Stabilization of a two-coordinate, acyclic diaminosilylene (ADASi): completion of the series of isolable diaminotetrylenes, :E(NR2)2 (E = group 14 element)

Reactivity of an Acyclic Silylsilylene toward Ethylene: Migratory Insertion into the Si–Si Bond

(2015) Daniel Wendel et al.   ORGANOMETALLICS

A singly bonded amido-distannyne: H2 activation and isocyanide coordination

(2014) Terrance J. Hadlington et al.   CHEMICAL COMMUNICATIONS

Highly Electron-Rich Pincer-Type Iron Complexes Bearing Innocent Bis(metallylene)pyridine Ligands: Syntheses, Structures, and Catalytic Activity

(2014) Daniel Gallego et al.   ORGANOMETALLICS

Elucidation of Carbene Ambiphilicity Leading to the Discovery of Reversible Ammonia Activation

(2013) Jonathan P. Moerdyk et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dispersion Forces and Counterintuitive Steric Effects in Main Group Molecules: Heavier Group 14 (Si–Pb) Dichalcogenolate Carbene Analogues with Sub-90° Interligand Bond Angles

(2013) Brian D. Rekken et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Complexation of Ethylene by a Silylene under Ambient Conditions

(2013) Felicitas Lips et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interconnected Bis-Silylenes: A New Dimension in Organosilicon Chemistry

(2012) Sakya S. Sen et al.   ACCOUNTS OF CHEMICAL RESEARCH

Bis[N,N′-diisopropylbenzamidinato(−)]silicon(II): A Silicon(II) Compound with Both a Bidentate and a Monodentate Amidinato Ligand

(2012) Konstantin Junold et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Generic One-Pot Route to Acyclic Two-Coordinate Silylenes from Silicon(IV) Precursors: Synthesis and Structural Characterization of a Silylsilylene

(2012) Andrey V. Protchenko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of a Stable, Acyclic, Two-Coordinate Silylene

(2012) Brian D. Rekken et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Utilizing Steric Bulk to Stabilize Molybdenum Aminogermylyne and Aminogermylene Complexes

(2012) Jamie Hicks et al.   ORGANOMETALLICS

Aromatic Ylide-Stabilized Carbocyclic Silylene

(2011) Matthew Asay et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms

(2011) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Extremely bulky amido-group 14 element chloride complexes: Potential synthons for low oxidation state main group chemistry

(2011) Jiaye Li et al.   DALTON TRANSACTIONS

Striking Stability of a Substituted Silicon(II) Bis(trimethylsilyl)amide and the Facile Si–Me Bond Cleavage without a Transition Metal Catalyst

(2011) Sakya S. Sen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Digermyne with a Ge–Ge Single Bond That Activates Dihydrogen in the Solid State

(2011) Jiaye Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

Chemistry of functionalized silylenes

(2011) Sakya S. Sen et al.   Chemical Science

Synthesis of a Stable Disilyne Bisphosphine Adduct and Its Non-Metal-Mediated CO2 Reduction to CO

(2010) David Gau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An isolable dialkylsilylene and its derivatives. A step toward comprehension of heavy unsaturated bonds

(2010) Mitsuo Kira   CHEMICAL COMMUNICATIONS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

N−H Activation of Amines and Ammonia by Ru via Metal−Ligand Cooperation

(2010) Eugene Khaskin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature

(2010) Yun Xiong et al.   Nature Chemistry

SiBr2(Idipp): A Stable N-Heterocyclic Carbene Adduct of Dibromosilylene

(2009) Alexander C. Filippou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

[2,6-(Trip)2H3C6](Cp*)Si: A Stable Monomeric Arylsilicon(II) Compound

(2009) Peter Jutzi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination

(2009) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY