Monomeric C ,N -Chelated Germanium Hydrides in N-C Bond Cleavage

Spontaneous Double Hydrometallation Induced by N→M Coordination in Organometallic Hydrides of Group 14 Elements

(2016) Miroslav Novák et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reaction Mechanism of the Hydrogermylation/Hydrostannylation of Unactivated Alkenes with Two-Coordinate EII Hydrides (E=Ge, Sn): A Theoretical Study

(2016) Lili Zhao et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrosilylation in imino-substituded N- or C-monoanionic ligands

(2016) Hana Hošnová et al.   INORGANICA CHIMICA ACTA

Less Is More: Three-Coordinate C,N-Chelated Distannynes and Digermynes

(2015) Miroslav Novák et al.   CHEMISTRY-A EUROPEAN JOURNAL

Bis-Sulfonyl O,C,O-Chelated Metallylenes (Ge, Sn) as Adjustable Ligands for Iron and Tungsten Complexes

(2015) Noémi Deak et al.   CHEMISTRY-A EUROPEAN JOURNAL

Facile Rearrangement of a Bis(N-heterocyclic carbene)borate Chelate Ligand and Access to [:GeX]+Complexes (X = H, Cl)

(2015) Yun Xiong et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Two-coordinate group 14 element(ii) hydrides as reagents for the facile, and sometimes reversible, hydrogermylation/hydrostannylation of unactivated alkenes and alkynes

(2015) Terrance J. Hadlington et al.   Chemical Science

A singly bonded amido-distannyne: H2 activation and isocyanide coordination

(2014) Terrance J. Hadlington et al.   CHEMICAL COMMUNICATIONS

Hydrosilylation Induced by N→Si Intramolecular Coordination: Spontaneous Transformation of Organosilanes into 1-Aza-Silole-Type Molecules in the Absence of a Catalyst

(2014) Miroslav Novák et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cationic Metallogermylene and Dicationic Dimetallodigermenes: Synthesis by Chloride Abstraction from N-Heterocyclic Carbene-Stabilized Chlorometallogermylenes

(2014) Koya Inomata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds

(2014) Terrance J. Hadlington et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Unexpected Reactivity of Germyliumylidene Hydride [:GeH]+ Stabilized by a Bis(N-heterocyclic carbene)borate Ligand

(2014) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of H2by a Multiply Bonded Amido-Digermyne: Evidence for the Formation of a Hydrido-Germylene

(2013) Terrance J. Hadlington et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable Complexes of Parent Digermene: An Inorganic Analogue of Ethylene

(2013) S. M. Ibrahim Al-Rafia et al.   ORGANOMETALLICS

Monomeric Sn(ii) and Ge(ii) hydrides supported by a tridentate pincer-based ligand

(2012) Shabana Khan et al.   CHEMICAL COMMUNICATIONS

Germylene and (Diazomethyl)germylene Complexes - Potential Precursors for a Transition-Metal-Germa-Alkyne Complex

(2012) Eric Bonnefille et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Germanium Isocyanide Complex Featuring (n → π*) Back-Bonding and Its Conversion to a Hydride/Cyanide Product via C–H Bond Activation under Mild Conditions

(2012) Zachary D. Brown et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Structural Characterization of Metallogermylenes, Cp-Substituted Germylene, and a Germanium(II)-Borane Adduct from Pyridyl-1-azaallyl Germanium(II) Chloride

(2012) Wing-Por Leung et al.   ORGANOMETALLICS

Metal Activation of a Germylenoid, a New Approach to Metal–Germanium Triple Bonds: Synthesis and Reactions of the Germylidyne Complexes [Cp(CO)2M≡Ge–C(SiMe3)3] (M = Mo, W)

(2012) Alexander C. Filippou et al.   ORGANOMETALLICS

Trapping the Parent Inorganic Ethylenes H2SiGeH2 and H2SiSnH2 in the Form of Stable Adducts at Ambient Temperature

(2011) S. M. Ibrahim Al-Rafia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin

(2011) S. M. Ibrahim Al-Rafia et al.   CHEMICAL COMMUNICATIONS

Synthesis, Characterization, and Reactivity of an N-Heterocyclic Germanium(II) Hydride: Reversible Hydrogermylation of a Phosphaalkyne

(2011) Sam L. Choong et al.   ORGANOMETALLICS

Stabilization of the Heavy Methylene Analogues, GeH2and SnH2, within the Coordination Sphere of a Transition Metal

(2010) S. M. Ibrahim Al-Rafia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Halogermanium(II) Complexes Having Phenylamidinate As Supporting Ligands: Syntheses, Characterizations, and Reactivities

(2010) Dimitri Matioszek et al.   ORGANOMETALLICS

Reactions of Tin(II) Hydride Species with Unsaturated Molecules

(2009) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Donor/acceptor stabilization of Ge(ii) dihydride

(2009) Kelsey C. Thimer et al.   CHEMICAL COMMUNICATIONS

Reactivity of germanium(II) hydride with nitrous oxide, trimethylsilyl azide, ketones, and alkynes and the reaction of a methyl analogue with trimethylsilyl diazomethane

(2009) Anukul Jana et al.   DALTON TRANSACTIONS

Energy-consistent pseudopotentials and correlation consistent basis sets for the 5d elements Hf–Pt

(2009) Detlev Figgen et al.   JOURNAL OF CHEMICAL PHYSICS

A Germanium(II) Hydride as an Effective Reagent for Hydrogermylation Reactions

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis, characterisation and reactivity of germanium(ii) amidinate and guanidinate complexes

(2008) Cameron Jones et al.   DALTON TRANSACTIONS