Metal-Ligand Cooperation

Exploiting Metal–Ligand Bifunctional Reactions in the Design of Iron Asymmetric Hydrogenation Catalysts

(2015) Robert H. Morris   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogenation and Dehydrogenation Iron Pincer Catalysts Capable of Metal–Ligand Cooperation by Aromatization/Dearomatization

(2015) Thomas Zell et al.   ACCOUNTS OF CHEMICAL RESEARCH

A Metal-Ligand Cooperative Pathway for Intermolecular Oxa-Michael Additions to Unsaturated Nitriles

(2015) Sébastien Perdriau et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A new class of PN3-pincer ligands for metal–ligand cooperative catalysis

(2015) Huaifeng Li et al.   COORDINATION CHEMISTRY REVIEWS

Beyond H2: exploiting 2-hydroxypyridine as a design element from [Fe]-hydrogenase for energy-relevant catalysis

(2015) Cameron M Moore et al.   CURRENT OPINION IN CHEMICAL BIOLOGY

O2 Activation by Metal–Ligand Cooperation with IrI PNP Pincer Complexes

(2015) Moran Feller et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Cooperation in the Formal Hydrogenation of N2O Using a PCsp2P Iridium Pincer Complex

(2015) Lauren E. Doyle et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of the Catalytic Formation of Lactams from Amines and Water with Liberation of H2

(2015) Urs Gellrich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative Metal–Ligand Reactivity and Catalysis in Low-Spin Ferrous Alkoxides

(2015) Wan-Yi Chu et al.   ORGANOMETALLICS

Metal-ligand cooperation by aromatization-dearomatization as a tool in single bond activation

(2015) D. Milstein   PHILOSOPHICAL TRANSACTIONS OF THE ROYAL SOCIETY A-MATHEMATICAL PHYSICAL AND ENGINEERING SCIENCES

Combining Low-Pressure CO2 Capture and Hydrogenation To Form Methanol

(2015) Julia R. Khusnutdinova et al.   ACS Catalysis

Computational Mechanistic Studies on Reactions of Transition Metal Complexes with Noninnocent Pincer Ligands: Aromatization–Dearomatization or Not

(2015) Haixia Li et al.   ACS Catalysis

Catalytic Hydrogenation of CO2 to Formates by a Lutidine-Derived Ru–CNC Pincer Complex: Theoretical Insight into the Unrealized Potential

(2015) Georgy A. Filonenko et al.   ACS Catalysis

Base-Free Methanol Dehydrogenation Using a Pincer-Supported Iron Compound and Lewis Acid Co-catalyst

(2015) Elizabeth A. Bielinski et al.   ACS Catalysis

Hydrogenation of Esters to Alcohols with a Well-Defined Iron Complex

(2014) Svenja Werkmeister et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boryl-assisted hydrogenolysis of a nickel–methyl bond

(2014) Natalia Curado et al.   CHEMICAL COMMUNICATIONS

Metal–ligand bifunctional reactivity and catalysis of protic N-heterocyclic carbene and pyrazole complexes featuring β-NH units

(2014) Shigeki Kuwata et al.   CHEMICAL COMMUNICATIONS

Bond Activation and Catalysis by Ruthenium Pincer Complexes

(2014) Chidambaram Gunanathan et al.   CHEMICAL REVIEWS

Hydrogenases

(2014) Wolfgang Lubitz et al.   CHEMICAL REVIEWS

Metal-Ligand Cooperation on a Diruthenium Platform: Selective Imine Formation through Acceptorless Dehydrogenative Coupling of Alcohols with Amines

(2014) Biswajit Saha et al.   CHEMISTRY-A EUROPEAN JOURNAL

Intramolecular CH/OH Bond Cleavage with Water and Alcohol Using a Phosphine-Free Ruthenium Carbene NCN Pincer Complex

(2014) Demyan E. Prokopchuk et al.   CHEMISTRY-A EUROPEAN JOURNAL

Platinum Complexes of a Borane-Appended Analogue of 1,1′-Bis(diphenylphosphino)ferrocene: Flexible Borane Coordination Modes and in situ Vinylborane Formation

(2014) Bradley E. Cowie et al.   CHEMISTRY-A EUROPEAN JOURNAL

System with Potential Dual Modes of Metal-Ligand Cooperation: Highly Catalytically Active Pyridine-Based PNNH-Ru Pincer Complexes

(2014) Eran Fogler et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalysis by Aluminum(III) Complexes of Non-Innocent Ligands

(2014) Louise A. Berben   CHEMISTRY-A EUROPEAN JOURNAL

Rational development of iron catalysts for asymmetric transfer hydrogenation

(2014) Peter E. Sues et al.   DALTON TRANSACTIONS

Development of Molecular Electrocatalysts for Energy Storage

(2014) Daniel L. DuBois   INORGANIC CHEMISTRY

Catalytic Mechanisms of Direct Pyrrole Synthesis via Dehydrogenative Coupling Mediated by PNP-Ir or PNN-Ru Pincer Complexes: Crucial Role of Proton-Transfer Shuttles in the PNP-Ir System

(2014) Shuanglin Qu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative Transition Metal/Lewis Acid Bond-Activation Reactions by a Bidentate (Boryl)iminomethane Complex: A Significant Metal–Borane Interaction Promoted by a Small Bite-Angle LZ Chelate

(2014) Brandon R. Barnett et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Based Catalysts for the Hydrogenation of Esters to Alcohols

(2014) Sumit Chakraborty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidant-Free Conversion of Cyclic Amines to Lactams and H2 Using Water As the Oxygen Atom Source

(2014) Julia R. Khusnutdinova et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Molecular Iron Catalyst for the Acceptorless Dehydrogenation and Hydrogenation of N-Heterocycles

(2014) Sumit Chakraborty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alcohol Amination with Ammonia Catalyzed by an Acridine-Based Ruthenium Pincer Complex: A Mechanistic Study

(2014) Xuan Ye et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron Catalysts Containing Amine(imine)diphosphine P-NH-N-P Ligands Catalyze both the Asymmetric Hydrogenation and Asymmetric Transfer Hydrogenation of Ketones

(2014) Weiwei Zuo et al.   ORGANOMETALLICS

Conformational Flexibility of Dibenzobarrelene-Based PC(sp3)P Pincer Iridium Hydride Complexes: The Role of Hemilabile Functional Groups and External Coordinating Solvents

(2014) Gleb A. Silantyev et al.   ORGANOMETALLICS

B–H Bond Cleavage via Metal–Ligand Cooperation by Dearomatized Ruthenium Pincer Complexes

(2014) Aviel Anaby et al.   ORGANOMETALLICS

Efficient Hydrogenation of Ketones and Aldehydes Catalyzed by Well-Defined Iron(II) PNP Pincer Complexes: Evidence for an Insertion Mechanism

(2014) Nikolaus Gorgas et al.   ORGANOMETALLICS

Synthesis and Reactivity of a Nucleophilic Palladium(II) Carbene

(2014) Cezar C. Comanescu et al.   ORGANOMETALLICS

Positional Effects of Hydroxy Groups on Catalytic Activity of Proton-Responsive Half-Sandwich Cp*Iridium(III) Complexes

(2014) Yuki Suna et al.   ORGANOMETALLICS

Hydrogenation of Esters Catalyzed by Ruthenium PN3-Pincer Complexes Containing an Aminophosphine Arm

(2014) Tao Chen et al.   ORGANOMETALLICS

Reversible CO2 binding triggered by metal–ligand cooperation in a rhenium(i) PNP pincer-type complex and the reaction with dihydrogen

(2014) Matthias Vogt et al.   Chemical Science

Efficient Catalyst for Acceptorless Alcohol Dehydrogenation: Interplay of Theoretical and Experimental Studies

(2014) Guixiang Zeng et al.   ACS Catalysis

Well-Defined Iron Catalysts for the Acceptorless Reversible Dehydrogenation-Hydrogenation of Alcohols and Ketones

(2014) Sumit Chakraborty et al.   ACS Catalysis

Lutidine-Derived Ru-CNC Hydrogenation Pincer Catalysts with Versatile Coordination Properties

(2014) Georgy A. Filonenko et al.   ACS Catalysis

Direct Deamination of Primary Amines by Water To Produce Alcohols

(2013) Julia R. Khusnutdinova et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Hydrogen Production from Methanol with a Defined Iron Pincer Catalyst under Mild Conditions

(2013) Elisabetta Alberico et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Synthesis of Pyrroles by Dehydrogenative Coupling of β-Aminoalcohols with Secondary Alcohols Catalyzed by Ruthenium Pincer Complexes

(2013) Dipankar Srimani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The NH Functional Group in Organometallic Catalysis

(2013) Baoguo Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible carbon–carbon bond formation between carbonyl compounds and a ruthenium pincer complex

(2013) Chelsea A. Huff et al.   CHEMICAL COMMUNICATIONS

Stepwise Metal-Ligand Cooperation by a Reversible Aromatization/Deconjugation Sequence in Ruthenium Complexes with a Tetradentate Phenanthroline-Based Ligand

(2013) Robert Langer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reactivity Studies of Iridium Pyridylidenes [TpMe2Ir(C6H5)2(C(CH)3C(R)NH] (R=H, Me, Ph)

(2013) Crispín Cristóbal et al.   CHEMISTRY-A EUROPEAN JOURNAL

Recent Developments in the Coordination Chemistry of Multidentate Ligands Featuring a Boron Moiety

(2013) Hajime Kameo et al.   Chemistry-An Asian Journal

Activation of carbon–hydrogen bonds and dihydrogen by 1,2-CH-addition across metal–heteroatom bonds

(2013) Joanna R. Webb et al.   DALTON TRANSACTIONS

The First ZnII-Catalyzed Oxidative Amidation of Benzyl Alcohols with Amines under Solvent-Free Conditions

(2013) Xiao-Feng Wu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A general and practical oxidation of alcohols to primary amides under metal-free conditions

(2013) Xiao-Feng Wu et al.   GREEN CHEMISTRY

Room Temperature Rapid Functionalization of E–H Bonds (E = O, N, S) via the Metal–Ligand Cooperation Mechanism

(2013) Adam Scharf et al.   INORGANIC CHEMISTRY

Catalytic Generation of Borenium Ions by Cooperative B–H Bond Activation: The Elusive Direct Electrophilic Borylation of Nitrogen Heterocycles with Pinacolborane

(2013) Timo Stahl et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Mechanism of Borane–Amine Dehydrocoupling with Bifunctional Ruthenium Catalysts

(2013) Alexander N. Marziale et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Water, Ammonia, and Other Small Molecules by PCcarbeneP Nickel Pincer Complexes

(2013) Dmitry V. Gutsulyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acceptorless Dehydrogenation of C–C Single Bonds Adjacent to Functional Groups by Metal–Ligand Cooperation

(2013) Shuhei Kusumoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N–N Bond Cleavage of Hydrazines with a Multiproton-Responsive Pincer-Type Iron Complex

(2013) Kazuki Umehara et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation of Nitriles by Metal Ligand Cooperation. Reversible Formation of Ketimido- and Enamido-Rhenium PNP Pincer Complexes and Relevance to Catalytic Design

(2013) Matthias Vogt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A homogeneous transition metal complex for clean hydrogen production from methanol–water mixtures

(2013) Rafael E. Rodríguez-Lugo et al.   Nature Chemistry

A sustainable catalytic pyrrole synthesis

(2013) Stefan Michlik et al.   Nature Chemistry

Catalytic transformation of alcohols to carboxylic acid salts and H2 using water as the oxygen atom source

(2013) Ekambaram Balaraman et al.   Nature Chemistry

Reactions of Five-Coordinate Platinum(IV) Complexes with Molecular Oxygen

(2013) Margaret L. Scheuermann et al.   ORGANOMETALLICS

Heterolytic Cleavage of Dihydrogen by an Iron(II) PNP Pincer Complex via Metal–Ligand Cooperation

(2013) Bernhard Bichler et al.   ORGANOMETALLICS

Bifunctional Ruthenium(II) PCP Pincer Complexes and Their Catalytic Activity in Acceptorless Dehydrogenative Reactions

(2013) Sanaa Musa et al.   ORGANOMETALLICS

Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane

(2013) Henry Fong et al.   ORGANOMETALLICS

Amine(imine)diphosphine Iron Catalysts for Asymmetric Transfer Hydrogenation of Ketones and Imines

(2013) W. Zuo et al.   SCIENCE

Applications of Acceptorless Dehydrogenation and Related Transformations in Chemical Synthesis

(2013) C. Gunanathan et al.   SCIENCE

Mechanistic Insight through Factors Controlling Effective Hydrogenation of CO2 Catalyzed by Bioinspired Proton-Responsive Iridium(III) Complexes

(2013) Wan-Hui Wang et al.   ACS Catalysis

Metal–Ligand Cooperation in the Cycloisomerization of Alkynoic Acids with Indenediide Palladium Pincer Complexes

(2013) Noel Nebra et al.   ACS Catalysis

Multidentate actor ligands as versatile platforms for small molecule activation and catalysis

(2013) Vincent T. Annibale et al.   RSC Advances

From Esters to Alcohols and Back with Ruthenium and Osmium Catalysts

(2012) Denis Spasyuk et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Learning from the Neighbors: Improving Homogeneous Catalysts with Functional Ligands Motivated by Heterogeneous and Biocatalysis

(2012) Bjorn Askevold et al.   ChemCatChem

Manganese oxide-catalyzed transformation of primary amines to primary amides through the sequence of oxidative dehydrogenation and successive hydration

(2012) Ye Wang et al.   CHEMICAL COMMUNICATIONS

Lewis acid-catalyzed oxidation of benzylamines to benzamides

(2012) Xiao-Feng Wu et al.   CHEMICAL COMMUNICATIONS

Tautomerisation of 2-Substituted Pyridines to N-Heterocyclic Carbene Ligands Induced by the 16 e− Unsaturated [TpMe2IrIII(C6H5)2] Moiety

(2012) Salvador Conejero et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Highly Active Bifunctional Iridium Complex with an Alcohol/Alkoxide-Tethered N-Heterocyclic Carbene for Alkylation of Amines with Alcohols

(2012) Agnieszka Bartoszewicz et al.   CHEMISTRY-A EUROPEAN JOURNAL

A New Mode of Activation of CO2 by Metal-Ligand Cooperation with Reversible CC and MO Bond Formation at Ambient Temperature

(2012) Matthias Vogt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Evidence for Metal–Ligand Cooperation in a Pd–PNF Pincer-Catalyzed Cross-Coupling

(2012) Adam Scharf et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aldehyde Binding through Reversible C–C Coupling with the Pincer Ligand upon Alcohol Dehydrogenation by a PNP–Ruthenium Catalyst

(2012) Michael Montag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Mechanism of Efficient Asymmetric Transfer Hydrogenation of Acetophenone Using an Iron(II) Complex Containing an (S,S)-Ph2PCH2CH═NCHPhCHPhN═CHCH2PPh2 Ligand: Partial Ligand Reduction Is the Key

(2012) Alexandre A. Mikhailine et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis

(2012) W. Hill Harman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible hydrogen storage using CO2 and a proton-switchable iridium catalyst in aqueous media under mild temperatures and pressures

(2012) Jonathan F. Hull et al.   Nature Chemistry

Outer sphere hydrogenation catalysis

(2012) Odile Eisenstein et al.   NEW JOURNAL OF CHEMISTRY

Factors Favoring Efficient Bifunctional Catalysis. Study of a Ruthenium(II) Hydrogenation Catalyst Containing an N-Heterocyclic Carbene with a Primary Amine Donor

(2012) Wylie W. N. O et al.   ORGANOMETALLICS

N–H Activation by Rh(I) via Metal–Ligand Cooperation

(2012) Moran Feller et al.   ORGANOMETALLICS

Reactivity of Scandium β-Diketiminate Alkyl Complexes with Carbon Dioxide

(2012) Francis A. LeBlanc et al.   ORGANOMETALLICS

β-Elimination-Immune PCcarbeneP Iridium Complexes via Double C–H Activation: Ligand–Metal Cooperation in Hydrogen Activation

(2012) Richard J. Burford et al.   ORGANOMETALLICS

Role of a Noninnocent Pincer Ligand in the Activation of CO2 at (PNN)Ru(H)(CO)

(2012) Chelsea A. Huff et al.   ORGANOMETALLICS

Copper-Catalyzed Aerobic Oxidative Synthesis of Primary Amides from (Aryl)methanamines

(2012) Hua Fu et al.   SYNLETT

Coordination Versatility of sp3-Hybridized Pincer Ligands toward Ligand–Metal Cooperative Catalysis

(2012) Dmitri Gelman et al.   ACS Catalysis

Ester Hydrogenation Catalyzed by a Ruthenium(II) Complex Bearing an N-Heterocyclic Carbene Tethered with an “NH2” Group and a DFT Study of the Proposed Bifunctional Mechanism

(2012) Wylie W. N. O et al.   ACS Catalysis

Catalytic Reductive Transformations of Carboxylic and Carbonic Acid Derivatives Using Molecular Hydrogen

(2012) Pavel A. Dub et al.   ACS Catalysis

Metal–Ligand Cooperation by Aromatization–Dearomatization: A New Paradigm in Bond Activation and “Green” Catalysis

(2011) Chidambaram Gunanathan et al.   ACCOUNTS OF CHEMICAL RESEARCH

Ligand-Metal Cooperation in PCP Pincer Complexes: Rational Design and Catalytic Activity in Acceptorless Dehydrogenation of Alcohols

(2011) Sanaa Musa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unprecedented Catalytic Hydrogenation of Urea Derivatives to Amines and Methanol

(2011) Ekambaram Balaraman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient Hydrogen Production from Alcohols under Mild Reaction Conditions

(2011) Martin Nielsen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ester hydrogenation catalyzed by Ru-CNN pincer complexes

(2011) Yunshan Sun et al.   CHEMICAL COMMUNICATIONS

Cooperative Aliphatic PNP Amido Pincer Ligands - Versatile Building Blocks for Coordination Chemistry and Catalysis

(2011) Sven Schneider et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Cooperative Catalysis with First-Row Late Transition Metals

(2011) Jarl Ivar van der Vlugt   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Net Heterolytic Cleavage of B–H and B–B Bonds Across the N–Pd Bond in a Cationic (PNP)Pd Fragment

(2011) Yanjun Zhu et al.   INORGANIC CHEMISTRY

Experimental Investigations of a Partial Ru–O Bond during the Metal–Ligand Bifunctional Addition in Noyori-Type Enantioselective Ketone Hydrogenation

(2011) Satoshi Takebayashi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cooperative Catalytic Activation of Si−H Bonds by a Polar Ru−S Bond: Regioselective Low-Temperature C−H Silylation of Indoles under Neutral Conditions by a Friedel−Crafts Mechanism

(2011) Hendrik F. T. Klare et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

H–H and N–H Bond Cleavage of Dihydrogen and Ammonia with a Bifunctional Parent Imido (NH)-Bridged Diiridium Complex

(2011) Takashi Kimura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Secondary Coordination Sphere Interactions Facilitate the Insertion Step in an Iridium(III) CO2Reduction Catalyst

(2011) Timothy J. Schmeier et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ammonia formation by metal–ligand cooperative hydrogenolysis of a nitrido ligand

(2011) Bjorn Askevold et al.   Nature Chemistry

Efficient hydrogenation of organic carbonates, carbamates and formates indicates alternative routes to methanol based on CO2 and CO

(2011) Ekambaram Balaraman et al.   Nature Chemistry

Water Splitting Promoted by a Ruthenium(II) PNN Complex: An Alternate Pathway through a Dihydrogen Complex for Hydrogen Production

(2011) K. S. Sandhya et al.   ORGANOMETALLICS

Osmium and Ruthenium Catalysts for Dehydrogenation of Alcohols

(2011) Marcello Bertoli et al.   ORGANOMETALLICS

Mechanistic Investigation of the Hydrogenation of Ketones Catalyzed by a Ruthenium(II) Complex Featuring an N-Heterocyclic Carbene with a Tethered Primary Amine Donor: Evidence for an Inner Sphere Mechanism

(2011) Wylie W. N. O et al.   ORGANOMETALLICS

Conversions of Cyclic Amines to Nylon Precursor Lactams Using Bulk Gold and Fumed Silica Catalysts

(2011) Erik R. Klobukowski et al.   ACS Catalysis

A Biologically Inspired Organometallic Fuel Cell (OMFC) That Converts Renewable Alcohols into Energy and Chemicals

(2010) Samuel P. Annen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metallacyclic Pyridylidene Structures from Reactions of Terminal Pyridylidenes with Alkenes and Acetylene

(2010) Eleuterio Álvarez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemistry ofConcertoMolecular Catalysis Based on the Metal/NH Bifunctionality

(2010) Takao Ikariya   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Double addition of H2to transition metal–borane complexes: a ‘hydride shuttle’ process between boron and transition metal centres

(2010) Nikolaos Tsoureas et al.   CHEMICAL COMMUNICATIONS

Discovery, Applications, and Catalytic Mechanisms of Shvo’s Catalyst

(2010) Brian L. Conley et al.   CHEMICAL REVIEWS

Domino Rhodium/Palladium-Catalyzed Dehydrogenation Reactions of Alcohols to Acids by Hydrogen Transfer to Inactivated Alkenes

(2010) Mónica Trincado et al.   CHEMISTRY-A EUROPEAN JOURNAL

Quest for metal/NH bifunctional bioinspired catalysis in a dinuclear platform

(2010) Shigeki Kuwata et al.   DALTON TRANSACTIONS

Heterolytic splitting of H–X bonds at a cationic (PNP)Pd center

(2010) Lauren C. Gregor et al.   DALTON TRANSACTIONS

Ruthenium Complexes with Cooperative PNP-Pincer Amine, Amido, Imine, and Enamido Ligands: Facile Ligand Backbone Functionalization Processes

(2010) Anja Friedrich et al.   INORGANIC CHEMISTRY

N−H Activation of Amines and Ammonia by Ru via Metal−Ligand Cooperation

(2010) Eugene Khaskin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

“Long-Range” Metal−Ligand Cooperation in H2Activation and Ammonia-Promoted Hydride Transfer with a Ruthenium−Acridine Pincer Complex

(2010) Chidambaram Gunanathan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multifunctional ligands in transition metal catalysis

(2010) Robert H. Crabtree   NEW JOURNAL OF CHEMISTRY

Organoiridium Pyridonates and Their Role in the Dehydrogenation of Alcohols

(2010) Aaron M. Royer et al.   ORGANOMETALLICS

Perspectives on How Nature Employs the Principles of Organometallic Chemistry in Dihydrogen Activation in Hydrogenases†

(2010) John C. Gordon et al.   ORGANOMETALLICS

Metal−Ligand Cooperativity in O2Activation: Observation of a “Pt−O−O−C” Peroxo Intermediate§

(2010) Margaret L. Scheuermann et al.   ORGANOMETALLICS

Synthesis and Reactivity of an Iridium(I) Acetonyl PNP Complex. Experimental and Computational Study of Metal−Ligand Cooperation in H−H and C−H Bond Activation via Reversible Ligand Dearomatization

(2010) Leonid Schwartsburd et al.   ORGANOMETALLICS

Cationic Ruthenium Hydrido−Carbonyls Derived from Metallocene-Based Pincers: Unusual Rearrangements and H2Evolution with Formation of Cationic Ruthenium Metallocenylidenes

(2010) Avthandil A. Koridze et al.   ORGANOMETALLICS

Bifunctional Transition Metal-Based Molecular Catalysts for Asymmetric C–C and C–N Bond Formation

(2010) Takao Ikariya et al.   TOPICS IN CATALYSIS

Discovery of Environmentally Benign Catalytic Reactions of Alcohols Catalyzed by Pyridine-Based Pincer Ru Complexes, Based on Metal–Ligand Cooperation

(2010) David Milstein   TOPICS IN CATALYSIS

Ruthenium Complexes with Cooperative PNP Ligands: Bifunctional Catalysts for the Dehydrogenation of Ammonia-Borane

(2009) Martina Käß et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible H2splitting between Ru(ii) and a remote carbanion in a zwitterionic compound

(2009) Elzbieta Stepowska et al.   CHEMICAL COMMUNICATIONS

Structural and Functional Analogues of the Active Sites of the [Fe]-, [NiFe]-, and [FeFe]-Hydrogenases†

(2009) Cédric Tard et al.   CHEMICAL REVIEWS

Highly active iridium catalysts for the hydrogenation of ketones and aldehydes

(2009) Xuanhua Chen et al.   DALTON TRANSACTIONS

Metal–ligand cooperation in the trans addition of dihydrogen to a pincer Ir(i) complex: a DFT study

(2009) Mark A. Iron et al.   DALTON TRANSACTIONS

Theoretical study on the mechanism of H2activation mediated by two transition metal thiolate complexes: Homolytic for Ir, heterolytic for Rh

(2009) Jingcong Tao et al.   DALTON TRANSACTIONS

The crystal structure of C176A mutated [Fe]-hydrogenase suggests an acyl-iron ligation in the active site iron complex

(2009) Takeshi Hiromoto et al.   FEBS LETTERS

H2Activation by a (PNP)Ir(C6H5) Complex via the Dearomatization/Aromatization Process of the PNP Ligand: A Computational Study

(2009) Guixiang Zeng et al.   INORGANIC CHEMISTRY

Catalytic hydrogenation of CO and CN bonds via heterolysis of H2 mediated by metal–sulfur bonds of rhodium and iridium thiolate complexes

(2009) Mayumi Sakamoto et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Metal−Ligand Cooperation in H2Production and H2O Decomposition on a Ru(II) PNN Complex: The Role of Ligand Dearomatization−Aromatization

(2009) Jun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen- and Oxygen-Driven Interconversion between Imido-Bridged Dirhodium(III) and Amido-Bridged Dirhodium(II) Complexes

(2009) Koji Ishiwata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic Hydrogen/Deuterium Effects in the Direct Hydrogenation of Ketones Catalyzed by a Well-Defined Ruthenium Diphosphine Diamine Complex

(2009) Marco Zimmer-De Iuliis et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclopentadienone Iron Alcohol Complexes: Synthesis, Reactivity, and Implications for the Mechanism of Iron-Catalyzed Hydrogenation of Aldehydes

(2009) Charles P. Casey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Conversion of Alcohols to Acetals and H2Catalyzed by an Acridine-Based Ruthenium Pincer Complex

(2009) Chidambaram Gunanathan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Monoiron Hydrogenase Catalysis: Hydrogen Activation with the Formation of a Dihydrogen, Fe−Hδ−···Hδ+−O, Bond and Methenyl-H4MPT+Triggered Hydride Transfer

(2009) Xinzheng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Water Splitting and Oxygen−Oxygen Bond Formation by a Mononuclear Ruthenium Complex

(2009) Xinzheng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Consecutive Thermal H2and Light-Induced O2Evolution from Water Promoted by a Metal Complex

(2009) Stephan W. Kohl et al.   SCIENCE

Ethanol as Hydrogen Donor: Highly Efficient Transfer Hydrogenations with Rhodium(I) Amides

(2008) Theo Zweifel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective Synthesis of Primary Amines Directly from Alcohols and Ammonia

(2008) Chidambaram Gunanathan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cooperating Ligands in Catalysis

(2008) Hansjörg Grützmacher   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyzed Dehydrogenative Coupling of Primary Alcohols with Water, Methanol, or Amines

(2008) Theo Zweifel et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reactions at the Ru-S Bonds of Coordinatively Unsaturated Ruthenium Complexes with Tethered 2,6-Dimesitylphenyl Thiolate

(2008) Yasuhiro Ohki et al.   Chemistry-An Asian Journal

Computational Study of the Factors Controlling Enantioselectivity in Ruthenium(II) Hydrogenation Catalysts

(2008) Devis Di Tommaso et al.   INORGANIC CHEMISTRY

New Cationic and Zwitterionic Cp*M(κ2-P,S) Complexes (M = Rh, Ir): Divergent Reactivity Pathways Arising from Alternative Modes of Ancillary Ligand Participation in Substrate Activation

(2008) Kevin D. Hesp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium-Catalyzed Dehydrogenation of Ammonia Boranes

(2008) Nicole Blaquiere et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible Heterolysis of H2Mediated by an M−S(Thiolate) Bond (M = Ir, Rh): A Mechanistic Implication for [NiFe] Hydrogenase

(2008) Yasuhiro Ohki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Indenyl Hemilability: Unveiling a Masked (η5-C5Me5)Ru(κ2-P,Carbene) Zwitterion Via Facile and Reversible Ru−C(sp3) Bond Cleavage

(2008) Matthew A. Rankin et al.   ORGANOMETALLICS

Origin of Enantioselective Hydrogenation of Ketones by RuH2(diphosphine)(diamine) Catalysts: A Theoretical Study

(2008) Tom Leyssens et al.   ORGANOMETALLICS

Isolation and Interconversion of ProticN-Heterocyclic Carbene and Imidazolyl Complexes: Application to Catalytic Dehydrative Condensation ofN-(2-Pyridyl)benzimidazole and Allyl Alcohol

(2008) Kenjirou Araki et al.   ORGANOMETALLICS

The Crystal Structure of [Fe]-Hydrogenase Reveals the Geometry of the Active Site

(2008) S. Shima et al.   SCIENCE

Prototropic rearrangements in cycloheptatrienyl PCP pincer iridium complexes

(2007) Angelika M. Winter et al.   DALTON TRANSACTIONS

Theoretical investigation on the mechanisms of transfer hydrogenation of ketones catalyzed by iridium complexes

(2007) Siwei Bi et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY