Alkaline-Earth-Catalysed Cross-Dehydrocoupling of Amines and Hydrosilanes: Reactivity Trends, Scope and Mechanism

Tailored Cyclic and Linear Polycarbosilazanes by Barium-Catalyzed N−H/H−Si Dehydrocoupling Reactions

(2016) Clément Bellini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Barium-Mediated Cross-Dehydrocoupling of Hydrosilanes with Amines: A Theoretical and Experimental Approach

(2015) Clément Bellini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Dehydrocoupling: Group 2 Mediated Boron-Nitrogen Desilacoupling

(2015) David J. Liptrot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Computational Mechanistic Elucidation of the Intramolecular Aminoalkene Hydroamination Catalysed by Iminoanilide Alkaline-Earth Compounds

(2015) Sven Tobisch   CHEMISTRY-A EUROPEAN JOURNAL

Highly Fluorinated Tris(indazolyl)borate Silylamido Complexes of the Heavier Alkaline Earth Metals: Synthesis, Characterization, and Efficient Catalytic Intramolecular Hydroamination

(2015) Nuria Romero et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stoichiometric and catalytic Si–N bond formation using the p-block base Al(NMe2)3

(2015) Lucy K. Allen et al.   DALTON TRANSACTIONS

Formation of a Cationic Calcium Hydride Cluster with a “Naked” Triphenylsilyl Anion by Hydrogenolysis of Bis(triphenylsilyl)calcium

(2015) Valeri Leich et al.   INORGANIC CHEMISTRY

Yttrium-Catalyzed Amine–Silane Dehydrocoupling: Extended Reaction Scope with a Phosphorus-Based Ligand

(2015) Adi E. Nako et al.   ORGANOMETALLICS

Palladium nanoparticles supported on graphene as catalysts for the dehydrogenative coupling of hydrosilanes and amines

(2015) Juan F. Blandez et al.   Catalysis Science & Technology

Catalytic metal-free Si–N cross-dehydrocoupling

(2014) Lutz Greb et al.   CHEMICAL COMMUNICATIONS

Hydrosilylation catalysis by an earth alkaline metal silyl: synthesis, characterization, and reactivity of bis(triphenylsilyl)calcium

(2014) Valeri Leich et al.   CHEMICAL COMMUNICATIONS

Catalytic dehydrogenative Si–N coupling of pyrroles, indoles, carbazoles as well as anilines with hydrosilanes without added base

(2013) C. David F. Königs et al.   CHEMICAL COMMUNICATIONS

Mechanisms of metal-catalyzed dehydrocoupling reactions

(2013) Rory Waterman   CHEMICAL SOCIETY REVIEWS

Cyclohydroamination of Aminoalkenes Catalyzed by Disilazide Alkaline-Earth Metal Complexes: Reactivity Patterns and Deactivation Pathways

(2013) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heteroleptic Alkyl and Amide Iminoanilide Alkaline Earth and Divalent Rare Earth Complexes for the Catalysis of Hydrophosphination and (Cyclo)Hydroamination Reactions

(2013) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reaction Path Optimization without NEB Springs or Interpolation Algorithms

(2013) P. Plessow   Journal of Chemical Theory and Computation

Synthesis and Characterization of Ethylene-Bridged Copolycarbosilazane as Precursors for Silicon Carbonitride Ceramics

(2013) Dong Su et al.   JOURNAL OF THE AMERICAN CERAMIC SOCIETY

Catalysis in service of main group chemistry offers a versatile approach to p-block molecules and materials

(2013) Erin M. Leitao et al.   Nature Chemistry

Dearomatized BIAN Alkaline-Earth Alkyl Catalysts for the Intramolecular Hydroamination of Hindered Aminoalkenes

(2013) Merle Arrowsmith et al.   ORGANOMETALLICS

Hetero-dehydrocoupling of silanes and amines by heavier alkaline earth catalysis

(2013) Michael S. Hill et al.   Chemical Science

[(NHC)Yb{N(SiMe3)2}2]-Catalyzed Cross-Dehydrogenative Coupling of Silanes with Amines

(2012) Weilong Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

When Bigger Is Better: Intermolecular Hydrofunctionalizations of Activated Alkenes Catalyzed by Heteroleptic Alkaline Earth Complexes

(2012) Bo Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium acetate/base-catalyzed N-silylation of indole derivatives with hydrosilanes

(2012) Shintaro Itagaki et al.   CHEMICAL COMMUNICATIONS

Zinc-Catalyzed Dehydrogenative N-Silylation of Indoles with Hydrosilanes

(2012) Teruhisa Tsuchimoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Heteroleptic Silylamido Phenolate Complexes of Calcium and the Larger Alkaline Earth Metals: β-Agostic Ae⋅⋅⋅SiH Stabilization and Activity in the Ring-Opening Polymerization ofL-Lactide

(2012) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Effective Alkaline Earth Catalysts for the Sterically Governed Hydrophosphonylation of Aldehydes and Nonactivated Ketones

(2012) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organosilicon Molecules with Medicinal Applications

(2012) Annaliese K. Franz et al.   JOURNAL OF MEDICINAL CHEMISTRY

Ruthenium carbonyl-catalysed Si–heteroatom X coupling (X = S, O, N)

(2012) Chun Keong Toh et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Alkaline Earth Catalysis of Alkynyl Alcohol Hydroalkoxylation/Cyclization

(2012) Christine Brinkmann et al.   ORGANOMETALLICS

Inorganic block copolymer lithography

(2012) Adam Nunns et al.   POLYMER

Peralkylated Barium Complexes

(2011) Olaf Michel et al.   CHEMISTRY-A EUROPEAN JOURNAL

Barium Bis(dimethylsilyl)amide - Adduct vs. Oxo Formation

(2011) Olaf Michel et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Effect of the damping function in dispersion corrected density functional theory

(2011) Stefan Grimme et al.   JOURNAL OF COMPUTATIONAL CHEMISTRY

Use of Solution-Phase Vibrational Frequencies in Continuum Models for the Free Energy of Solvation

(2011) Raphael F. Ribeiro et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Tris(oxazolinyl)boratomagnesium-Catalyzed Cross-Dehydrocoupling of Organosilanes with Amines, Hydrazine, and Ammonia

(2011) James F. Dunne et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cation Charge Density and Precatalyst Selection in Group 2-Catalyzed Aminoalkene Hydroamination

(2011) Merle Arrowsmith et al.   ORGANOMETALLICS

Suppression of Schlenk Equilibration and Heavier Alkaline Earth Alkyl Catalysis: A Dearomatization Strategy

(2011) Merle Arrowsmith et al.   ORGANOMETALLICS

2,5-Bis{N-(2,6-diisopropylphenyl)iminomethyl}pyrrolyl Complexes of the Heavy Alkaline Earth Metals: Synthesis, Structures, and Hydroamination Catalysis

(2011) Jelena Jenter et al.   ORGANOMETALLICS

The COSMO and COSMO-RS solvation models

(2011) Andreas Klamt   Wiley Interdisciplinary Reviews-Computational Molecular Science

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

(2010) Stefan Grimme et al.   JOURNAL OF CHEMICAL PHYSICS

Iridium-Catalyzed, Silyl-Directed Borylation of Nitrogen-Containing Heterocycles

(2010) Daniel W. Robbins et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis(dimethylsilyl)amide Complexes of the Alkaline-Earth Metals Stabilized by β-Si−H Agostic Interactions: Synthesis, Characterization, and Catalytic Activity

(2010) Yann Sarazin et al.   ORGANOMETALLICS

COSMO-RS: An Alternative to Simulation for Calculating Thermodynamic Properties of Liquid Mixtures

(2010) Andreas Klamt et al.   Annual Review of Chemical and Biomolecular Engineering

Bond Activations of PhSiH3by Cp2SmH: A Mechanistic Investigation by the DFT Method

(2009) Lionel Perrin et al.   ORGANOMETALLICS

Bis(imidazolin-2-ylidene-1-yl)borate Complexes of the Heavier Alkaline Earths: Synthesis and Studies of Catalytic Hydroamination

(2009) Merle Arrowsmith et al.   ORGANOMETALLICS

Bis(trimethylsilyl)methyl Derivatives of Calcium, Strontium and Barium: Potentially Useful Dialkyls of the Heavy Alkaline Earth Elements

(2008) Mark R. Crimmin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Aminotroponiminate Complexes of the Heavy Alkaline Earth and the Divalent Lanthanide Metals as Catalysts for the Hydroamination/Cyclization Reaction

(2008) Simmi Datta et al.   ORGANOMETALLICS