Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 22, Pages 11501-11507Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.6b02160
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Funding
- National Natural Science Foundation of China [21325209, 81402798, 81521005]
- Shanghai Municipal Committee of Science and Technology [14xd1404400]
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A base-free process to access indole-fused polyheterocycles via a highly efficient and atom-economic palladium-catalyzed intramolecular cross dehydrogenetive coupling (CDC) reaction of 4-aniline substituted coumarins, quinolinones, and pyrones has been developed. A wide range of indolo[3,2-c]coumarins, indolo[3,2-c]quinolinones, and indolo[3,2-c]pyrones can be facilely afforded in good to excellent yields (up to 99%).
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