Preparation of Stable Low-Oxidation-State Group 14 Element Amidohydrides and Hydride-Mediated Ring-Expansion Chemistry of N-Heterocyclic Carbenes

Multiple-Charged P1-Centered Cations: Perspectives in Synthesis

(2012) Kai-Oliver Feldmann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CN Bond Cleavage and Ring Expansion of N-Heterocyclic Carbenes using Hydrosilanes

(2012) David Schmidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beryllium-Induced CN Bond Activation and Ring Opening of an N-Heterocyclic Carbene

(2012) Merle Arrowsmith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Two-Coordinate Acyclic Silylene

(2012) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Isolable NHC-Stabilized Silylene Radical Cation: Synthesis and Structural Characterization

(2012) Hiroaki Tanaka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond

(2012) H. Braunschweig et al.   SCIENCE

Parent Heavy Methylenes: Chemical Tricks to Access Isolable Complexes of Elusive H2E: Species (E=Ge and Sn)

(2011) Shigeyoshi Inoue et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of a Phosphine-Stabilized Silicon(II) Hydride and Its Addition to Olefins: A Catalyst-Free Hydrosilylation Reaction

(2011) Ricardo Rodriguez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stable N-Heterocyclic Carbene Complexes of Hypermetallyl Germanium(II) and Tin(II) Compounds

(2011) Nadia Katir et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis and Reactions of N-Heterocyclic Carbene Boranes

(2011) Dennis P. Curran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Dimer of Silaisonitrile with Two-Coordinate Silicon Atoms

(2011) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trapping the Parent Inorganic Ethylenes H2SiGeH2 and H2SiSnH2 in the Form of Stable Adducts at Ambient Temperature

(2011) S. M. Ibrahim Al-Rafia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin

(2011) S. M. Ibrahim Al-Rafia et al.   CHEMICAL COMMUNICATIONS

Efficient generation of stable adducts of Si(ii) dihydride using a donor–acceptor approach

(2011) S. M. Ibrahim Al-Rafia et al.   CHEMICAL COMMUNICATIONS

A stable silicon(ii) monohydride

(2011) Anukul Jana et al.   DALTON TRANSACTIONS

Silylation of N-heterocyclic carbene with aminochlorosilane and -disilane: dehydrohalogenation vs. Si–Si bond cleavage

(2011) Haiyan Cui et al.   DALTON TRANSACTIONS

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Interaction of Carbene and Olefin Donors with [Cl2PN]3: Exploration of a Reductive Pathway toward (PN)3

(2011) S. M. Ibrahim Al-Rafia et al.   INORGANIC CHEMISTRY

Cleavage of Carbene-Stabilized Disilicon

(2011) Mariham Y. Abraham et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Characterization of a Neutral Tricoordinate Organoboron Isoelectronic with Amines

(2011) R. Kinjo et al.   SCIENCE

A Water-Compatible NHC-Borane: Photopolymerizations in Water and Rate Constants for Elementary Radical Reactions

(2011) Mohamad-Ali Tehfe et al.   ACS Macro Letters

Silicon Analogues of Carboxylic Acids: Synthesis of Isolable Silanoic Acids by Donor-Acceptor Stabilization

(2010) Yun Xiong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Functionalizable Boron-Containing π-Electron Materials that Incorporate Formally Aromatic Fused Borepin Rings

(2010) Anthony Caruso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Sol–gel precursors for group 14 nanocrystals

(2010) Joel A. Kelly et al.   CHEMICAL COMMUNICATIONS

Amine− and Phosphine−Borane Adducts: New Interest in Old Molecules

(2010) Anne Staubitz et al.   CHEMICAL REVIEWS

Ammonia-Borane and Related Compounds as Dihydrogen Sources

(2010) Anne Staubitz et al.   CHEMICAL REVIEWS

[{2,6-(Me2NCH2)2C6H3}Sn(μ-OH)W(CO)5]2: A Transition-Metal-Coordinated Organotin(II) Hydroxide

(2010) Roman Jambor et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Facile Synthesis of a Rare Chlorosilylene-BH3 Adduct

(2010) Ramachandran Azhakar et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Synthesis and Structural Characterization of a Series of Dimeric Metal(II) Imido Complexes {M(μ-NAr#)}2[M = Ge, Sn, Pb; Ar#= C6H3-2,6-(C6H2-2,4,6-Me3)2] and the Related Monomeric Primary Amido Derivatives M{N(H)Ar#}2(M = Ge, Sn, Pb): Spectroscopic Manifestations of Secondary Metal−Ligand Interactions

(2010) William A. Merrill et al.   INORGANIC CHEMISTRY

Aminostannanes and aminostannylenes containing a C,N-chelated ligand

(2010) Zdeňka Padělková et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Substitution Reactions at Tetracoordinate Boron: Synthesis of N-Heterocyclic Carbene Boranes with Boron−Heteroatom Bonds

(2010) Andrey Solovyev et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

AnN-Heterocyclic Carbene−Disilyne Complex and Its Reactivity toward ZnCl2

(2010) Torahiko Yamaguchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 4- and 4,5-Functionalized Imidazol-2-ylidenes from a Single 4,5-Unsubstituted Imidazol-2-ylidene

(2010) Daniel Mendoza-Espinosa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stabilization of the Heavy Methylene Analogues, GeH2and SnH2, within the Coordination Sphere of a Transition Metal

(2010) S. M. Ibrahim Al-Rafia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbenes−Borane Complexes: A New Class of Initiators for Radical Photopolymerization

(2010) Mohamad-Ali Tehfe et al.   MACROMOLECULES

Lewis Base Stabilized Dichlorosilylene

(2009) Rajendra S. Ghadwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Main-Group-Metal Clusters Stabilized by N-Heterocyclic Carbenes

(2009) Robert Wolf et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Abnormal Reactivity of an N-Heterocyclic Carbene (NHC) with a Phosphaalkene: A Route to a 4-Phosphino-Substituted NHC

(2009) Joshua I. Bates et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Donor/acceptor stabilization of Ge(ii) dihydride

(2009) Kelsey C. Thimer et al.   CHEMICAL COMMUNICATIONS

N-Aryl substituted heterocyclic silylenes

(2009) Lingbing Kong et al.   DALTON TRANSACTIONS

Sn(I) halides: Novel binary compounds of tin and their application in synthetic chemistry

(2009) Andreas Pacher et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis and characterization of the unstable primary amido tin(ii) dimer Sn2{N(H)Dipp}4 (Dipp = C6H3-2,6-Pri2) and the first sesqui-amido hemi-chloride derivative Sn2{N(H)Dipp}3Cl: facile conversion of a primary amide to the imide (SnNDipp)4

(2008) W. Alexander Merrill et al.   DALTON TRANSACTIONS

Plasma synthesis of group IV quantum dots for luminescence and photovoltaic applications

(2008) Uwe Kortshagen et al.   PURE AND APPLIED CHEMISTRY

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE