CN Bond Cleavage and Ring Expansion of N-Heterocyclic Carbenes using Hydrosilanes

The Parent Borylene: Betwixt and Between

(2012) Dennis P. Curran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beryllium-Induced CN Bond Activation and Ring Opening of an N-Heterocyclic Carbene

(2012) Merle Arrowsmith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Formation of Cyclometallated N-Heterocyclic Carbene (NHC) Complexes from LnRuCl2 (L = Cyclooctadiene, PPh3, DMSO) Precursors

(2012) Nicola Bramananthan et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Decisive Steps of the Hydrodefluorination of Fluoroaromatics using [Ni(NHC)2]

(2012) Peter Fischer et al.   ORGANOMETALLICS

Yes They Can: Small-molecule Activation with Stable Diaminocarbenes

(2011) Ulrich Siemeling   AUSTRALIAN JOURNAL OF CHEMISTRY

Si–H Activation of hydrosilanes leading to hydrido silyl and bis(silyl) nickel complexes

(2011) Thomas Zell et al.   DALTON TRANSACTIONS

Carbene-stabilized main group diatomic allotropes

(2011) Yuzhong Wang et al.   DALTON TRANSACTIONS

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Dihydrogen Activation by Frustrated Carbene-Borane Lewis Pairs: An Experimental and Theoretical Study of Carbene Variation

(2011) Sabrina Kronig et al.   INORGANIC CHEMISTRY

Synthesis, Structure, and Reactivity of Organo-Iron(II) Complexes with N-Heterocyclic Carbene Ligation

(2011) Li Xiang et al.   ORGANOMETALLICS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Silicon Triple Bonds: The Molybdenum Silylidyne Complex [Cp(CO)2Mo≡Si-R]

(2010) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

(2010) Guido D. Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of dihydrogen by non-metal systems

(2010) Douglas W. Stephan   CHEMICAL COMMUNICATIONS

Neutral and Cationic Hydridoruthenium Tetrakiscarbene Complexes

(2010) Robert Wolf et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and Characterization of Tetrakis(carbene)ruthenium(II) Complexes Featuring an [Ru(NHC)4]2+ Core

(2010) Max Würtemberger et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Triple Alkyl C-H Bond Activation Mediated by Ruthenium(II): Preparation of Isopropenyl-Substituted Carbene Complexes

(2010) Robert Wolf et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

AnN-Heterocyclic Carbene−Disilyne Complex and Its Reactivity toward ZnCl2

(2010) Torahiko Yamaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Experimental and Computational Investigation of C−N Bond Activation in Ruthenium N-Heterocyclic Carbene Complexes

(2010) L. Jonas L. Häller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature

(2010) Yun Xiong et al.   Nature Chemistry

The Zirconium Benzyl Mediated C−N Bond Cleavage of an Amino-Linked N-Heterocyclic Carbene

(2010) Yu-Cheng Hu et al.   ORGANOMETALLICS

Carbene-Stabilized Parent Phosphinidene†

(2010) Yuzhong Wang et al.   ORGANOMETALLICS

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

SiBr2(Idipp): A Stable N-Heterocyclic Carbene Adduct of Dibromosilylene

(2009) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Nonmetal-Mediated Fragmentation of P4: Isolation of P1and P2Bis(carbene) Adducts

(2009) Olivier Back et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unique homonuclear multiple bonding in main group compounds

(2009) Yuzhong Wang et al.   CHEMICAL COMMUNICATIONS

Template-controlled synthesis of a planar [16]ane-P2CNHC2macrocycle

(2009) Aarón Flores-Figueroa et al.   CHEMICAL COMMUNICATIONS

Stable Noncyclic Singlet Carbenes

(2009) Joan Vignolle et al.   CHEMICAL REVIEWS

Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications

(2009) Macarena Poyatos et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene (NHC)-Stabilized Silanechalcogenones: NHC→Si(R2)E (E=O, S, Se, Te)

(2009) Shenglai Yao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbene Stabilization of Diarsenic: From Hypervalency to Allotropy

(2009) Mariham Y. Abraham et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ambiphilicity of Dichlorosilylene in a Single Molecule

(2009) Rajendra S. Ghadwal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Facile C–S, S–H, and S–S bond cleavage using a nickel(0) NHC complex

(2009) Thomas Schaub et al.   DALTON TRANSACTIONS

Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

(2009) Douglas W. Stephan   DALTON TRANSACTIONS

Dehydrogenation reactivity of a frustrated carbene–borane Lewis pair

(2009) Dirk Holschumacher et al.   DALTON TRANSACTIONS

Elimination of an Alkyl Group from Imidazolium Salts: Imidazole-Coordinated Dinuclear Monodentate NHC-Palladium Complexes Driven by Self-Assembly and Their Application in the Heck Reaction

(2009) Lian-jun Liu et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Ligand-Promoted Carbene Insertion into the Aryl Substituent of anN-Heterocyclic Carbene Ligand in Ruthenium-Based Metathesis Catalysts

(2009) Brandon R. Galan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Neutral Ga6Octahedron: Synthesis, Structure, and Aromaticity

(2009) Brandon Quillian et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Isolable NHC-Supported Silanone

(2009) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dehydrochlorination to Silylenes by N-Heterocyclic Carbenes

(2009) Haiyan Cui et al.   ORGANOMETALLICS

Facile C−N Bond Cleavage Promoted by Cuprous Oxide: Formation of C−C-Coupled Biimidazole from Its Methylene-Bridged Congener

(2009) Shahulhameed Sabiah et al.   ORGANOMETALLICS

Heterolytic Dihydrogen Activation by a Frustrated Carbene-Borane Lewis Pair

(2008) Dirk Holschumacher et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bonding capabilities of imidazol-2-ylidene ligands in group-10 transition-metal chemistry

(2008) Udo Radius et al.   COORDINATION CHEMISTRY REVIEWS

Planar, Twisted, and Trans-Bent:  Conformational Flexibility of Neutral Diborenes

(2008) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Active Trifluoromethylating Agents from Well-Defined Copper(I)−CF3Complexes

(2008) Galyna G. Dubinina et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbene-Stabilized Diphosphorus

(2008) Yuzhong Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−F Activation of Fluorinated Arenes using NHC-Stabilized Nickel(0) Complexes: Selectivity and Mechanistic Investigations

(2008) Thomas Schaub et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C−H Bond Activation of Heteroarenes Mediated by a Half-Sandwich Iron Complex of N-Heterocyclic Carbene

(2008) Yasuhiro Ohki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal Template Controlled Formation of [11]ane-P2CNHCMacrocycles

(2008) Oliver Kaufhold et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Frustrated Lewis pairs”: a concept for new reactivity and catalysis

(2008) Douglas W. Stephan   ORGANIC & BIOMOLECULAR CHEMISTRY

NHC Complexes of Osmium Clusters: A Structural and Reactivity Study

(2008) Craig E. Cooke et al.   ORGANOMETALLICS

Dinuclear Palladacyclic Complexes Derived from C−N Cleavage of an Imidazolium Salt: Synthesis, Structural Characterization, and Their Uses for C−C Coupling

(2008) Jiansheng Ye et al.   ORGANOMETALLICS

Bonding of Imidazol-2-ylidene Ligands in Nickel Complexes

(2008) Udo Radius et al.   ORGANOMETALLICS

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE

Heterolytic H2 Activation by Nonmetals

(2007) Alyson L. Kenward et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION