To Rearrange or not to Rearrange: Reactivity of NHCs towards Chloro- and HydrostannanesR2SnCl2(R= Me, Ph) and Ph3SnH

Access to Base Adducts of Low-Valent Organotin-Hydride Compounds by Controlled, Stepwise Hydrogen Abstraction from a Tetravalent Organotin Trihydride

(2016) Christian P. Sindlinger et al.   CHEMISTRY-A EUROPEAN JOURNAL

25 years of N-heterocyclic carbenes: activation of both main-group element–element bonds and NHCs themselves

(2016) Sabrina Würtemberger-Pietsch et al.   DALTON TRANSACTIONS

Diamidocarbene Induced B–H Activation: A New Class of Initiator-Free Olefin Hydroboration Reagents

(2016) Dominika N. Lastovickova et al.   ORGANOMETALLICS

The reductive P–P coupling of primary and secondary phosphines mediated by N-heterocyclic carbenes

(2015) Heidi Schneider et al.   CHEMICAL COMMUNICATIONS

Room Temperature Ring Expansion of N-Heterocyclic Carbenes and BB Bond Cleavage of Diboron(4) Compounds

(2015) Sabrina Pietsch et al.   CHEMISTRY-A EUROPEAN JOURNAL

Effects of the electronic structure of five-membered N-heterocyclic carbenes on insertion of silanes and boranes into the NHC C–N bond

(2015) Kalon J. Iversen et al.   DALTON TRANSACTIONS

Activation of N-Heterocyclic Carbenes by {BeH2} and {Be(H)(Me)} Fragments

(2015) Merle Arrowsmith et al.   ORGANOMETALLICS

SHELXT– Integrated space-group and crystal-structure determination

(2015) George M. Sheldrick   Acta Crystallographica A-Foundation and Advances

Intramolecular CN Bond Activation and Ring-Expansion Reactions of N-Heterocyclic Carbenes

(2014) Patrick Hemberger et al.   CHEMISTRY-A EUROPEAN JOURNAL

Carbene-9-BBN Ring Expansions as a Route to Intramolecular Frustrated Lewis Pairs for CO2Reduction

(2014) Tongen Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Facile Route to Backbone-Tethered N-Heterocyclic Carbene (NHC) Ligands via NHC to aNHC Rearrangement in NHC Silicon Halide Adducts

(2014) Heidi Schneider et al.   CHEMISTRY-A EUROPEAN JOURNAL

Systematic Investigation of the Ring-Expansion Reaction of N-Heterocyclic Carbenes with an Iminoborane Dihydride

(2014) Daniel Franz et al.   Chemistry-An Asian Journal

Activation of the C–N bond of N-heterocyclic carbenes by inorganic elements

(2014) Kalon J. Iversen et al.   DALTON TRANSACTIONS

Mechanistic Investigations on E–N Bond-Breaking and Ring Expansion for N-Heterocyclic Carbene Analogues Containing the Group 14 Elements (E)

(2014) Ming-Der Su   INORGANIC CHEMISTRY

Assessing the reactivity of theN,N′-diamidocarbenes toward compounds containing early p-block elements

(2014) Dominika N. Lastovickova et al.   JOURNAL OF PHYSICAL ORGANIC CHEMISTRY

Boron–Boron Multiple Bonding: From Charged to Neutral and Back Again

(2014) Holger Braunschweig et al.   ORGANOMETALLICS

Hydrogen abstraction from organotin di- and trihydrides by N-heterocyclic carbenes: a new method for the preparation of NHC adducts to tin(ii) species and observation of an isomer of a hexastannabenzene derivative [R6Sn6]

(2014) Christian P. Sindlinger et al.   Chemical Science

Unimolecular Reaction Mechanism of an Imidazolin-2-ylidene: An iPEPICO Study on the Complex Dissociation of an Arduengo-Type Carbene

(2013) Patrick Hemberger et al.   CHEMISTRY-A EUROPEAN JOURNAL

A theoretical study on the ring expansion of NHCs by silanes

(2013) Kalon J. Iversen et al.   DALTON TRANSACTIONS

A Dihydrodisilene Transition Metal Complex from an N-Heterocyclic Carbene-Stabilized Silylene Monohydride

(2013) Shigeyoshi Inoue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism and Regioselectivity of C–N Bond Cleavage and Ring Expansion of N-Heterocyclic Carbenes

(2013) Ran Fang et al.   ORGANOMETALLICS

Comparison of the Mechanism of Borane, Silane, and Beryllium Hydride Ring Insertion into N-Heterocyclic Carbene C–N Bonds: A Computational Study

(2013) Kalon J. Iversen et al.   ORGANOMETALLICS

Carbene-Bound Borane and Silane Adducts: A Comprehensive DFT Study on Their Stability and Propensity for Hydride-Mediated Ring Expansion

(2013) Mohammad R. Momeni et al.   ORGANOMETALLICS

CN Bond Cleavage and Ring Expansion of N-Heterocyclic Carbenes using Hydrosilanes

(2012) David Schmidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beryllium-Induced CN Bond Activation and Ring Opening of an N-Heterocyclic Carbene

(2012) Merle Arrowsmith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Preparation of Stable Low-Oxidation-State Group 14 Element Amidohydrides and Hydride-Mediated Ring-Expansion Chemistry of N-Heterocyclic Carbenes

(2012) S. M. Ibrahim Al-Rafia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ambient-Temperature Isolation of a Compound with a Boron-Boron Triple Bond

(2012) H. Braunschweig et al.   SCIENCE

Carbene-stabilized main group diatomic allotropes

(2011) Yuzhong Wang et al.   DALTON TRANSACTIONS

Carbene Stabilization of Highly Reactive Main-Group Molecules

(2011) Yuzhong Wang et al.   INORGANIC CHEMISTRY

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of SiH, BH, and PH Bonds at a Single Nonmetal Center

(2010) Guido D. Frey et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ammonia N–H activation by a N,N′-diamidocarbene

(2010) Todd W. Hudnall et al.   CHEMICAL COMMUNICATIONS

N-Heterocyclic Carbene Analogues with Low-Valent Group 13 and Group 14 Elements: Syntheses, Structures, and Reactivities of a New Generation of Multitalented Ligands†

(2010) Matthew Asay et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbene Mediated Activation of Tetravalent Silicon Compounds: A Critical Evaluation

(2010) Matthew J. Fuchter   CHEMISTRY-A EUROPEAN JOURNAL

Stable N-Heterocyclic Carbene Adducts of Arylchlorosilylenes and Their Germanium Homologues

(2010) Alexander C. Filippou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Stable singlet carbenes as mimics for transition metal centers

(2010) David Martin et al.   Chemical Science

N-Heterocyclic Carbene Stabilized Digermanium(0)

(2009) Anastas Sidiropoulos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unique homonuclear multiple bonding in main group compounds

(2009) Yuzhong Wang et al.   CHEMICAL COMMUNICATIONS

Stable Noncyclic Singlet Carbenes

(2009) Joan Vignolle et al.   CHEMICAL REVIEWS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

Cleavage of a N−H Bond of Ammonia at Room Temperature by a Germylene

(2009) Anukul Jana et al.   INORGANIC CHEMISTRY

AnN,N′-Diamidocarbene: Studies in C−H Insertion, Reversible Carbonylation, and Transition-Metal Coordination Chemistry

(2009) Todd W. Hudnall et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Stable Silicon(0) Compound with a Si=Si Double Bond

(2008) Y. Wang et al.   SCIENCE