Catalytic versus stoichiometric dehydrocoupling using main group metals

Tuning the [L2Rh⋯H3B·NR3]+ interaction using phosphine bite angle. Demonstration by the catalytic formation of polyaminoboranes

(2011) Romaeo Dallanegra et al.   CHEMICAL COMMUNICATIONS

Alkylstrontium diamidoboranes: β-hydride elimination and Sr–C insertion

(2011) Peter Bellham et al.   CHEMICAL COMMUNICATIONS

Unprecedented reactivity of an aluminium hydride complex with ArNH2BH3: nucleophilic substitution versus deprotonation

(2011) Sjoerd Harder et al.   CHEMICAL COMMUNICATIONS

Catalytic dehydrocoupling of Me2NHBH3 with Al(NMe2)3

(2011) Hugh J. Cowley et al.   CHEMICAL COMMUNICATIONS

Stoichiometric reactivity of dialkylamine boranes with alkaline earth silylamides

(2011) Michael S. Hill et al.   DALTON TRANSACTIONS

Catalytic dehydrogenation of dimethylamine borane by group 4 metallocene alkyne complexes and homoleptic amido compounds

(2011) Torsten Beweries et al.   DALTON TRANSACTIONS

Regeneration of Ammonia Borane Spent Fuel by Direct Reaction with Hydrazine and Liquid Ammonia

(2011) A. D. Sutton et al.   SCIENCE

Group 13 BN dehydrocoupling reagents, similar to transition metal catalysts but with unique reactivity

(2011) Max M. Hansmann et al.   Chemical Science

Calcium-centred phosphine oxide reactivity: P–C metathesis, reduction and P–P coupling

(2010) Michael S. Hill et al.   CHEMICAL COMMUNICATIONS

Stoichiometric and catalytic Sn-mediated dehydrocoupling of primary phosphines

(2010) Vesal Naseri et al.   CHEMICAL COMMUNICATIONS

Group 3-centred dehydrocoupling of Me2NH·BH3

(2010) Michael S. Hill et al.   CHEMICAL COMMUNICATIONS

Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules

(2010) Anne Staubitz et al.   CHEMICAL REVIEWS

Thermal Decomposition of Mono- and Bimetallic Magnesium Amidoborane Complexes

(2010) Jan Spielmann et al.   CHEMISTRY-A EUROPEAN JOURNAL

Group 2 Promoted Hydrogen Release from NMe2H⋅BH3: Intermediates and Catalysis

(2010) David J. Liptrot et al.   CHEMISTRY-A EUROPEAN JOURNAL

Formation and Rearrangement of SnII Phosphanediide Cages

(2010) Mary McPartlin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Dehydrocoupling/Dehydrogenation of N-Methylamine-Borane and Ammonia-Borane: Synthesis and Characterization of High Molecular Weight Polyaminoboranes

(2010) Anne Staubitz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Bis(σ-amine-borane) Complexes: An Unusual Binding Mode at a Transition-Metal Center

(2009) Romaeo Dallanegra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Convenient synthesis and crystal structure of a monomeric zinc hydride complex with a three-coordinate metal center

(2009) Jan Spielmann et al.   CHEMICAL COMMUNICATIONS

Recent perspectives on main group-mediated dehydrocoupling of P–P bonds

(2009) Robert J. Less et al.   CHEMICAL COMMUNICATIONS

Synthesis and structure of a magnesium–amidoborane complex and its role in catalytic formation of a new bis-aminoborane ligand

(2009) Jan Spielmann et al.   CHEMICAL COMMUNICATIONS

Hydrogen Elimination in Bulky Calcium Amidoborane Complexes: Isolation of a Calcium Borylamide Complex

(2009) Jan Spielmann et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Hydroamination of Aminoalkenes by Calcium and Magnesium Complexes: A Synthetic and Mechanistic Study

(2009) Mark R. Crimmin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Calcium Amidoborane Hydrogen Storage Materials: Crystal Structures of Decomposition Products

(2008) Jan Spielmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Dehydrocoupling of Primary Amine-Borane Adducts: A Route to High Molecular Weight Polyaminoboranes, Boron-Nitrogen Analogues of Polyolefins

(2008) Anne Staubitz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Early Main-Group Metal Catalysts for the Hydrogenation of Alkenes with H2

(2008) Jan Spielmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stoichiometric and catalytic activation of P–H and P–P bonds

(2008) Sharonna Greenberg et al.   CHEMICAL SOCIETY REVIEWS

B–N compounds for chemical hydrogenstorage

(2008) Charles W. Hamilton et al.   CHEMICAL SOCIETY REVIEWS

Dehydrogenative Bond-Forming Catalysis Involving Phosphines

(2008) Rory Waterman   CURRENT ORGANIC CHEMISTRY

Reduction of Ketones with Hydrocarbon-Soluble Calcium Hydride: Stoichiometric Reactions and Catalytic Hydrosilylation

(2008) Jan Spielmann et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

σ-Borane Complexes of Iridium: Synthesis and Structural Characterization

(2008) Travis J. Hebden et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Amine-Borane σ-Complexes of Rhodium. Relevance to the Catalytic Dehydrogenation of Amine-Boranes

(2008) Thomas M. Douglas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY