Reversible Silylene Insertion Reactions into Si−H and P−H σ-Bonds at Room Temperature

Enabling and Probing Oxidative Addition and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E–H Bonds by a Bis(boryl)stannylene

(2016) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Insertion of a Cationic Metallogermylene into E–H Bonds (E = H, B, Si)

(2015) Koya Inomata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Insertion of Unactivated Alkenes into Silicon(II)-Tin Bonds

(2013) Ricardo Rodriguez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Generic One-Pot Route to Acyclic Two-Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene

(2012) Andrey V. Protchenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of a Phosphine-Stabilized Silicon(II) Hydride and Its Addition to Olefins: A Catalyst-Free Hydrosilylation Reaction

(2011) Ricardo Rodriguez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible Binding of Ethylene to Silylene-Phosphine Complexes at Room Temperature

(2011) Ricardo Rodriguez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

(2010) Guido D. Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nucleophilic Silylenoid Character of Stable Phosphonium Sila-ylides

(2010) David Gau et al.   CHEMISTRY-A EUROPEAN JOURNAL

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination

(2009) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diarylstannylene Activation of Hydrogen or Ammonia with Arene Elimination

(2008) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible, Metal-Free, Heterolytic Activation of H2at Room Temperature

(2008) Matthias Ullrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY