Versatile Conversion ofN-Heterocyclic Silylene to Silyl Metal Compounds by Insertion of Divalent Silicon into Metal-Carbon and Metal-Hydrogen Bonds

Reactions of StableN-Heterocyclic Silylenes with Ketones and 3,5-Di-tert-butyl-o-benzoquinone

(2011) Ramachandran Azhakar et al.   ORGANOMETALLICS

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

Metal-Free Activation of EH3 (E=P, As) by an Ylide-like Silylene and Formation of a Donor-Stabilized Arsasilene with a HSiAsH Subunit

(2010) Carsten Präsang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

A New Entry into Aluminum Chemistry: [L1AlMe]⋅THF, a Versatile Building Block for Bimetallic and Polymetallic Complexes

(2010) Sankaranarayana Pillai Sarish et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis and Rearrangement of Stable NHC→Silylene Adducts and Their Unique Reactivity towards Cyclohexylisocyanide

(2010) Yun Xiong et al.   Chemistry-An Asian Journal

Steering S−H and N−H Bond Activation by a Stable N-Heterocyclic Silylene: Different Addition of H2S, NH3, and Organoamines on a Silicon(II) Ligand versus Its Si(II)→Ni(CO)3Complex

(2010) Antje Meltzer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Aromatic C−F and C−H Bond Activation with Silylenes of Different Coordinate Silicon

(2010) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From silicon(II)-based dioxygen activation to adducts of elusive dioxasiliranes and sila-ureas stable at room temperature

(2010) Yun Xiong et al.   Nature Chemistry

The Striking Stabilization of Ni0(η6-Arene) Complexes by an Ylide-Like Silylene Ligand

(2009) Antje Meltzer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

Synthesis and structural diversity of oligosilanylzinc compounds

(2009) Walter Gaderbauer et al.   DALTON TRANSACTIONS

Diketiminate Silicon(II) and Related NHSi Ligands Generated in the Coordination Sphere of Nickel(0)

(2009) Antje Meltzer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Addition of Ammonia at a Silicon(II) Center and an Unprecedented Hydrogenation Reaction of Compounds with Low-Valent Group 14 Elements Using Ammonia Borane

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reactivity of a Zwitterionic Stable Silylene toward Halosilanes and Haloalkanes

(2009) Yun Xiong et al.   ORGANOMETALLICS

Insertion Reaction of a Silylene into a N−H Bond of Hydrazine and a [1+4] Cycloaddition with Diphenyl Hydrazone§

(2009) Anukul Jana et al.   ORGANOMETALLICS

Dichotomic Reactivity of a Stable Silylene toward Terminal Alkynes: Facile CH Bond Insertion versus Autocatalytic Formation of Silacycloprop-3-ene

(2008) Shenglai Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION