Journal
ORGANIC LETTERS
Volume 18, Issue 7, Pages 1654-1657Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.6b00529
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Funding
- ACT-C from JST (Japan)
- MEXT (Japan) [26102004, 25105714]
- Grants-in-Aid for Scientific Research [25105714, 15H06201, 26102004] Funding Source: KAKEN
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It has been established that a cationic rhodium(I)/BINAP complex catalyzes the cycloisomerization of 2-silylethynylphenols, leading to 3-silylbenzofurans, via 1,2-silicon migration. Similarly, the cycloisomerization of 2-silylethynylanilines, leading to 3-silylindoles, via 1,2-silicon migration was catalyzed by a cationic rhodium(I)/H-8-BINAP complex.
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