Syntheses and Structures of Ruthenium Complexes Containing a Ru-H-Tl Three-Center-Two-Electron Bond

Competition between the Hydride Ligands of Two Types in Proton Transfer to [{κ3 -P -CH3 C(CH2 CH2 PPh2 )3 }RuH(η2 -BH4 )]

(2017) Igor E. Golub et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Molybdenum Trihydride Complexes: Computational Model of Oxidatively Induced Reductive Elimination of Dihydrogen

(2017) Lukasz Szatkowski et al.   INORGANIC CHEMISTRY

Diverse Reactivity of ECp* (E = Al, Ga) toward Low-Coordinate Transition Metal Amides [TM(N(SiMe3)2)2] (TM = Fe, Co, Zn): Insertion, Cp* Transfer, and Orthometalation

(2017) Jana Weßing et al.   INORGANIC CHEMISTRY

Ammonia Borane Dehydrogenation Catalyzed by (κ4-EP3)Co(H) [EP3 = E(CH2CH2PPh2)3; E = N, P] and H2 Evolution from Their Interaction with NH Acids

(2017) Stefano Todisco et al.   INORGANIC CHEMISTRY

Cationic, Neutral, and Anionic Hydrides of Iridium with PSiP Pincers

(2017) Elizabeth Suárez et al.   INORGANIC CHEMISTRY

Reversible Coordination of Boron–, Aluminum–, Zinc–, Magnesium–, and Calcium–Hydrogen Bonds to Bent {CuL2} Fragments: Heavy σ Complexes of the Lightest Coinage Metal

(2017) Alexandra Hicken et al.   INORGANIC CHEMISTRY

Detection of an Iridium–Dihydrogen Complex: A Proposed Intermediate in Ionic Hydrogenation

(2017) Jonathan M. Goldberg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable Dihydrogen Complexes of Cobalt(−I) Suggest an Inverse trans-Influence of Lewis Acidic Group 13 Metalloligands

(2017) Matthew V. Vollmer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural snapshots of concerted double E–H bond activation at a transition metal centre

(2017) Joseph A. B. Abdalla et al.   Nature Chemistry

Characterization of a Borane σ Complex of a Diiron Dithiolate: Model for an Elusive Dihydrogen Adduct

(2017) Noémie Lalaoui et al.   ORGANOMETALLICS

Elongated σ-Borane versus σ-Borane in Pincer–POP–Osmium Complexes

(2017) Miguel A. Esteruelas et al.   ORGANOMETALLICS

Synthesis of Iron Hydride Complexes Relevant to Hydrogen Isotope Exchange in Pharmaceuticals

(2017) Renyuan Pony Yu et al.   ORGANOMETALLICS

Approaches to Sigma Complexes via Displacement of Agostic Interactions: An Experimental and Theoretical Investigation

(2017) A. Ramaraj et al.   ORGANOMETALLICS

Hydride oxidation from a titanium–aluminum bimetallic complex: insertion, thermal and electrochemical reactivity

(2017) Alexandra C. Brown et al.   Chemical Science

Solid-state molecular organometallic chemistry. Single-crystal to single-crystal reactivity and catalysis with light hydrocarbon substrates

(2017) F. Mark Chadwick et al.   Chemical Science

A Rhodium-Pentane Sigma-Alkane Complex: Characterization in the Solid State by Experimental and Computational Techniques

(2016) F. Mark Chadwick et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The unusual hydridicity of a cobalt bound Si–H moiety

(2016) Jin Kim et al.   CHEMICAL COMMUNICATIONS

Polyhydrides of Platinum Group Metals: Nonclassical Interactions and σ-Bond Activation Reactions

(2016) Miguel A. Esteruelas et al.   CHEMICAL REVIEWS

Dihydrogen Complexation

(2016) Robert H. Crabtree   CHEMICAL REVIEWS

Reactions of Hydrosilanes with Transition Metal Complexes

(2016) Joyce Y. Corey   CHEMICAL REVIEWS

Brønsted–Lowry Acid Strength of Metal Hydride and Dihydrogen Complexes

(2016) Robert H. Morris   CHEMICAL REVIEWS

Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation

(2016) Pablo Ríos et al.   CHEMISTRY-A EUROPEAN JOURNAL

mer, fac, and Bidentate Coordination of an Alkyl-POP Ligand in the Chemistry of Nonclassical Osmium Hydrides

(2016) Miguel A. Esteruelas et al.   INORGANIC CHEMISTRY

Reversible Inter- and Intramolecular Carbon–Hydrogen Activation, Hydrogen Addition, and Catalysis by the Unsaturated Complex Pt(IPr)(SnBut3)(H)

(2016) Anjaneyulu Koppaka et al.   INORGANIC CHEMISTRY

Half-Sandwich Silane σ-Complexes of Ruthenium Supported by NHC Carbene

(2016) Van Hung Mai et al.   ORGANOMETALLICS

Formation of a σ-alkane Complex and a Molecular Rearrangement in the Solid-State: [Rh(Cyp2PCH2CH2PCyp2)(η2:η2-C7H12)][BArF4]

(2016) Alasdair I. McKay et al.   ORGANOMETALLICS

μ3-η2:η2:η2-Coordination of Primary Silane on a Triruthenium Plane

(2015) Masahiro Nagaoka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dimeric platinum–stannylene complexes by twofold ligand transfer from an NHC adduct to an organotin(ii) hydride

(2015) Christian P. Sindlinger et al.   CHEMICAL COMMUNICATIONS

Synthesis of [Pt(SnBut3)(IBut)(μ-H)]2, a Coordinatively Unsaturated Dinuclear Compound which Fragments upon Addition of Small Molecules to Form Mononuclear Pt–Sn Complexes

(2015) Anjaneyulu Koppaka et al.   INORGANIC CHEMISTRY

Heterolytic Activation of Dihydrogen Molecule by Hydroxo-/Sulfido-Bridged Ruthenium–Germanium Dinuclear Complex. Theoretical Insights

(2015) Noriaki Ochi et al.   INORGANIC CHEMISTRY

Observation of Cationic Transition Metal–Alkane Complexes with Moderate Stability in Hydrofluorocarbon Solution

(2015) Hon Man Yau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Interligand Interactions Dictate the Regioselectivity of trans-Hydrometalations and Related Reactions Catalyzed by [Cp*RuCl]. Hydrogen Bonding to a Chloride Ligand as a Steering Principle in Catalysis

(2015) Stephan M. Rummelt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Ruthenium Dihydrogen Germylene Complex and the Catalytic Synthesis of Digermoxane

(2015) Katharine A. Smart et al.   ORGANOMETALLICS

Addition of aluminium, zinc and magnesium hydrides to rhodium(iii)

(2015) Olga Ekkert et al.   Chemical Science

Silver(i) and thallium(i) cations as unsupported bridges between two metal bases

(2014) Holger Braunschweig et al.   CHEMICAL COMMUNICATIONS

Characterisation of Alkane σ-Complexes

(2014) Rowan D. Young   CHEMISTRY-A EUROPEAN JOURNAL

Cyclometalated heteronuclear Pt/Ag and Pt/Tl complexes: a structural and photophysical study

(2013) Sirous Jamali et al.   DALTON TRANSACTIONS

A Highly Efficient Luminescent Pt2Tl2 Chain with a Short TlI–TlI Interaction

(2013) Sirous Jamali et al.   INORGANIC CHEMISTRY

Multiple Si–H Bond Activations by tBu2PCH2CH2PtBu2 and tBu2PCH2PtBu2 Di(phosphine) Complexes of Rhodium and Iridium

(2013) Meg E. Fasulo et al.   ORGANOMETALLICS

Formation of sub-valent carbenoid ligands by metal-mediated dehydrogenation chemistry: coordination and activation of H2Ga{(NDippCMe)2CH}

(2013) Joshua Turner et al.   Chemical Science

Stabilization of ArSiH4−and SiH62−Anions in Diruthenium SiH σ-Complexes

(2012) Mark C. Lipke et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Spin–orbit coupling and electron correlation in relativistic configuration interaction and coupled-cluster methods

(2011) Inkoo Kim et al.   CHEMICAL PHYSICS

Reactions of Hydrosilanes with Transition Metal Complexes and Characterization of the Products

(2011) Joyce Y. Corey   CHEMICAL REVIEWS

Gallane-coordinated transition metal complexes and related compounds

(2010) Takako Muraoka et al.   COORDINATION CHEMISTRY REVIEWS

Nonclassical Ruthenium Silyl Dihydride Complexes TpRu(PPh3)(η3-HSiR3H) [Tp = Hydridotris(pyrazolyl)borate]: Catalytic Hydrolytic Oxidation of Organosilanes to Silanols with TpRu(PPh3)(η3-HSiR3H)

(2010) Ting Yan Lee et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Two-component relativistic density functional method for computing nonsingular complex linear response of molecules based on the zeroth order regular approximation

(2009) Ajitha Devarajan et al.   JOURNAL OF CHEMICAL PHYSICS

Consistent approaches to van der Waals radii for the metallic elements

(2009) Sheng-Zhi Hu et al.   ZEITSCHRIFT FUR KRISTALLOGRAPHIE

Luminescent One- And Two-Dimensional Extended Structures and a Loosely Associated Dimer Based on Platinum(II)–Thallium(I) Backbones†

(2008) Juan Forniés et al.   INORGANIC CHEMISTRY

Cp(Pri2MeP)FeH2SiR3:  Nonclassical Iron Silyl Dihydride

(2008) Dmitry V. Gutsulyak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY