Diverse Activation Modes in the Hydroboration of Aldehydes and Ketones with Germanium, Tin, and Lead Lewis Pairs

Group 14 inorganic hydrocarbon analogues

(2016) Eric Rivard   CHEMICAL SOCIETY REVIEWS

A Systematic Study of Structure and E−H Bond Activation Chemistry by Sterically Encumbered Germylene Complexes

(2016) Matthew Usher et al.   CHEMISTRY-A EUROPEAN JOURNAL

Intramolecular Tetrylene Lewis Adducts: Synthesis and Reactivity

(2016) Julia Schneider et al.   CHEMISTRY-A EUROPEAN JOURNAL

Access to Base Adducts of Low-Valent Organotin-Hydride Compounds by Controlled, Stepwise Hydrogen Abstraction from a Tetravalent Organotin Trihydride

(2016) Christian P. Sindlinger et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ring-Shaped Phosphinoamido-Magnesium-Hydride Complexes: Syntheses, Structures, Reactivity, and Catalysis

(2016) Lea Fohlmeister et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Aluminum Dihydride Working as a Catalyst in Hydroboration and Dehydrocoupling

(2016) Zhi Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enabling and Probing Oxidative Addition and Reductive Elimination at a Group 14 Metal Center: Cleavage and Functionalization of E–H Bonds by a Bis(boryl)stannylene

(2016) Andrey V. Protchenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Addition of Ethylene or Hydrogen to a Main-Group Metal Cluster under Mild Conditions

(2015) Petra Vasko et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Exploiting Electrostatics To Generate Unsaturation: Oxidative GeE Bond Formation Using a Non π-Donor Stabilized [R(L)Ge:]+ Cation

(2015) Arnab Rit et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemistry of Stannylene-Based Lewis Pairs: Dynamic Tin Coordination Switching Between Donor and Acceptor Character

(2015) Kilian M. Krebs et al.   CHEMISTRY-A EUROPEAN JOURNAL

Insertion of a Cationic Metallogermylene into E–H Bonds (E = H, B, Si)

(2015) Koya Inomata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multiple complexation of CO and related ligands to a main-group element

(2015) Holger Braunschweig et al.   NATURE

Reactions of m-Terphenyl-Stabilized Germylene and Stannylene with Water and Methanol: Oxidative Addition versus Arene Elimination and Different Reaction Pathways for Alkyl- and Aryl-Substituted Species

(2015) Jeremy D. Erickson et al.   ORGANOMETALLICS

A nitrogen-base catalyzed generation of organotin(ii) hydride from an organotin trihydride under reductive dihydrogen elimination

(2015) Christian P. Sindlinger et al.   Chemical Science

Catalytic Hydroboration of Carbonyl Derivatives, Imines, and Carbon Dioxide

(2015) Che Chang Chong et al.   ACS Catalysis

Metal-Free σ-Bond Metathesis in 1,3,2-Diazaphospholene-Catalyzed Hydroboration of Carbonyl Compounds

(2014) Che Chang Chong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dihydrogen Activation by a Silylium Silylene Frustrated Lewis Pair and the Unexpected Isomerization Reaction of a Protonated Silylene

(2014) Annemarie Schäfer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Application of the Donor–Acceptor Concept to Intercept Low Oxidation State Group 14 Element Hydrides using a Wittig Reagent as a Lewis Base

(2014) Anindya K. Swarnakar et al.   INORGANIC CHEMISTRY

Reaction Mechanisms of Small-Molecule Activation by Amidoditetrylynes R2N–EE–NR2 (E = Si, Ge, Sn)

(2014) Markus Hermann et al.   INORGANIC CHEMISTRY

Low Coordinate Germanium(II) and Tin(II) Hydride Complexes: Efficient Catalysts for the Hydroboration of Carbonyl Compounds

(2014) Terrance J. Hadlington et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis and Unexpected Reactivity of Germyliumylidene Hydride [:GeH]+ Stabilized by a Bis(N-heterocyclic carbene)borate Ligand

(2014) Yun Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrogen abstraction from organotin di- and trihydrides by N-heterocyclic carbenes: a new method for the preparation of NHC adducts to tin(ii) species and observation of an isomer of a hexastannabenzene derivative [R6Sn6]

(2014) Christian P. Sindlinger et al.   Chemical Science

Phosphastannirane: A Phosphorus/Tin(II) Lewis Pair that Undergoes Alkyne and Alkene Addition

(2013) Sarah Freitag et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of gaseous PH3 with low coordinate diaryltetrylene compounds

(2013) Jonathan W. Dube et al.   CHEMICAL COMMUNICATIONS

EH3(E=N, P, As) and H2Activation with N-Heterocyclic Silylene and Germylene Homologues

(2013) Marta Erminia Alberto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Facile, High-Yield Functionalization of Germanium and Tin by Oxidative Insertion of Tetrelenes into the E–H Bonds of Inorganic Acids (E = C, N, O, F): Arene Elimination versus Oxidative Addition and Formation of a Germanium Cation–Water Complex

(2013) Zachary D. Brown et al.   ORGANOMETALLICS

Stannylene-Based Lewis Pairs

(2013) Sarah Freitag et al.   ORGANOMETALLICS

Silylium Ion/Phosphane Lewis Pairs

(2013) Matti Reißmann et al.   ORGANOMETALLICS

The Facile Reduction of Carbon Dioxide to Carbon Monoxide with an Amido-Digermyne

(2012) Jiaye Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Monomeric Sn(ii) and Ge(ii) hydrides supported by a tridentate pincer-based ligand

(2012) Shabana Khan et al.   CHEMICAL COMMUNICATIONS

Magnesium-catalysed hydroboration of aldehydes and ketones

(2012) Merle Arrowsmith et al.   CHEMICAL COMMUNICATIONS

Preparation of Stable Low-Oxidation-State Group 14 Element Amidohydrides and Hydride-Mediated Ring-Expansion Chemistry of N-Heterocyclic Carbenes

(2012) S. M. Ibrahim Al-Rafia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Group 14 Hydrides with Low Valent Elements for Activation of Small Molecules

(2011) Swadhin K. Mandal et al.   ACCOUNTS OF CHEMICAL RESEARCH

Metal-Free Activation of EH3 (E=P, As) by an Ylide-like Silylene and Formation of a Donor-Stabilized Arsasilene with a HSiAsH Subunit

(2010) Carsten Präsang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tandem Frustrated Lewis Pair/Tris(pentafluorophenyl)borane-Catalyzed Deoxygenative Hydrosilylation of Carbon Dioxide

(2010) Andreas Berkefeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

Reactions of Tin(II) Hydride Species with Unsaturated Molecules

(2009) Anukul Jana et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Frustrated Lewis Pairs: Metal-free Hydrogen Activation and More

(2009) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Donor/acceptor stabilization of Ge(ii) dihydride

(2009) Kelsey C. Thimer et al.   CHEMICAL COMMUNICATIONS

Reactivity of germanium(II) hydride with nitrous oxide, trimethylsilyl azide, ketones, and alkynes and the reaction of a methyl analogue with trimethylsilyl diazomethane

(2009) Anukul Jana et al.   DALTON TRANSACTIONS

Hydrostannylation of Ketones and Alkynes with LSnH [L = HC(CMeNAr)2, Ar = 2,6-iPr2C6H3]

(2009) Anukul Jana et al.   INORGANIC CHEMISTRY

A Germanium(II) Hydride as an Effective Reagent for Hydrogermylation Reactions

(2009) Anukul Jana et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction of Hydrogen or Ammonia with Unsaturated Germanium or Tin Molecules under Ambient Conditions: Oxidative Addition versus Arene Elimination

(2009) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylene- and Germylene-Mediated C−H Activation: Reaction with Alkanes, Ethers, and Amines

(2009) Randon H. Walker et al.   ORGANOMETALLICS

Reversible Reactions of Ethylene with Distannynes Under Ambient Conditions

(2009) Y. Peng et al.   SCIENCE

Diarylstannylene Activation of Hydrogen or Ammonia with Arene Elimination

(2008) Yang Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY