Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 139, Issue 23, Pages 7749-7752Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.7b04564
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Funding
- MEXT KAKENHI Grant [JP23105543, JP25105747]
- Taisho Pharmaceutical Co., Ltd. Award in Synthetic Organic Chemistry, Japan
- Grants-in-Aid for Scientific Research [17K05817] Funding Source: KAKEN
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We developed ruthenium-catalyzed cycloisomerization of alkynylanilides that gave 3-substituted indoles in high yields. The reaction proceeded via the disubstituted vinylidene ruthenium complex that was formed by the 1,2-carbon migration.
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