Journal
ADVANCED SYNTHESIS & CATALYSIS
Volume 357, Issue 14-15, Pages 2975-3006Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.201500520
Keywords
amines; gold catalysis; homogeneous catalysis; hydroamination; sulfides
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This review covers the formation of N- and S-containing heterocycles, initiated by gold-catalyzed nucleophilic attack of N- or S-nucleophiles onto alkynes. These types of nucleophiles have been somewhat overlooked as compared to their C- or O-counterparts in other reviews. In this particular work, their intramolecular gold-mediated attack onto alkynes is reviewed in depth. It is structured in such a fashion that the reader will get a clear view of which substrates react in which cyclization mode.
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