Calcium-Catalyzed Arene C−H Bond Activation by Low-Valent AlI

Nucleophilic Aromatic Substitution at Benzene with Powerful Strontium Hydride and Alkyl Complexes

(2019) Bastian Rösch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reversible, Room-Temperature C—C Bond Activation of Benzene by an Isolable Metal Complex

(2019) Jamie Hicks et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Inert C–H Bond Transformations Enabled by Organometallic Manganese Catalysis

(2018) Yuanyuan Hu et al.   ACCOUNTS OF CHEMICAL RESEARCH

The Arene-Limited Nondirected C-H Activation of Arenes

(2018) Philipp Wedi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Increasing Catalyst Efficiency in C−H Activation Catalysis

(2018) Tobias Gensch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxidative Addition and Reductive Elimination at Main-Group Element Centers

(2018) Terry Chu et al.   CHEMICAL REVIEWS

A combined experimental and computational study on the reaction of fluoroarenes with Mg–Mg, Mg–Zn, Mg–Al and Al–Zn bonds

(2018) Clare Bakewell et al.   Chemical Science

Room temperature catalytic carbon–hydrogen bond alumination of unactivated arenes: mechanism and selectivity

(2018) Thomas N. Hooper et al.   Chemical Science

Facile Benzene Reduction by a Ca2+ /AlI Lewis Acid/Base Combination

(2018) Steffen Brand et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Road Travelled: After Main-Group Elements as Transition Metals

(2018) Catherine Weetman et al.   ChemCatChem

Synthesis, structure and reaction chemistry of a nucleophilic aluminyl anion

(2018) Jamie Hicks et al.   NATURE

3d Transition Metals for C–H Activation

(2018) Parthasarathy Gandeepan et al.   CHEMICAL REVIEWS

Diverse Reactivity of ECp* (E = Al, Ga) toward Low-Coordinate Transition Metal Amides [TM(N(SiMe3)2)2] (TM = Fe, Co, Zn): Insertion, Cp* Transfer, and Orthometalation

(2017) Jana Weßing et al.   INORGANIC CHEMISTRY

Metal-catalyzed C H activation/functionalization: The fundamentals

(2017) Fares Roudesly et al.   JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL

A Stable Neutral Compound with an Aluminum–Aluminum Double Bond

(2017) Prasenjit Bag et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocalcium-mediated nucleophilic alkylation of benzene

(2017) Andrew S. S. Wilson et al.   SCIENCE

Alkaline earths as main group reagents in molecular catalysis

(2016) Michael S. Hill et al.   CHEMICAL SOCIETY REVIEWS

Ligand coordination modulates reductive elimination from aluminium(iii)

(2016) Stephanie J. Urwin et al.   DALTON TRANSACTIONS

Oxidative Addition of π-Bonds and σ-Bonds to an Al(I) Center: The Second-Order Carbene Property of the AlNacNac Compound

(2016) Wolfgang W. Schoeller et al.   INORGANIC CHEMISTRY

Frustrated Lewis Pair Chemistry: Development and Perspectives

(2015) Douglas W. Stephan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective electrophilic borylation of haloarenes

(2015) Alessandro Del Grosso et al.   CHEMICAL COMMUNICATIONS

para-C–H Borylation of Benzene Derivatives by a Bulky Iridium Catalyst

(2015) Yutaro Saito et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evolution of C–H Bond Functionalization from Methane to Methodology

(2015) John F. Hartwig   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A meta-selective C–H borylation directed by a secondary interaction between ligand and substrate

(2015) Yoichiro Kuninobu et al.   Nature Chemistry

Oxidative Addition of σ Bonds to an Al(I) Center

(2014) Terry Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Intermolecular C-H Silylation of Arenes with High Steric Regiocontrol

(2014) C. Cheng et al.   SCIENCE

Directed ortho-meta'- and meta-meta'-dimetalations: A template base approach to deprotonation

(2014) A. J. Martinez-Martinez et al.   SCIENCE

Synthesis of a Dialumene-Benzene Adduct and Its Reactivity as a Synthetic Equivalent of a Dialumene

(2013) Tomohiro Agou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Reductive elimination: a pathway to low-valent aluminium species

(2013) Chelladurai Ganesamoorthy et al.   CHEMICAL COMMUNICATIONS

Directed Functionalization of CH Bonds: Now alsometaSelective

(2012) Thanh Truong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-catalyzed C–H borylation of quinolines and unsymmetrical 1,2-disubstituted benzenes: insights into steric and electronic effects on selectivity

(2012) Hazmi Tajuddin et al.   Chemical Science

Introduction to Selective Functionalization of C−H Bonds

(2010) Robert H. Crabtree   CHEMICAL REVIEWS

From Limestone to Catalysis: Application of Calcium Compounds as Homogeneous Catalysts

(2010) Sjoerd Harder   CHEMICAL REVIEWS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

Main-group elements as transition metals

(2010) Philip P. Power   NATURE

Convenient synthesis and crystal structure of a monomeric zinc hydride complex with a three-coordinate metal center

(2009) Jan Spielmann et al.   CHEMICAL COMMUNICATIONS

C−H Activation for the Construction of C−B Bonds

(2009) Ibraheem A. I. Mkhalid et al.   CHEMICAL REVIEWS

Mechanisms of C–H bond activation: rich synergy between computation and experiment

(2009) Youcef Boutadla et al.   DALTON TRANSACTIONS

Iridium complexes of N-heterocyclic carbenes in C–H borylation using energy efficient microwave technology: influence of structure, ligand donor strength and counter ion on catalytic activity

(2009) Christoph F. Rentzsch et al.   GREEN CHEMISTRY

Stable Adducts of a Dimeric Magnesium(I) Compound

(2008) Shaun P. Green et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The molecular and electronic structure of carbon–hydrogen bond activation and transition metal assisted hydrogen transfer

(2008) Benjamin Alan Vastine et al.   COORDINATION CHEMISTRY REVIEWS

Catalytic Phenylborylation Reaction by Iridium(0) Nanoparticles Produced from Hydridoiridium Carborane

(2008) Zhu Yinghuai et al.   INORGANIC CHEMISTRY