Journal
ORGANIC LETTERS
Volume 20, Issue 5, Pages 1417-1420Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.8b00192
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Funding
- Shenzhen Science and Technology Innovation Committee [JSGG20160229150510483, JCYJ 20150529153646078]
- NSFC [21672017, 21732001, 21290183, 21472072]
- 111 Program of MOE
- Program for Changjiang Scholars and Innovative Research Team in University [PCSIRT: IRT_15R28]
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A novel palladium-catalyzed decarboxylative coupling reaction of vinyl benzoxazinanones with arynes which may feature an intramolecular nucleophilic attack of an amino group at the central carbon of pi-allylpalladium intermediate has been developed. The cis-5,5a,6,10b-tetrahydroindeno[2,1-b]indoles were generated in moderate to good yields. One key to the success of the present reaction was to achieve comparable rates for the palladium-catalyzed decarboxylation and aryne formation steps.
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