Three-Coordinate Boron(III) and Diboron(II) Dications

Tris(pentafluorophenyl)borane and Beyond: Modern Advances in Borylation Chemistry

(2017) James R. Lawson et al.   INORGANIC CHEMISTRY

Twist of a Silicon–Silicon Double Bond: Selective Anti-Addition of Hydrogen to an Iminodisilene

(2017) Daniel Wendel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

From Si(II) to Si(IV) and Back: Reversible Intramolecular Carbon–Carbon Bond Activation by an Acyclic Iminosilylene

(2017) Daniel Wendel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silicon and Oxygen’s Bond of Affection: An Acyclic Three-Coordinate Silanone and Its Transformation to an Iminosiloxysilylene

(2017) Daniel Wendel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aluminum/Nitrogen Cycles and an Open Cage with Al-H and N-H Functions

(2017) Michael Veith et al.   ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE

Synthesis of a cyclopentadienyl(imino)stannylene and its direct conversion into halo(imino)stannylenes

(2017) Tatsumi Ochiai et al.   RSC Advances

Isolation and Structure of Germylene-Germyliumylidenes Stabilized by N-Heterocyclic Imines

(2016) Tatsumi Ochiai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Tin Analogue of Carbenoid: Isolation and Reactivity of a Lithium Bis(imidazolin-2-imino)stannylenoid

(2016) Tatsumi Ochiai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cationic aluminum hydride complexes: reactions of carbene–alane adducts with trityl-borate

(2016) Levy L. Cao et al.   CHEMICAL COMMUNICATIONS

Applications of N-heterocyclic imines in main group chemistry

(2016) Tatsumi Ochiai et al.   CHEMICAL SOCIETY REVIEWS

Desymmetrizing Electron-Deficient Diboranes(4): Diverse Products and Their Reactivity

(2016) Nicole Arnold et al.   CHEMISTRY-A EUROPEAN JOURNAL

Developing nitrosocarborane chemistry

(2016) Samuel L. Powley et al.   DALTON TRANSACTIONS

N-Heterocyclic olefin stabilized boron dication

(2016) Wan-Hua Lee et al.   DALTON TRANSACTIONS

Advances in the development of complexes that contain a group 13 element chalcogen multiple bond

(2016) Daniel Franz et al.   DALTON TRANSACTIONS

Cp*-Substituted Boron Cations: The Effect of NHC, NHO, and CAAC Ligands

(2016) Jih-Sheng Huang et al.   INORGANIC CHEMISTRY

Forming B–B Bonds by the Controlled Reduction of a Tetraaryl-diborane(6)

(2016) Thomas Kaese et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isolation of a Diborane(6) Dication: Formation and Cleavage of an Electron-Precise B(sp3)–B(sp3) Bond

(2016) Lingbing Kong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile Access to Stable Silylium Ions Stabilized by N-Heterocyclic Imines

(2016) Tatsumi Ochiai et al.   MOLECULES

Mechanistic Studies on the Rearrangement of a Boron Cation: From a nido-Carborane to a Planar Boracycle

(2016) Ya-Fan Lin et al.   ORGANOMETALLICS

The broadening reach of frustrated Lewis pair chemistry

(2016) D. W. Stephan   SCIENCE

The Hexacyanodiborane(6) Dianion [B2(CN)6]2−

(2015) Johannes Landmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable but Highly Reactive Phosphine-Coordinated Borenium: Metal-free Dihydrogen Activation and Alkyne 1,2-Carboboration

(2015) Marc Devillard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Planar N-Heterocyclic Carbene Diarylborenium Ions: Synthesis by Cationic Borylation and Reactivity with Lewis Bases

(2015) Jeffrey M. Farrell et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Hydrogenations at Room Temperature and Atmospheric Pressure with Mesoionic Carbene-Stabilized Borenium Catalysts

(2015) Patrick Eisenberger et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Main Group Lewis Acids in Frustrated Lewis Pair Chemistry: Beyond Electrophilic Boranes

(2015) Sarah A. Weicker et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

A unified survey of Si–H and H–H bond activation catalysed by electron-deficient boranes

(2015) Martin Oestreich et al.   CHEMICAL SOCIETY REVIEWS

Mild Dehydrogenation of Ammonia Borane Complexed with Aluminum Borohydride

(2015) Iurii Dovgaliuk et al.   CHEMISTRY OF MATERIALS

Lowering the Reduction Potential of a Boron Compound by Means of the Substituent Effect of the Boryl Group: One-Electron Reduction of an Unsymmetrical Diborane(4)

(2015) Hiroki Asakawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Formation of an Imino-Stabilized Cyclic Tin(II) Cation from an Amino(imino)stannylene

(2015) Tatsumi Ochiai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Isolation of a germanium(ii) cation and a germylene iron carbonyl complex utilizing an imidazolin-2-iminato ligand

(2015) Tatsumi Ochiai et al.   DALTON TRANSACTIONS

Mono- and di-cationic hydrido boron compounds

(2015) Rajendra S. Ghadwal et al.   DALTON TRANSACTIONS

1,1/1,2 Isomerisation in Lewis base adducts of B2cat2

(2015) I. A. Cade et al.   DALTON TRANSACTIONS

The enhanced structural carborane effect

(2015) Samuel L. Powley et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Frustrated Lewis Pairs

(2015) Douglas W. Stephan   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A family of N-heterocyclic carbene-stabilized borenium ions for metal-free imine hydrogenation catalysis

(2015) Jeffrey M. Farrell et al.   Chemical Science

A monotopic aluminum telluride with an Al=Te double bond stabilized by N-heterocyclic carbenes

(2015) Daniel Franz et al.   Nature Communications

Frustrated Lewis Pairs: From Concept to Catalysis

(2014) Douglas W. Stephan   ACCOUNTS OF CHEMICAL RESEARCH

Isolation of a Three-Coordinate Boron Cation with a Boron-Sulfur Double Bond

(2014) Daniel Franz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Systematic Investigation of the Ring-Expansion Reaction of N-Heterocyclic Carbenes with an Iminoborane Dihydride

(2014) Daniel Franz et al.   Chemistry-An Asian Journal

The Elusive Three-Coordinate Dicationic Hydrido Boron Complex

(2014) Wen-Ching Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Facile scission of isonitrile carbon–nitrogen triple bond using a diborane(4) reagent

(2014) Hiroki Asakawa et al.   Nature Communications

A Di-Substituted Boron Dication and Its Hydride-Induced Transformation to an NHC-Stabilized Borabenzene

(2013) Chao-Tang Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Haloboration of Internal Alkynes with Boronium and Borenium Cations as a Route to Tetrasubstituted Alkenes

(2013) James R. Lawson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis acidity of boron compounds

(2013) Igor B. Sivaev et al.   COORDINATION CHEMISTRY REVIEWS

Transition metal complexes supported by highly basic imidazolin-2-iminato and imidazolin-2-imine N-donor ligands

(2013) Xian Wu et al.   COORDINATION CHEMISTRY REVIEWS

Synthesis, characterization and reactivity of an imidazolin-2-iminato aluminium dihydride

(2013) Daniel Franz et al.   DALTON TRANSACTIONS

Synthesis and Single Crystal Structure of Sodium Octahydrotriborate, NaB3H8

(2013) Andrew C. Dunbar et al.   INORGANIC CHEMISTRY

Weakly Stabilized Primary Borenium Cations and Their Dicationic Dimers

(2013) Aleksandrs Prokofjevs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Quaternizing Diboranes(4): Highly Divergent Outcomes and an Inorganic Wagner–Meerwein Rearrangement

(2013) Holger Braunschweig et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An inorganic propellane with central B–B bond

(2012) Steffen Pospiech et al.   CHEMICAL COMMUNICATIONS

Cationic Tricoordinate Boron Intermediates: Borenium Chemistry from the Organic Perspective

(2012) Timothy S. De Vries et al.   CHEMICAL REVIEWS

Activation of Hydrogen and Hydrogenation Catalysis by a Borenium Cation

(2012) Jeffrey M. Farrell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Taking the F out of FLP: Simple Lewis Acid–Base Pairs for Mild Reductions with Neutral Boranes via Borenium Ion Catalysis

(2012) Patrick Eisenberger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borenium Ion Catalyzed Hydroboration of Alkenes with N-Heterocyclic Carbene-Boranes

(2012) Aleksandrs Prokofjevs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pinacol Boronates by Direct Arene Borylation with Borenium Cations

(2011) Alessandro Del Grosso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unprecedented reactivity of an aluminium hydride complex with ArNH2BH3: nucleophilic substitution versus deprotonation

(2011) Sjoerd Harder et al.   CHEMICAL COMMUNICATIONS

Ammonium Octahydrotriborate (NH4B3H8): New Synthesis, Structure, and Hydrolytic Hydrogen Release

(2011) Zhenguo Huang et al.   INORGANIC CHEMISTRY

Spectroscopic and Structural Characterization of the CyNHC Adduct of B2pin2 in Solution and in the Solid State

(2011) Christian Kleeberg et al.   JOURNAL OF ORGANIC CHEMISTRY

Structure and Reactivity of a Preactivated sp2–sp3Diboron Reagent: Catalytic Regioselective Boration of α,β-Unsaturated Conjugated Compounds

(2011) Ming Gao et al.   JOURNAL OF ORGANIC CHEMISTRY

Boron–Boron σ-Bond Formation by Two-Electron Reduction of a H-Bridged Dimer of Monoborane

(2011) Yoshiaki Shoji et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Generation of a Carbene-Stabilized Bora-borylene and its Insertion into a C–H Bond

(2011) Philipp Bissinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Directed Aliphatic C–H Borylation Using Borenium Cation Equivalents

(2011) Aleksandrs Prokofjevs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Stable Doubly Hydrogen-Bridged Butterfly-Shaped Diborane(4) Compound

(2010) Yoshiaki Shoji et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Porphyrin complexes containing coordinated BOB groups: synthesis, chemical reactivity and the structure of [BOB(tpClpp)]2+

(2008) Warwick J. Belcher et al.   DALTON TRANSACTIONS

Synthesis and Structure of a Ferrocenylboron Dication

(2008) Holger Braunschweig et al.   INORGANIC CHEMISTRY

First Dinuclear B(II) Monocations with Bridging Guanidinate Ligands: Synthesis and Properties

(2008) Oxana Ciobanu et al.   INORGANIC CHEMISTRY

Dicarbollylamine Ligand as a Tunable Template for σ,σ- and π,σ-Bonding Modes: Syntheses, Structures, and Theoretical Studies of η5:η1-Coordinated Constrained-Geometry Group 13 Metal Complexes

(2008) Jong-Dae Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY