Recent Progress in the Transition Metal Catalyzed Synthesis of Indoles

Investigation of rubidium(I) ion solvation in liquid ammonia using QMCF-MD simulation and NBO analysis of first solvation shell structure

(2018) Yuniawan Hidayat et al.   JOURNAL OF MOLECULAR MODELING

Copper-Catalyzed Synthesis of Multisubstituted Indoles through Tandem Ullmann-Type C–N Formation and Cross-dehydrogenative Coupling Reactions

(2018) Yue Li et al.   JOURNAL OF ORGANIC CHEMISTRY

One-Pot Synthesis of Indole-3-acetic Acid Derivatives through the Cascade Tsuji–Trost Reaction and Heck Coupling

(2018) Dongsheng Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of topologically constrained naphthalimide appended palladium(ii)–N-heterocyclic carbene complexes – insights into additive controlled product selectivity

(2018) Pradeep Kumar Reddy Panyam et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of cis-5,5a,6,10b-Tetrahydroindeno[2,1-b]indoles through Palladium-Catalyzed Decarboxylative Coupling of Vinyl Benzoxazinanones with Arynes

(2018) Shengguo Duan et al.   ORGANIC LETTERS

Palladium-Catalyzed Cascade Approach to 12-(Aryl)indolo[1,2-c]quin­azolin-6(5H)-ones

(2018) Antonia Iazzetti et al.   SYNTHESIS-STUTTGART

Palladium-catalyzed intramolecular aerobic C-H amination of enamines for the synthesis of 2-trifluoromethylindoles

(2018) Feng Wei et al.   TETRAHEDRON

N,N-Dimethylformamide-stabilized palladium nanoclusters as a catalyst for Larock indole synthesis

(2018) Kaito Onishi et al.   RSC Advances

Metal-Catalyzed Synthesis of Substituted Indoles

(2018) So Won Youn et al.   Asian Journal of Organic Chemistry

The regioselective synthesis of 2-phosphinoylindoles via Rh(iii)-catalyzed C–H activation

(2018) Huanan Wang et al.   Organic Chemistry Frontiers

Pd(II)–Ni(II) Pyrazolate Framework as Active and Recyclable Catalyst for the Hydroamination of Terminal Alkynes

(2018) Francisco G. Cirujano et al.   TOPICS IN CATALYSIS

Synthesis and Anticancer Evaluation of 2,3-Disubstituted Indoles Derived from Azobenzenes and Internal Olefins

(2017) Yongguk Oh et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Direct Access to Indoles by IrIII -Catalyzed C-H Functionalization of Acetanilides with Diazo Compounds

(2017) Pitambar Patel et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Mechanochemical indole synthesis by rhodium-catalysed oxidative coupling of acetanilides and alkynes under solventless conditions in a ball mill

(2017) Gary N. Hermann et al.   GREEN CHEMISTRY

Synthesis of 3-phenylsulfonyl-2-trifluoromethyl-1H-indoles: A copper catalyzed cyclization approach

(2017) Simon E. Lopez et al.   JOURNAL OF FLUORINE CHEMISTRY

Ruthenium-Catalyzed 1,6-Aromatic Enamide–Silylalkyne Cycloisomerization: Approach to 2,3-Disubstituted Indoles

(2017) Kohei Takamoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Atom-Economic Synthesis of Pentaleno[2,1-b]indoles via Tandem Cyclization of Alkynones Initiated by Aminopalladation

(2017) Junjie Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Sequential Vinylic C–H Arylation/Amination of 2-Vinylanilines with Aryl boronic Acids: Access to 2-Arylindoles

(2017) Ruixia Yu et al.   JOURNAL OF ORGANIC CHEMISTRY

The Development of a Palladium-Catalyzed Tandem Addition/Cyclization for the Construction of Indole Skeletons

(2017) Shuling Yu et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 2,3-Disubstituted NH Indoles via Rhodium(III)-Catalyzed C–H Activation of Arylnitrones and Coupling with Diazo Compounds

(2017) Xin Guo et al.   JOURNAL OF ORGANIC CHEMISTRY

A Divergent Approach to Indoles and Oxazoles from Enamides by Directing-Group-Controlled Cu-Catalyzed Intramolecular C–H Amination and Alkoxylation

(2017) Chiaki Yamamoto et al.   JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed Cycloisomerization of 2-Alkynylanilides: Synthesis of 3-Substituted Indoles by 1,2-Carbon Migration

(2017) Takuma Watanabe et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 1H-indole-3-sulfonates via palladium-catalyzed tandem reactions of 2-alkynyl arylazides with sulfonic acids

(2017) Xiaoxiang Zhang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Indole synthesis by palladium-catalyzed tandem allylic isomerization – furan Diels–Alder reaction

(2017) Jie Xu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium-catalyzed redox-neutral coupling of phenidones with alkynes

(2017) Zhoulong Fan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Gold(i)-catalyzed synthesis of 2-substituted indoles from 2-alkynylnitroarenes with diboron as reductant

(2017) Wenqiang Fu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-catalyzed tandem addition/cyclization in aqueous medium: synthesis of 2-arylindoles

(2017) Shuling Yu et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

N-Heterocyclic carbene palladium-catalyzed cascade annulation/alkynylation of 2-alkynylanilines with terminal alkynes

(2017) Jianxiao Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

One-pot synthesis of 2,3-difunctionalized indoles via Rh(iii)-catalyzed carbenoid insertion C–H activation/cyclization

(2017) Honggui Lv et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed Dehydrogenative Difunctionalization of Aminoalkenes with Aminals as Oxidants and Electrophiles

(2017) Lixin Li et al.   ORGANIC LETTERS

Synthesis of Benzo[1,4]heterocycles using Palladium Catalyzed Heck Reaction to Vinylogous Carbonates/Carbamates: Unexpected Formation of Indoles via Carbopalladation Intercepted by Nucleopalladation

(2017) Santosh J. Gharpure et al.   ORGANIC LETTERS

Csp2–Csp2 and Csp2–N Bond Formation in a One-Pot Reaction between N-Tosylhydrazones and Bromonitrobenzenes: An Unexpected Cyclization to Substituted Indole Derivatives

(2017) Tourin Bzeih et al.   ORGANIC LETTERS

Palladium-Catalyzed Intramolecular Arylative Carboxylation of Allenes with CO2 for the Construction of 3-Substituted Indole-2-carboxylic Acids

(2017) Yuki Higuchi et al.   ORGANIC LETTERS

A C–H Activation-Based Strategy for N-Amino Azaheterocycle Synthesis

(2017) Pengfei Shi et al.   ORGANIC LETTERS

Palladium-catalyzed synthesis of indole fused coumarins via cross-dehydrogenative coupling

(2017) Amrita Dey et al.   TETRAHEDRON LETTERS

Copper-mediated intramolecular aza-Wacker-type cyclization of 2-alkenylanilines toward 3-aryl indoles

(2017) Rui Yang et al.   TETRAHEDRON LETTERS

Beyond C2 and C3: Transition-Metal-Catalyzed C–H Functionalization of Indole

(2017) Jamie A. Leitch et al.   ACS Catalysis

Continuous flow synthesis of indoles by Pd-catalyzed deoxygenation of 2-nitrostilbenes with carbon monoxide

(2017) Gabriel Glotz et al.   RSC Advances

Facile synthesis of 1-aminoindoles via Rh(iii)-catalysed intramolecular three-component annulation

(2017) Zi Yang et al.   Organic Chemistry Frontiers

Facile Synthesis of 2,3-Disubstituted Indoles by NBS/CuCl Mediated Oxidative Cyclization ofN-Aryl Enamines

(2017) Fang-Zhi Hu et al.   ChemistrySelect

Pd/Norbornene: A Winning Combination for Selective Aromatic Functionalization via C–H Bond Activation

(2016) Nicola Della Ca’ et al.   ACCOUNTS OF CHEMICAL RESEARCH

Commercial Supported Gold Nanoparticles Catalyzed Alkyne Hydroamination and Indole Synthesis

(2016) Shengzong Liang et al.   ADVANCED SYNTHESIS & CATALYSIS

Multiple Roles of the Pyrimidyl Group in the Rhodium-Catalyzed Regioselective Synthesis and Functionalization of Indole-3-carboxylic Acid Esters

(2016) Hui Jiang et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Synthesis of Indole Derivatives From Pyrimidyl-Substituted Anilines and Diazo Compounds

(2016) Ke Yu et al.   ADVANCED SYNTHESIS & CATALYSIS

Electrochemical C−H/N−H Functionalization for the Synthesis of Highly Functionalized (Aza)indoles

(2016) Zhong-Wei Hou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ruthenium(II)-Catalyzed C−H Activation of Imidamides and Divergent Couplings with Diazo Compounds: Substrate-Controlled Synthesis of Indoles and 3H-Indoles

(2016) Yunyun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cationic Cobalt(III) Catalyzed Indole Synthesis: The Regioselective Intermolecular Cyclization of N-Nitrosoanilines and Alkynes

(2016) Yujie Liang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Eight-Step Enantioselective Total Synthesis of (−)-Cycloclavine

(2016) Stephanie R. McCabe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt(III)-Catalyzed Redox-Neutral Synthesis of Unprotected Indoles Featuring an N−N Bond Cleavage

(2016) Andreas Lerchen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cascade photoredox/gold catalysis: access to multisubstituted indoles via aminoarylation of alkynes

(2016) Chuanhua Qu et al.   CHEMICAL COMMUNICATIONS

Linear Polystyrene-stabilized Pt Nanoparticles Catalyzed Indole Synthesis in Water via Aerobic Alcohol Oxidation

(2016) Atsushi Ohtaka et al.   CHEMISTRY LETTERS

Rhodium(I)-Catalyzed Benzannulation of Heteroaryl Propargylic Esters: Synthesis of Indoles and Related Heterocycles

(2016) Xiaoxun Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cobalt(III)-Catalyzed Intramolecular Cross-Dehydrogenative C−H/X−H Coupling: Efficient Synthesis of Indoles and Benzofurans

(2016) Jayanta Ghorai et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium(II)-Catalyzed Traceless C−H Functionalization Using an N−N Bond as an Internal Oxidant

(2016) Shuguang Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Progress in the Synthesis of 2,3-Disubstituted Indole by Cyclization

(2016) Ting Liang et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalysed Carbenoid C(sp2)-H Functionalisation of Aniline Substrates with α-Diazo Esters: Formation of Oxindoles and Characterisation/Utility of an Intermediate-Like Rhodacycle

(2016) Srinivasarao Allu et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Regioselective Arylative Ring-Closing Reaction of 2-Alkynylphenyl Derivatives: Formation of Arylated Benzoxazin-2-ones, Benzoxazin-2-amines and 2,3-Disubstituted Indoles

(2016) Hideki Minami et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 2,3-Disubstituted Indoles and Benzofurans by the Tandem Reaction of Rhodium(II)-Catalyzed Intramolecular C–H Insertion and Oxygen-Mediated Oxidation

(2016) Hongjuan Shen et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 1,2-Disubstituted Indoles from α-Aminonitriles and 2-Halobenzyl Halides

(2016) Anne-Katrin Bachon et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of 3-Cyano-1H-indoles and Their 2′-Deoxyribonucleoside Derivatives through One-Pot Cascade Reactions

(2016) Bin Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Synthesis of Indoles and Isoquinolines with in Situ Generated Phosphinimine

(2016) Qi Zhou et al.   JOURNAL OF ORGANIC CHEMISTRY

Access to Indole-Fused Polyheterocycles via Pd-Catalyzed Base-Free Intramolecular Cross Dehydrogenative Coupling

(2016) Chao Cheng et al.   JOURNAL OF ORGANIC CHEMISTRY

Double Palladium Catalyzed Reductive Cyclizations. Synthesis of 2,2′-, 2,3′-, and 3,3′-Bi-1H-indoles, Indolo[3,2-b]indoles, and Indolo[2,3-b]indoles

(2016) Nurul H. Ansari et al.   JOURNAL OF ORGANIC CHEMISTRY

Substrate-Controlled Transformation of Azobenzenes to Indazoles and Indoles via Rh(III)-Catalysis

(2016) Shangjun Cai et al.   JOURNAL OF ORGANIC CHEMISTRY

One-Pot Synthesis of Substituted Benzo[b]furans and Indoles from Dichlorophenols/Dichloroanilines Using a Palladium–Dihydroxyterphenylphosphine Catalyst

(2016) Miyuki Yamaguchi et al.   JOURNAL OF ORGANIC CHEMISTRY

Iodine/Copper Iodide-Mediated C–H Functionalization: Synthesis of Imidazo[1,2-a]pyridines and Indoles from N-Aryl Enamines

(2016) Jing Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Indole Synthesis via Cyclative Formation of 2,3-Dizincioindoles and Regioselective Electrophilic Trapping

(2016) Laurean Ilies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Remote C−H alkylation and C−C bond cleavage enabled by an in situ generated palladacycle

(2016) Juntao Ye et al.   Nature Chemistry

A dramatic enhancing effect of InBr3 towards the oxidative Sonogashira cross-coupling reaction of 2-ethynylanilines

(2016) A. Ikeda et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(III)-Catalyzed Cascade Cyclization/Electrophilic Amidation for the Synthesis of 3-Amidoindoles and 3-Amidofurans

(2016) Zhiyong Hu et al.   ORGANIC LETTERS

2-(Trifluoromethyl)indoles via Pd(0)-Catalyzed C(sp3)–H Functionalization of Trifluoroacetimidoyl Chlorides

(2016) Julia Pedroni et al.   ORGANIC LETTERS

Cu(OAc)2-Mediated Cascade Annulation of Diarylalkyne Sulfonamides through Dual C–N Bond Formation: Synthesis of 5,10-Dihydroindolo[3,2-b]indoles

(2016) Junchao Yu et al.   ORGANIC LETTERS

Indole Synthesis via Cobalt(III)-Catalyzed Oxidative Coupling of N-Arylureas and Internal Alkynes

(2016) Zhuo-Zhuo Zhang et al.   ORGANIC LETTERS

Synthesis of Indole-2-carboxylate Derivatives via Palladium-Catalyzed Aerobic Amination of Aryl C–H Bonds

(2016) Kyle Clagg et al.   ORGANIC LETTERS

A Mild and General Larock Indolization Protocol for the Preparation of Unnatural Tryptophans

(2016) Kangway V. Chuang et al.   ORGANIC LETTERS

A Cascade Phosphinoylation/Cyclization/Desulfonylation Process for the Synthesis of 3-Phosphinoylindoles

(2016) Yuzhen Gao et al.   ORGANIC LETTERS

Rhodium-Catalyzed Cyclization of 2-Ethynylanilines in the Presence of Isocyanates: Approach toward Indole-3-carboxamides

(2016) Akiho Mizukami et al.   ORGANIC LETTERS

N-Methyl Transfer Induced Copper-Mediated Oxidative Diamination of Alkynes

(2016) Hon Eong Ho et al.   ORGANIC LETTERS

Rhodium-Catalyzed Cycloisomerization of 2-Silylethynyl Phenols and Anilines via 1,2-Silicon Migration

(2016) Hiroshi Kanno et al.   ORGANIC LETTERS

C–H Activation-Based Traceless Synthesis via Electrophilic Removal of a Directing Group. Rhodium(III)-Catalyzed Entry into Indoles from N-Nitroso and α-Diazo-β-keto Compounds

(2016) Jie Wang et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Synthesis of N-Unprotected Indoles from Imidamides and Diazo Ketoesters via C–H Activation and C–C/C–N Bond Cleavage

(2016) Zisong Qi et al.   ORGANIC LETTERS

Co(III)-Catalyzed, Internal and Terminal Alkyne-Compatible Synthesis of Indoles

(2016) Shuguang Zhou et al.   ORGANIC LETTERS

A Versatile, Traceless C–H Activation-Based Approach for the Synthesis of Heterocycles

(2016) Shuguang Zhou et al.   ORGANIC LETTERS

Lewis Acid Catalysis with Cationic Dinuclear Gold(II,II) and Gold(III,III) Phosphorus Ylide Complexes

(2016) Benjamin R. Reiner et al.   ORGANOMETALLICS

Catalytic Synthesis of Substituted Indoles and Quinolines from the Dehydrative C–H Coupling of Arylamines with 1,2- and 1,3-Diols

(2016) Hanbin Lee et al.   ORGANOMETALLICS

Copper-catalyzed synthesis of 2,3-disubstituted indoles from ortho-haloanilines and β-keto esters/β-diketone

(2016) Xiao-Guang Liu et al.   TETRAHEDRON

A simple and efficient approach to the N -amination of oxazolidinones using monochloroamine

(2016) Uyen Huynh et al.   TETRAHEDRON LETTERS

Pd-Catalyzed α-Arylation of Sulfones in a Three-Component Synthesis of 3-[2-(Phenyl/methylsulfonyl)ethyl]indoles

(2016) Daniel Solé et al.   ACS Catalysis

Catalytic α-Arylation of Imines Leading to N-Unprotected Indoles and Azaindoles

(2016) Enrico Marelli et al.   ACS Catalysis

An Oxidant-Free Strategy for Indole Synthesis via Intramolecular C–C Bond Construction under Visible Light Irradiation: Cross-Coupling Hydrogen Evolution Reaction

(2016) Cheng-Juan Wu et al.   ACS Catalysis

Rhodium-Catalyzed Annulation of Tertiary Aniline N-Oxides to N-Alkylindoles: Regioselective C–H Activation, Oxygen-Atom Transfer, and N-Dealkylative Cyclization

(2016) Bin Li et al.   ACS Catalysis

Control over Organometallic Intermediate Enables Cp*Co(III) Catalyzed Switchable Cyclization to Quinolines and Indoles

(2016) Qingquan Lu et al.   ACS Catalysis

Selective Synthesis of Indoles by Cobalt(III)-Catalyzed C–H/N–O Functionalization with Nitrones

(2016) Hui Wang et al.   ACS Catalysis

Highly selective intramolecular addition of C–N and S–N bonds to alkynes catalyzed by palladium: a practical access to two distinct functional indoles

(2016) Chenglin Wu et al.   RSC Advances

Synthesis of spiro isoindolinone-indolines and 1,2-disubstituted indoles from 2-iodobenzamide derivatives

(2016) Bharath Kumar Villuri et al.   RSC Advances

Gold-catalyzed formation of indole derivatives from 2-alkynyl arylazides and oxygen-containing heterocycles

(2016) Xiaoxiang Zhang et al.   RSC Advances

Synthesis of 3-arylindole derivatives from nitroalkane precursors

(2016) Chia-Yu Huang et al.   RSC Advances

Iridium(iii)- and rhodium(iii)-catalyzed coupling of anilines with α-diazoesters via chelation-assisted C–H activation

(2016) Guo-Dong Tang et al.   Organic Chemistry Frontiers

Computational exploration of the reaction mechanism of the Cu+-catalysed synthesis of indoles fromN-aryl enaminones

(2016) Carlos E. P. Bernardo et al.   Royal Society Open Science

One-Pot Synthesis of Indoles from Alkynes and Anilines through Palladium-Catalyzed Double C-H Activation using O2as the oxidant

(2016) Dunfa Shi et al.   ChemistrySelect

Homogeneous Gold-Catalyzed Cyclization Reactions of Alkynes withN- andS-Nucleophiles

(2015) Wouter Debrouwer et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Redox-Neutral CH Annulation of Arylnitrones and Alkynes for the Synthesis of Indole Derivatives

(2015) Zhi Zhou et al.   ADVANCED SYNTHESIS & CATALYSIS

Iron-Catalyzed Intramolecular C(sp2 )−H Amination

(2015) Isabel T. Alt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed CH Annulation of Nitrones with Alkynes: A Regiospecific Route to Unsymmetrical 2,3-Diaryl-Substituted Indoles

(2015) Hao Yan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed CH Annulation of Anthranils with Alkynes: A Facile, Flexible, and Atom-Economical Synthesis of Unprotected 7-Acylindoles

(2015) Hongming Jin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diastereo-Divergent Synthesis of Saturated Azaheterocycles Enabled bytBuOK-Mediated Hydroamination of Alkenyl Hydrazones

(2015) Atsushi Kaga et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd0-Catalyzed Intramolecular α-Arylation of Sulfones: Domino Reactions in the Synthesis of Functionalized Tetrahydroisoquinolines

(2015) Daniel Solé et al.   CHEMISTRY-A EUROPEAN JOURNAL

Ruthenium(II)-Catalyzed CH Functionalizations with Allenes: Versatile Allenylations and Allylations

(2015) Sachiyo Nakanowatari et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold-Catalyzed Tandem Reactions of 2-Alkynyl Arylazides and Carboxylic Acids for the Synthesis of 1H-Indol-3-yl Esters

(2015) Xiaoxiang Zhang et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Selective Cyclization of Arylnitrones to Indolines under External Oxidant-Free Conditions: Dual Role of Rh(III) Catalyst in the C–H Activation and Oxygen Atom Transfer

(2015) Ramesh B. Dateer et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Lewis Acid Mediated Vinylogous Additions of Enol Nucleophiles into an α,β-Unsaturated Platinum Carbene

(2015) Paul A. Allegretti et al.   ORGANIC LETTERS

Simple and Mild Synthesis of Indoles via Hydroamination Reaction Catalysed by NHC–Gold Complexes: Looking for Optimized Conditions

(2015) Malina Michalska et al.   SYNLETT

Indole synthesis through transition metal-catalyzed C–H activation

(2015) Tenglong Guo et al.   TETRAHEDRON LETTERS

Rh(iii)-catalyzed synthesis of 1-aminoindole derivatives from 2-acetyl-1-arylhydrazines and diazo compounds in water

(2014) Yujie Liang et al.   CHEMICAL COMMUNICATIONS

Dehydrative C–H/N–OH Functionalizations in H2O by Ruthenium(II) Catalysis: Subtle Effect of Carboxylate Ligands and Mechanistic Insight

(2014) Fanzhi Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Substituted 3-Indolylimines and Indole-3-carboxaldehydes by Rhodium(II)-Catalyzed Annulation

(2014) Basker Rajagopal et al.   ORGANIC LETTERS

Rhodium-Catalyzed Oxidative Annulation of Hydrazines with Alkynes Using a Nitrobenzene Oxidant

(2014) Deng Yuan Li et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Redox-Neutral C–H Activation via N–N Cleavage: Synthesis of N-Substituted Indoles

(2014) Zhenxing Zhang et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed Indole Synthesis Using N–N Bond as an Internal Oxidant

(2013) Baoqing Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Improved indole syntheses from anilines and vicinal diols by cooperative catalysis of ruthenium complex and acid

(2013) Min Zhang et al.   RSC Advances

Synthesis of Pyrroles, Indoles, and Carbazoles through Transition-Metal-Catalyzed CH Functionalization

(2013) Naohiko Yoshikai et al.   Asian Journal of Organic Chemistry

Efficient and Versatile Synthesis of Indoles from Enamines and Imines by Cross-Dehydrogenative Coupling

(2012) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Progress in palladium-based catalytic systems for the sustainable synthesis of annulated heterocycles: a focus on indole backbones

(2012) Mélanie Platon et al.   CHEMICAL SOCIETY REVIEWS

A General Synthesis of Indole-3-carboxylic Esters by Palladium-Catalyzed Direct Oxidative Carbonylation of 2-Alkynylaniline Derivatives

(2012) Bartolo Gabriele et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Ruthenium-Catalyzed Oxidative C–H Bond Olefination of N-Methoxybenzamides Using an Oxidizing Directing Group

(2012) Bin Li et al.   ORGANIC LETTERS

Indole synthesis – something old, something new

(2012) Martyn Inman et al.   Chemical Science

Update 1 of: Synthesis and Functionalization of Indoles Through Palladium-Catalyzed Reactions

(2011) Sandro Cacchi et al.   CHEMICAL REVIEWS

Ruthenium-Catalyzed C–H/N–O Bond Functionalization: Green Isoquinolone Syntheses in Water

(2011) Lutz Ackermann et al.   ORGANIC LETTERS

Indole synthesis: a review and proposed classification

(2011) Douglass F. Taber et al.   TETRAHEDRON

Multicomponent Cascade Reactions: A Novel and Expedient Approach to Functionalized Indoles by an Unprecedented Nucleophilic Addition-Heterocyclization-Oxidative Alkoxycarbonylation Sequence

(2010) Bartolo Gabriele et al.   ADVANCED SYNTHESIS & CATALYSIS

Iridium- and ruthenium-catalysed synthesis of 2,3-disubstituted indoles from anilines and vicinal diols

(2010) Matyas Tursky et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Ruthenium-catalysed synthesis of 2- and 3-substituted quinolines from anilines and 1,3-diols

(2010) Rune Nygaard Monrad et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of 2-Indolylphosphines by Palladium-Catalyzed Annulation of 1-Alkynylphosphine Sulfides with 2-Iodoanilines

(2010) Azusa Kondoh et al.   ORGANIC LETTERS

Dirhodium(II)-Catalyzed Intramolecular CH Amination of Aryl Azides

(2008) Meihua Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Synthesis of Quinoline-3-Carboxylic Esters and Indol-2-Acetic Esters by Palladium-Catalyzed Carbonylation of 1-(2-Aminoaryl)-2-Yn-1-Ols

(2008) Bartolo Gabriele et al.   JOURNAL OF ORGANIC CHEMISTRY