Journal
CHINESE JOURNAL OF ORGANIC CHEMISTRY
Volume 35, Issue 7, Pages 1469-1474Publisher
SCIENCE PRESS
DOI: 10.6023/cjoc201501020
Keywords
2-alkynyl arylazides; tandem reactions; carboxylic acids; 1H-indol-3-yl esters
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Funding
- Young National Natural Science Foundation of China [21302096]
- Young Natural Science Foundation of Jiangsu Province [BK20130962]
- Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
- National Natural Science Foundation of China [21372117]
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1H-Indol-3-yl acetates are very important indole derivatives, which can be found in many bioactive compounds and natural products. In this work, 1H-indol-3-yl acetates were efficiently prepared via alpha-imino gold carbenes generated by gold-catalyzed reactions of 2-alkynyl arylazides. A very simple and general method for the synthesis of 1H-indol-3-yl acetates was provided after examining the substrates scope.
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