Reaction of an N-Heterocyclic Carbene-Stabilized Silicon(II) Monohydride with Alkynes: [2+2+1] Cycloaddition versus Hydrogen Abstraction

A facile access to a novel NHC-stabilized silyliumylidene ion and C–H activation of phenylacetylene

(2014) Syed Usman Ahmad et al.   CHEMICAL COMMUNICATIONS

New Route to Access an Acyl-Functionalized Phosphasilene and a Four-Membered Si-P-C-O Heterocycle

(2014) Nora C. Breit et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Donor-Stabilized Zwitterionic “Half-Parent” Phosphasilene and Its Unusual Reactivity towards Small Molecules

(2014) Kerstin Hansen et al.   CHEMISTRY-A EUROPEAN JOURNAL

[2+2+1] Cycloadditions of Bis(dialkylamino)acetylenes with SiI2(Idip): Syntheses and Reactivity Studies of Unprecedented 2,3,4,5-Tetraamino-1 H-siloles

(2014) Yury N. Lebedev et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molecular tailoring: a possible synthetic route to hexasilabenzene

(2013) Zsolt Benedek et al.   DALTON TRANSACTIONS

From a Zwitterionic Phosphasilene to Base Stabilized Silyliumylidene-Phosphide and Bis(silylene) Complexes

(2013) Nora C. Breit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Fragile Zwitterionic Phosphasilene as a Transfer Agent of the Elusive Parent Phosphinidene (:PH)

(2013) Kerstin Hansen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Dihydrodisilene Transition Metal Complex from an N-Heterocyclic Carbene-Stabilized Silylene Monohydride

(2013) Shigeyoshi Inoue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of an Isolable Base-Stabilized Silacycloprop-1-ylidene

(2012) Ricardo Rodriguez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Molecular Tailoring: Reaction Path Control with Bulky Substituents

(2012) Tibor Szilvási et al.   ORGANOMETALLICS

Hydrosilylation of Alkynes by Ni(CO)3-Stabilized Silicon(II) Hydride

(2011) Miriam Stoelzel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of a Phosphine-Stabilized Silicon(II) Hydride and Its Addition to Olefins: A Catalyst-Free Hydrosilylation Reaction

(2011) Ricardo Rodriguez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addition of a stable dialkylsilylene to carbon-carbon unsaturated bonds

(2011) Shintaro Ishida et al.   HETEROATOM CHEMISTRY

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

Synthesis, structure, and theoretical investigation of amidinato supported 1,4-disilabenzene

(2010) Sakya S. Sen et al.   CHEMICAL COMMUNICATIONS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Synthesis and Characterization of an Amidinate-Stabilized cis-1,2-Disilylenylethene [cis-LSi{C(Ph)C(H)}SiL] and a Singlet Delocalized Biradicaloid [LSi(μ2-C2Ph2)2SiL]

(2010) Hui-Xian Yeong et al.   CHEMISTRY-A EUROPEAN JOURNAL

High Yield Access to Silylene RSiCl (R = PhC(NtBu)2) and Its Reactivity toward Alkyne: Synthesis of Stable Disilacyclobutene

(2010) Sakya S. Sen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base-Stabilized 1-Silacyclopenta-2,4-dienylidenes

(2010) Yihua Gao et al.   ORGANOMETALLICS

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

Dichotomic Reactivity of a Stable Silylene toward Terminal Alkynes: Facile CH Bond Insertion versus Autocatalytic Formation of Silacycloprop-3-ene

(2008) Shenglai Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION