Sustainable Amine Synthesis: Iron Catalyzed Reactions of Hydrosilanes with Imines, Amides, Nitroarenes and Nitriles

Conservation of Critical Elements of the Periodic Table

(2019) Nontipa Supanchaiyamat et al.   ChemSusChem

Catalytic (de)hydrogenation promoted by non-precious metals – Co, Fe and Mn: recent advances in an emerging field

(2018) Georgy A. Filonenko et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of silyl iron hydride via Si–H activation and its dual catalytic application in the hydrosilylation of carbonyl compounds and dehydration of benzamides

(2018) Shishuai Ren et al.   DALTON TRANSACTIONS

Mechanisms of the H2- and transfer hydrogenation of polar bonds catalyzed by iron group hydrides

(2018) Robert H. Morris   DALTON TRANSACTIONS

Reduction of Nitro Compounds Using 3d-Non-Noble Metal Catalysts

(2018) Dario Formenti et al.   CHEMICAL REVIEWS

Iron Catalysis in Reduction and Hydrometalation Reactions

(2018) Duo Wei et al.   CHEMICAL REVIEWS

Iron-Catalyzed Reductive Cyclization of o-Nitrostyrenes Using Phenylsilane as the Terminal Reductant

(2017) Michael Shevlin et al.   ACS Catalysis

Advances in Base-Metal-Catalyzed Alkene Hydrosilylation

(2017) Xiaoyong Du et al.   ACS Catalysis

Imidazolium-based ionic liquid-catalyzed hydrosilylation of imines and reductive amination of aldehydes using hydrosilane as the reductant

(2017) Bin Li et al.   RSC Advances

Efficient reductive dehydration of primary amides to nitriles catalyzed by hydrido thiophenolato iron(II) complexes under hydrosilation conditions

(2016) Benjing Xue et al.   CATALYSIS COMMUNICATIONS

Chemistry Future: Priorities and Opportunities from the Sustainability Perspective

(2016) Matthias Beller et al.   ChemSusChem

Tetramethyldisiloxane: A Practical Organosilane Reducing Agent

(2016) Jaan Pesti et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

A Highly Efficient Base-Metal Catalyst: Chemoselective Reduction of Imines to Amines Using An Abnormal-NHC–Fe(0) Complex

(2016) Mrinal Bhunia et al.   ORGANOMETALLICS

Chemoselective nitro reduction and hydroamination using a single iron catalyst

(2016) Kailong Zhu et al.   Chemical Science

Amine synthesis via iron-catalysed reductive coupling of nitroarenes with alkyl halides

(2016) Chi Wai Cheung et al.   Nature Communications

Amine synthesis via transition metal homogeneous catalysed hydrosilylation

(2016) Bin Li et al.   RSC Advances

An Iron Catalyst for Asymmetric Alkene Hydrosilylation

(2015) Georgii I. Nikonov   ChemCatChem

Iron Catalysis in Organic Synthesis

(2015) Ingmar Bauer et al.   CHEMICAL REVIEWS

Iron-catalyzed reduction of carboxylic and carbonic acid derivatives

(2015) Delphine S. Mérel et al.   COORDINATION CHEMISTRY REVIEWS

The importance of elemental sustainability and critical element recovery

(2015) Andrew J. Hunt et al.   GREEN CHEMISTRY

Knölker-Type Iron Complexes Bearing an N-Heterocyclic Carbene Ligand: Synthesis, Characterization, and Catalytic Dehydration of Primary Amides

(2015) Saravanakumar Elangovan et al.   ORGANOMETALLICS

Practical olefin hydroamination with nitroarenes

(2015) J. Gui et al.   SCIENCE

Iron-Catalysed Hydrofunctionalisation of Alkenes and Alkynes

(2014) Mark D. Greenhalgh et al.   ChemCatChem

Mo(CO)6catalysed chemoselective hydrosilylation of α,β-unsaturated amides for the formation of allylamines

(2014) Alexey Volkov et al.   CHEMICAL COMMUNICATIONS

Methylation of secondary amines with dialkyl carbonates and hydrosilanes catalysed by iron complexes

(2014) Jianxia Zheng et al.   CHEMICAL COMMUNICATIONS

Chemistry of Iron N-Heterocyclic Carbene Complexes: Syntheses, Structures, Reactivities, and Catalytic Applications

(2014) Korbinian Riener et al.   CHEMICAL REVIEWS

A Practical and Catalytic Reductive Olefin Coupling

(2014) Julian C. Lo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Functionalized olefin cross-coupling to construct carbon–carbon bonds

(2014) Julian C. Lo et al.   NATURE

Iron-catalyzed hydrosilylation of CO2: CO2 conversion to formamides and methylamines

(2014) Xavier Frogneux et al.   Catalysis Science & Technology

Iron-catalysed tandem isomerisation/hydrosilylation reaction of allylic alcohols with amines

(2014) Haoquan Li et al.   RSC Advances

Pushing Back the Limits of Hydrosilylation: Unprecedented Catalytic Reduction of Organic Ureas to Formamidines

(2013) Jacky Pouessel et al.   ChemCatChem

Silicon-based C–N Cross-coupling Reaction

(2013) Kenta Shimizu et al.   CHEMISTRY LETTERS

Direct Hydrosilylation of Tertiary Amides to Amines by an In Situ Formed Iron/N-Heterocyclic Carbene Catalyst

(2013) Alexey Volkov et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Bis-N-Heterocyclic Carbene (NHC) Stabilized η6-Arene Iron(0) Complexes: Synthesis, Structure, Reactivity, and Catalytic Activity

(2013) Burgert Blom et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electron-Rich N-Heterocyclic Silylene (NHSi)–Iron Complexes: Synthesis, Structures, and Catalytic Ability of an Isolable Hydridosilylene–Iron Complex

(2013) Burgert Blom et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Desulfurization and H-Migration of Secondary Thioamides Catalyzed by an Iron Complex to Yield Imines and Their Reaction Mechanism

(2013) Kozo Fukumoto et al.   ORGANOMETALLICS

Scope and Mechanistic Studies of Catalytic Hydrosilylation with a High-Valent Nitridoruthenium(VI)

(2013) Srinivas Abbina et al.   ACS Catalysis

Two Iron Catalysts are Better than One: A General and Convenient Reduction of Aromatic and Aliphatic Primary Amides

(2012) Shoubhik Das et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Amine Synthesis through Mild Catalytic Hydrosilylation of Imines using Polymethylhydroxysiloxane and [RuCl2(arene)]2 Catalysts

(2012) Bin Li et al.   ChemSusChem

Phosphane-Pyridine Iron Complexes: Synthesis, Characterization and Application in Reductive Amination through the Hydrosilylation Reaction

(2012) Hassen Jaafar et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

Well-Defined Cyclopentadienyl NHC Iron Complex as the Catalyst for Efficient Hydrosilylation of Amides to Amines and Nitriles

(2011) David Bézier et al.   ChemCatChem

New catalyst systems for iron-catalyzed hydrosilane reduction of carboxamides

(2011) Hironori Tsutsumi et al.   CHEMICAL COMMUNICATIONS

Homogeneous catalysis using iron complexes: recent developments in selective reductions

(2011) Kathrin Junge et al.   CHEMICAL COMMUNICATIONS

NHC-carbene cyclopentadienyl iron based catalyst for a general and efficient hydrosilylation of imines

(2011) Luis C. Misal Castro et al.   CHEMICAL COMMUNICATIONS

Ruthenium-Catalyzed Reductive Amination of Allylic Alcohols

(2011) Zeyneb Sahli et al.   ORGANIC LETTERS

Alternative method for the reduction of aromatic nitro to amine using TMDS-iron catalyst system

(2011) Leyla Pehlivan et al.   TETRAHEDRON

Asymmetric catalysis using iron complexes – ‘Ruthenium Lite’?

(2011) Muftah Darwish et al.   Catalysis Science & Technology

Synthesis of Secondary Amines by Iron-Catalyzed Reductive Amination

(2010) Stephan Enthaler   ChemCatChem

Iron-catalyzed selective reduction of nitroarenes to anilines using organosilanes

(2010) Kathrin Junge et al.   CHEMICAL COMMUNICATIONS

Formamidines - Versatile Ligands for Zinc-Catalyzed Hydrosilylation and Iron-Catalyzed Epoxidation Reactions

(2010) Stephan Enthaler et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iron-catalyzed selective reduction of nitro compounds to amines

(2010) Leyla Pehlivan et al.   TETRAHEDRON LETTERS

Hydrosilane Reduction of Tertiary Carboxamides by Iron Carbonyl Catalysts

(2009) Yusuke Sunada et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Convenient and General Iron-Catalyzed Reduction of Amides to Amines

(2009) Shaolin Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Catalytic Hydrogenation of Functionalized Nitroarenes: An Update

(2009) Hans-Ulrich Blaser et al.   ChemCatChem

New catalytic properties of iron complexes: dehydration of amides to nitriles

(2009) Shaolin Zhou et al.   CHEMICAL COMMUNICATIONS

Coming of Age: Sustainable Iron-Catalyzed Cross-Coupling Reactions

(2009) Waldemar Maximilian Czaplik et al.   ChemSusChem

Highly Chemo- and Regioselective Reduction of Aromatic Nitro Compounds Using the System Silane/Oxo-Rhenium Complexes

(2009) Rita G. de Noronha et al.   JOURNAL OF ORGANIC CHEMISTRY

Practical Access to Amines by Platinum-Catalyzed Reduction of Carboxamides with Hydrosilanes: Synergy of Dual Si−H Groups Leads to High Efficiency and Selectivity

(2009) Shiori Hanada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent Progress in the Asymmetric Hydrosilylation of Ketones and Imines

(2009) Carmela Arena   MINI-REVIEWS IN ORGANIC CHEMISTRY

Sustainable Metal Catalysis with Iron: From Rust to a Rising Star?

(2008) Stephan Enthaler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Iron Catalysis in Organic Synthesis

(2008) Eike Bauer   CURRENT ORGANIC CHEMISTRY

Functionalization of magnetic nanoparticles with organic molecules: Loading level determination and evaluation of linker length effect on immobilization

(2007) Balasubramanian Srinivasan et al.   CHIRALITY