Reactivity of an N-Heterocyclic Carbene Stabilized Hydrosilylene towards a Ketone and CO2: Experimental and Theoretical Study

The reactivity of an NHC-stabilized silicon(II) hydride

(2016) Carsten Eisenhut et al.   PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS

A Persistent 1,2-Dihydrophosphasilene Adduct

(2015) Kerstin Hansen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Facile rotation around a silicon–phosphorus double bond enabled through coordination to tungsten

(2015) Nora C. Breit et al.   CHEMICAL COMMUNICATIONS

From an Isolable Acyclic Phosphinosilylene Adduct to Donor-Stabilized SiE Compounds (E=O, S, Se)

(2015) Kerstin Hansen et al.   CHEMISTRY-A EUROPEAN JOURNAL

Alkaline-Earth-Metal-Induced Liberation of Rare Allotropes of Elemental Silicon and Germanium from N-Heterocyclic Metallylenes

(2015) Burgert Blom et al.   INORGANIC CHEMISTRY

An NHC-Stabilized Silicon Analogue of Acylium Ion: Synthesis, Structure, Reactivity, and Theoretical Studies

(2015) Syed Usman Ahmad et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition Metal Complexes of a “Half-Parent” Phosphasilene Adduct Representing Silylene→Phosphinidene→Metal Complexes

(2015) Kerstin Hansen et al.   ORGANOMETALLICS

Why do N-heterocyclic carbenes and silylenes activate white phosphorus differently?

(2015) Tibor Szilvási et al.   STRUCTURAL CHEMISTRY

Can low-valent silicon compounds be better transition metal ligands than phosphines and NHCs?

(2015) Zsolt Benedek et al.   RSC Advances

Cyclic (Alkyl)(Amino)Carbenes (CAACs): Stable Carbenes on the Rise

(2014) Michèle Soleilhavoup et al.   ACCOUNTS OF CHEMICAL RESEARCH

A facile access to a novel NHC-stabilized silyliumylidene ion and C–H activation of phenylacetylene

(2014) Syed Usman Ahmad et al.   CHEMICAL COMMUNICATIONS

Reaction of an N-Heterocyclic Carbene-Stabilized Silicon(II) Monohydride with Alkynes: [2+2+1] Cycloaddition versus Hydrogen Abstraction

(2014) Carsten Eisenhut et al.   CHEMISTRY-A EUROPEAN JOURNAL

New Route to Access an Acyl-Functionalized Phosphasilene and a Four-Membered Si-P-C-O Heterocycle

(2014) Nora C. Breit et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Donor-Stabilized Zwitterionic “Half-Parent” Phosphasilene and Its Unusual Reactivity towards Small Molecules

(2014) Kerstin Hansen et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Amplified Ylidic “Half-Parent” Iminosilane LSi═NH

(2014) Kerstin Hansen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An overview of N-heterocyclic carbenes

(2014) Matthew N. Hopkinson et al.   NATURE

Reactions of an Isolable Dialkylsilylene with Carbon Dioxide and Related Heterocumulenes

(2014) Xupeng Liu et al.   ORGANOMETALLICS

Solid-State Covalent Capture of CO2by Using N-Heterocyclic Carbenes

(2013) Monika Vogt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Computational and experimental investigations of CO2and N2O fixation by sterically demanding N-heterocyclic carbenes (NHC) and NHC/borane FLP systems

(2013) Eileen Theuergarten et al.   DALTON TRANSACTIONS

Molecular tailoring: a possible synthetic route to hexasilabenzene

(2013) Zsolt Benedek et al.   DALTON TRANSACTIONS

From a Zwitterionic Phosphasilene to Base Stabilized Silyliumylidene-Phosphide and Bis(silylene) Complexes

(2013) Nora C. Breit et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Fragile Zwitterionic Phosphasilene as a Transfer Agent of the Elusive Parent Phosphinidene (:PH)

(2013) Kerstin Hansen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Dihydrodisilene Transition Metal Complex from an N-Heterocyclic Carbene-Stabilized Silylene Monohydride

(2013) Shigeyoshi Inoue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron-Rich N-Heterocyclic Silylene (NHSi)–Iron Complexes: Synthesis, Structures, and Catalytic Ability of an Isolable Hydridosilylene–Iron Complex

(2013) Burgert Blom et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Carbene-stabilized main group radicals and radical ions

(2013) Caleb D. Martin et al.   Chemical Science

Facile Access to Silicon-Functionalized Bis-Silylene Titanium(II) Complexes

(2012) Burgert Blom et al.   CHEMISTRY-A EUROPEAN JOURNAL

Preparation of Stable Low-Oxidation-State Group 14 Element Amidohydrides and Hydride-Mediated Ring-Expansion Chemistry of N-Heterocyclic Carbenes

(2012) S. M. Ibrahim Al-Rafia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactivity Studies of Heteroleptic Silylenes with N2O

(2012) Ramachandran Azhakar et al.   ORGANOMETALLICS

Molecular Tailoring: Reaction Path Control with Bulky Substituents

(2012) Tibor Szilvási et al.   ORGANOMETALLICS

Hydrosilylation of Alkynes by Ni(CO)3-Stabilized Silicon(II) Hydride

(2011) Miriam Stoelzel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of a Phosphine-Stabilized Silicon(II) Hydride and Its Addition to Olefins: A Catalyst-Free Hydrosilylation Reaction

(2011) Ricardo Rodriguez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient generation of stable adducts of Si(ii) dihydride using a donor–acceptor approach

(2011) S. M. Ibrahim Al-Rafia et al.   CHEMICAL COMMUNICATIONS

The Reactivity of a Silacyclopentadienylidene towards Aldehydes: Silole Ring Expansion and the Formation of Base-Stabilized Silacyclohexadienones

(2011) Yihua Gao et al.   CHEMISTRY-A EUROPEAN JOURNAL

A stable silicon(ii) monohydride

(2011) Anukul Jana et al.   DALTON TRANSACTIONS

Reactions of Stable Amidinate Chlorosilylene and [1+4]-Oxidative Addition of N-Heterocyclic Silylene with N-Benzylideneaniline

(2011) Anukul Jana et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Cleavage of Carbene-Stabilized Disilicon

(2011) Mariham Y. Abraham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zwitterionic and Donor-Stabilized N-Heterocyclic Silylenes (NHSis) for Metal-Free Activation of Small Molecules

(2011) Shenglai Yao et al.   ORGANOMETALLICS

Synthesis of a Stable Disilyne Bisphosphine Adduct and Its Non-Metal-Mediated CO2 Reduction to CO

(2010) David Gau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Convenient Access to Monosilicon Epoxides with Pentacoordinate Silicon

(2010) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Synthesis and Rearrangement of Stable NHC→Silylene Adducts and Their Unique Reactivity towards Cyclohexylisocyanide

(2010) Yun Xiong et al.   Chemistry-An Asian Journal

Addition of [(η5-C5Me5)IrH4] to a zwitterionic silylene: stepwise formation of iridium(v)-silyl and iridium(iii)-silylene complexes

(2010) Ann-Katrin Jungton et al.   DALTON TRANSACTIONS

Unique homonuclear multiple bonding in main group compounds

(2009) Yuzhong Wang et al.   CHEMICAL COMMUNICATIONS

Stable Heavier Carbene Analogues

(2009) Yoshiyuki Mizuhata et al.   CHEMICAL REVIEWS

Versatile Reactivity of a Zwitterionic Isolable Silylene toward Ketones: Silicon-Mediated, Regio- and Stereoselective CH Activation

(2009) Yun Xiong et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Systematic Investigation of Factors Influencing the Decarboxylation of Imidazolium Carboxylates

(2009) Bret R. Van Ausdall et al.   JOURNAL OF ORGANIC CHEMISTRY

A Germanium(II) Hydride as an Effective Reagent for Hydrogermylation Reactions

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of two C–H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters

(2008) Javier A. Cabeza et al.   DALTON TRANSACTIONS

Double C−H Bond Activation of an NHC N-Methyl Group on Triruthenium and Triosmium Carbonyl Clusters: A DFT Mechanistic Study

(2008) Javier A. Cabeza et al.   ORGANOMETALLICS