Journal
JOURNAL OF ORGANIC CHEMISTRY
Volume 81, Issue 5, Pages 1858-1869Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.5b02659
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- Rhineland Palatinate Center for Natural Products Research
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The alpha-alkylation of deprotonated Strecker products derived from primary amines and aromatic aldehydes with 2-halobenzyl halides furnishes intermediates that can be cyclized to 1,2-disubstituted indoles in moderate to high yields (up to 94% over two steps) by microwave-assisted copper- or palladium-catalyzed intramolecular cross-coupling.
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