorophenylboryl)naphthalene

(2009) Chunfang Jiang et al.   CHEMICAL COMMUNICATIONS

THE FUTURE OF MAIN GROUP CHEMISTRY

(2009) Tristram Chivers et al.   COMMENTS ON INORGANIC CHEMISTRY

Reactivity of germanium(II) hydride with nitrous oxide, trimethylsilyl azide, ketones, and alkynes and the reaction of a methyl analogue with trimethylsilyl diazomethane

(2009) Anukul Jana et al.   DALTON TRANSACTIONS

B(C6F5)3-Catalyzed Reduction of Ketones and Imines Using Silicon-Stereogenic Silanes: Stereoinduction by Single-Point Binding

(2009) Daniel T. Hog et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A Novel Approach to the Practical Synthesis of Sulfides: An InBr3-Et3SiH Catalytic System Promoted the Direct Reductive Sulfidation of Acetals with Disulfides

(2009) Norio Sakai et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Influence of Lewis Acid and Solvent in the Hydrosilylation of Aldehydes and Ketones with Et3SiH; Tris(pentafluorophenyl)borane B(C6F5)3 versus Metal Triflates [M(OTf)3; M = Sc, Bi, Ga, and Al] - Mechanistic Implications

(2009) Peter Bach et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Hydrostannylation of Ketones and Alkynes with LSnH [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3]

(2009) Anukul Jana et al.   INORGANIC CHEMISTRY

A Germanium(II) Hydride as an Effective Reagent for Hydrogermylation Reactions

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrogenation of Sensitive Organometallic Compounds by Antagonistic N/B Lewis Pair Catalyst Systems

(2009) Kirill V. Axenov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

On the Mechanism of B(C6F5)3-Catalyzed Direct Hydrogenation of Imines: Inherent and Thermally Induced Frustration

(2009) Tibor András Rokob et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Benzo[b]siloles via KH-Promoted Cyclization of (2-Alkynylphenyl)silanes

(2009) Laurean Ilies et al.   ORGANIC LETTERS

Secondary Amine Formation from Reductive Amination of Carbonyl Compounds Promoted by Lewis Acid Using the InCl3/Et3SiH System

(2009) On-Yi Lee et al.   ORGANIC LETTERS

Metal-Free Hydrogen Activation by the Frustrated Lewis Pairs of ClB(C6F5)2and HB(C6F5)2and Bulky Lewis Bases

(2009) Chunfang Jiang et al.   ORGANOMETALLICS

Polymethylhydrosiloxane (PMHS)/trifluoroacetic acid (TFA): a novel system for reductive amination reactions

(2009) Jay P. Patel et al.   TETRAHEDRON LETTERS

The reductive etherification of carbonyl compounds using polymethylhydrosiloxane activated by molecular iodine

(2009) J.S. Yadav et al.   TETRAHEDRON LETTERS

Recent Developments in the Organic Chemistry of Calcium - An Element with Unlimited Possibilities in Organometallic Chemistry?

(2009) Matthias Westerhausen   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Conclusive Evidence for an SN2-Si Mechanism in the B(C6F5)3-Catalyzed Hydrosilylation of Carbonyl Compounds: Implications for the Related Hydrogenation

(2008) Sebastian Rendler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Turning Frustration into Bond Activation: A Theoretical Mechanistic Study on Heterolytic Hydrogen Splitting by Frustrated Lewis Pairs

(2008) Tibor András Rokob et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogen and Amine Activation by a Frustrated Lewis Pair of a Bulky N-Heterocyclic Carbene and B(C6F5)3

(2008) Preston A. Chase et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Catalytic Hydrogenation of Enamines, Imines, and Conjugated Phosphinoalkenylboranes

(2008) Patrick Spies et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Early Main-Group Metal Catalysts for the Hydrogenation of Alkenes with H2

(2008) Jan Spielmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperating Ligands in Catalysis

(2008) Hansjörg Grützmacher   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-free catalytic hydrogenation of imines with tris(perfluorophenyl)borane

(2008) Dianjun Chen et al.   CHEMICAL COMMUNICATIONS

Reduction of Ketones with Hydrocarbon-Soluble Calcium Hydride: Stoichiometric Reactions and Catalytic Hydrosilylation

(2008) Jan Spielmann et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Highly Chemoselective Reductive Amination of Carbonyl Compounds Promoted by InCl3/Et3SiH/MeOH System

(2008) On-Yi Lee et al.   JOURNAL OF ORGANIC CHEMISTRY

Molecular Tweezers for Hydrogen: Synthesis, Characterization, and Reactivity

(2008) Victor Sumerin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Frustrated Lewis pairs”: a concept for new reactivity and catalysis

(2008) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

Direct Reduction of Esters to Ethers with an Indium(III) Bromide/Triethylsilane Catalytic System

(2008) Norio Sakai et al.   SYNTHESIS-STUTTGART

One-step conversion to tertiary amines: InBr3/Et3SiH-mediated reductive deoxygenation of tertiary amides

(2008) Norio Sakai et al.   TETRAHEDRON LETTERS

Rapid Assembly of Complex 3D Siloxane Architectures

(2007) David B. Thompson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY