Further Developments and Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis

Pd-Catalyzed Decarboxylative Asymmetric Allylic Alkylation: Development, Mechanistic Understanding and Recent Advances

(2019) Jinju James et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Synthesis of Silicon-Stereogenic Vinylhydrosilanes by Cobalt-Catalyzed Regio- and Enantioselective Alkyne Hydrosilylation with Dihydrosilanes

(2018) Huanan Wen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-Catalyzed Enantioselective [6+4] Cycloaddition of Vinyl Oxetanes with Azadienes to Access Ten-Membered Heterocycles

(2018) Ya-Nong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereodivergent Synthesis of Tetrahydrofuroindoles through Pd-Catalyzed Asymmetric Dearomative Formal [3+2] Cycloaddition

(2018) Qiang Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis Acid Catalyzed Enantioselective Desymmetrization of Donor-Acceptor meso -Diaminocyclopropanes

(2018) Daniele Perrotta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Chiral Cyclopent-2-enones by Nickel-Catalyzed Desymmetrization of Malonate Esters

(2018) Somnath Narayan Karad et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Asymmetric Aminohydroxylation of 1,3-Dienes

(2018) Hong-Cheng Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd/Cu dual catalysis: highly enantioselective access to α-substituted α-amino acids and α-amino amides

(2018) Xiaohong Huo et al.   CHEMICAL COMMUNICATIONS

Enantioselective nickel-catalyzed arylative intramolecular 1,4-allylations

(2018) Thi Le Nhon Nguyen et al.   CHEMICAL COMMUNICATIONS

Highly enantioselective synthesis of trifluoromethyl cyclopropanes by using Ru(ii)–Pheox catalysts

(2018) Manato Kotozaki et al.   CHEMICAL COMMUNICATIONS

Cu(ii)–tBu–PHOX catalyzed enantioselective malonate addition onto 3-hydroxy 2-oxindoles: application in the synthesis of dimeric pyrroloindoline alkaloids

(2018) K. Naresh Babu et al.   CHEMICAL COMMUNICATIONS

Renaissance of pyridine-oxazolines as chiral ligands for asymmetric catalysis

(2018) Guoqiang Yang et al.   CHEMICAL SOCIETY REVIEWS

Substrate and Catalyst Effects in the Enantioselective Copper-Catalysed C-H Insertion Reactions of α-Diazo-β-oxo Sulfones

(2018) Amy E. Shiely et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

CuI -Catalysed Enantioselective Alkyl 1,4-Additions to (E )-Nitroalkenes and Cyclic Enones with Phosphino-Oxazoline Ligands

(2018) Minkyeong Shin et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

P-Stereogenic and Non-P-Stereogenic Ir–MaxPHOX in the Asymmetric Hydrogenation of N-Aryl Imines. Isolation and X-ray Analysis of Imine Iridacycles

(2018) Ernest Salomó et al.   JOURNAL OF ORGANIC CHEMISTRY

Metal-Controlled Switching of Enantioselectivity in the Mukaiyama–Michael Reaction of α,β-Unsaturated 2-Acyl Imidazoles Catalyzed by Chiral Metal–Pybox Complexes

(2018) Subhrajit Rout et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis and Application of Hexamethyl-1,1′-spirobiindane-Based Phosphine-Oxazoline Ligands in Ni-Catalyzed Asymmetric Arylation of Cyclic Aldimines

(2018) Weiye Sun et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective 1,2-Difunctionalization of 1,3-Butadiene by Sequential Alkylation and Carbonyl Allylation

(2018) Yang Xiong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Synthesis of α,α-Disubstituted α-Amino Acids via Synergistic Cu/Ir Catalysis

(2018) Liang Wei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Regiodivergent Synthesis of Chiral Pyrrolidines with Two Quaternary Stereocenters via Ligand-Controlled Copper(I)-Catalyzed Asymmetric 1,3-Dipolar Cycloadditions

(2018) Shan Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Dearomative trans-1,2-Carboamination

(2018) Lucas W. Hernandez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intermolecular Pd-Catalyzed Hydroalkylation of Acyclic 1,3-Dienes with Activated Pronucleophiles

(2018) Nathan J. Adamson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ir/Cu Dual Catalysis: Enantio- and Diastereodivergent Access to α,α-Disubstituted α-Amino Acids Bearing Vicinal Stereocenters

(2018) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Highly Enantioselective Hydrosilylation of Unactivated Terminal Alkenes

(2018) Biao Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Enantioselective Ring Opening of Cyclic Diaryliodoniums toward the Synthesis of Chiral Diarylmethanes

(2018) Bin Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dibenzofuran-4,6-bis(oxazoline) (DBFOX). A novel trans-chelating bis(oxazoline) ligand for asymmetric reactions

(2018) Kennosuke Itoh et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Di-/Perfluoroalkylation of β-Ketoesters Enabled by Cooperative Photoredox/Nickel Catalysis

(2018) Jing Liu et al.   ORGANIC LETTERS

Synthesis of Benzyl Amines via Copper-Catalyzed Enantioselective Aza-Friedel–Crafts Addition of Phenols to N-Sulfonyl Aldimines

(2018) Jonathan M. Shikora et al.   ORGANIC LETTERS

Palladium-Catalyzed Enantioselective Synthesis of Cyclic Sulfamidates and Application to a Synthesis of Verubecestat

(2018) Wenyong Chen et al.   ORGANIC LETTERS

Asymmetric Formal Synthesis of (−)-Cephalotaxine via Palladium-Catalyzed Enantioselective Tsuji Allylation

(2018) Zhi-Wei Zhang et al.   ORGANIC LETTERS

Diastereo- and Enantioselective Dearomative [3 + 2] Cycloaddition Reaction of 2-Nitrobenzofurans with 3-Isothiocyanato Oxindoles

(2018) Jian-Qiang Zhao et al.   ORGANIC LETTERS

Asymmetric Catalytic [4 + 2] Cycloaddition via Cu–Allenylidene Intermediate: Stereoselective Synthesis of Tetrahydroquinolines Fused with a γ-Lactone Moiety

(2018) Hao Chen et al.   ORGANIC LETTERS

Highly Enantioselective Nickel-Catalyzed Oxa-[3+3]-annulation of Phenols with Benzylidene Pyruvates for Chiral Chromans

(2018) Hai Ren et al.   ORGANIC LETTERS

Total Synthesis of (R)-Sarkomycin Methyl Ester via Regioselective Intermolecular Pauson–Khand Reaction and Iridium-Catalyzed Asymmetric Isomerization

(2018) Albert Cabré et al.   ORGANIC LETTERS

Asymmetric Construction of 3-Azabicyclo[3.1.0]hexane Skeleton with Five Contiguous Stereogenic Centers by Cu-Catalyzed 1,3-Dipolar Cycloaddition of Trisubstituted Cyclopropenes

(2018) Hua Deng et al.   ORGANIC LETTERS

Asymmetric [4 + 2]-Cycloaddition of Copper–Allenylidenes with Hexahydro-1,3,5-triazines: Access to Chiral Tetrahydroquinazolines

(2018) Danqing Ji et al.   ORGANIC LETTERS

Tandem catalysis for asymmetric coupling of ethylene and enynes to functionalized cyclobutanes

(2018) Vinayak Vishnu Pagar et al.   SCIENCE

Highly enantioselective cyclopropanation of trisubstituted olefins

(2018) Jun Li et al.   Science China-Chemistry

Chromium-Catalyzed Asymmetric Dearomatization–Addition Reactions of Halomethyloxazoles and Indoles

(2018) Wei-Min He et al.   SYNTHESIS-STUTTGART

A chiral nickel DBFOX complex as a bifunctional catalyst for visible-light-promoted asymmetric photoredox reactions

(2018) Xiang Shen et al.   Chemical Science

Ni(II)-catalyzed asymmetric alkenylations of ketimines

(2018) Mao Quan et al.   Nature Communications

Copper-Catalyzed Stereo- and Enantioselective 1,4-Protosilylation of α,β-Unsaturated Ketimines To Synthesize Functionalized Allylsilanes

(2018) Bing-Chao Da et al.   ACS Catalysis

Merging Photoredox and Copper Catalysis: Enantioselective Radical Cyanoalkylation of Styrenes

(2018) Wanxing Sha et al.   ACS Catalysis

Practical synthesis of enantiopure benzylamines by catalytic hydrogenation or transfer hydrogenation reactions in isopropanol using a Ru-pybox catalyst

(2018) E. de Julián et al.   Organic Chemistry Frontiers

A copper(i)-catalyzed asymmetric Mannich reaction of glycine Schiff bases with isatin-derived ketimines: enantioselective synthesis of 3-substituted 3-aminooxindoles

(2018) Jing-Yan Zhu et al.   Organic Chemistry Frontiers

Highly enantioselective Ir/f-amphox-catalyzed hydrogenation of ketoamides: efficient access to chiral hydroxy amides

(2018) Yang Hu et al.   Organic Chemistry Frontiers

Nickel-catalyzed enantioselective sequential Nazarov cyclization/decarboxylation

(2018) Heyi Zhang et al.   Organic Chemistry Frontiers

Enhanced Reactivity by Torsional Strain of Cyclic Diaryliodonium in Cu-Catalyzed Enantioselective Ring-Opening Reaction

(2018) Kun Zhao et al.   Chem

Zn-Catalyzed Diastereo- and Enantioselective Dearomative [3+2] Cycloaddition Reaction of 2-Nitroindoles and 2-Nitrobenzothiophenes

(2018) Jian-Qiang Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Regioselective and Stereoselective [3+3] Annulation of Ketones Derived Azomethine Ylides with 2-Indolylethylenes: Direct Access to Highly Substituted Tetrahydro-γ-Carbolines

(2018) Yang-Zi Liu et al.   ADVANCED SYNTHESIS & CATALYSIS

Zinc-Catalyzed Enantioselective Dearomative [3+2] Cycloaddition Reaction of 3-Nitrobenzothiophenes and 3-Nitrothieno[2,3-b ]yridine with 3-Isothiocyanato Oxindoles

(2018) Deng-Feng Yue et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Asymmetric Ring-Opening of Cyclic Diaryliodonium with Benzylic and Aliphatic Amines

(2018) Shibo Xu et al.   ADVANCED SYNTHESIS & CATALYSIS

Iridium-Catalyzed Asymmetric Hydrogenation of Halogenated Ketones for the Efficient Construction of Chiral Halohydrins

(2018) Congcong Yin et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper(II)/RuPHOX-Catalyzed Enantioselective Mannich-Type Reaction of Glycine Schiff Bases with Cyclic Ketimines

(2018) Qihang Shao et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Enantioselective Synthesis of β-Amino Alcohols Featuring Tetrasubstituted Tertiary Carbons

(2018) Lan Tian et al.   ADVANCED SYNTHESIS & CATALYSIS

Diversiform Reactivity of Naphthols in Asymmetric Dearomatization or O-Alkylation Reactions with Aziridines

(2018) Linqing Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Ir-SpinPHOX Catalyzed Enantioselective Hydrogenation of 3-Ylidenephthalides

(2018) Yao Ge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Chemo- and Stereoselective Catalyst-Controlled Allylic C−H Insertion and Cyclopropanation Using Donor/Donor Carbenes

(2018) Dong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Friedel-Crafts Alkylation Reactions of β-Naphthols with Donor-Acceptor Aminocyclopropanes

(2018) Man Zhu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective Synthesis of Acyclic Quaternary Centers: Palladium-Catalyzed Decarboxylative Allylic Alkylation of Fully Substituted Acyclic Enol Carbonates

(2018) Eric J. Alexy et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Allylic C–H Alkylation via Palladium(II)/cis-ArSOX Catalysis

(2018) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Trifluoromethylalkynylation of Alkenes via Copper-Catalyzed Radical Relay

(2018) Liang Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Chiral Cyclohexyl-Fused Spirobiindanes: Practical Synthesis, Ligand Development, and Asymmetric Catalysis

(2018) Zhiyao Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Enantioselective Reductive Diarylation of Activated Alkenes by Domino Cyclization/Cross-Coupling

(2018) Kuai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereo- and Enantioselective Synthesis of Fluorine Motifs with Two Contiguous Stereogenic Centers

(2018) Sudipta Ponra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Ferrocene-Based NH-Free Phosphine-Oxazoline Ligand for Iridium-Catalyzed Asymmetric Hydrogenation of Ketones

(2018) Yanzhao Wang et al.   ORGANIC LETTERS

Cu-Catalyzed Enantioselective Atropisomer Synthesis via Thiolative Ring Opening of Five-Membered Cyclic Diaryliodoniums

(2018) Mengqing Hou et al.   ORGANIC LETTERS

Catalytic Enantioselective Decarboxylative Mannich-Type Reaction of N-Unprotected Isatin-Derived Ketimines

(2018) Masanao Sawa et al.   ORGANIC LETTERS

Palladium-Catalyzed Enantioselective Csp3–Csp3 Cross-Coupling for the Synthesis of (Poly)fluorinated Chiral Building Blocks

(2018) Yanhui Lu et al.   ORGANIC LETTERS

New spiro phosphinooxazolines for palladium-catalyzed asymmetric allylic amination

(2018) Yanfeng Gao et al.   TETRAHEDRON LETTERS

Development and Mechanistic Investigations of Enantioselective Pd-Catalyzed Intermolecular Hydroaminations of Internal Dienes

(2018) Sangjune Park et al.   ACS Catalysis

N,O- vs N,C-Chelation in Half-Sandwich Iridium Complexes: A Dramatic Effect on Enantioselectivity in Asymmetric Transfer Hydrogenation of Ketones

(2018) Gang Zhou et al.   ACS Catalysis

Controlled Synthesis of Enantioselective 1-Aminoindenes via Cobalt-Catalyzed [3 + 2] Annulation Reaction

(2018) Min-Hsien Chen et al.   ACS Catalysis

Synergistic Cu/Pd Catalysis for Enantioselective Allylation of Ketimine Esters: The Direct Synthesis of α-Substituted α-Amino Acids and 2H- Pyrrols

(2018) Liang Wei et al.   ADVANCED SYNTHESIS & CATALYSIS

Development of and Recent Advances in Pd-Catalyzed Decarboxylative Asymmetric Protonation

(2018) Cian Kingston et al.   JOURNAL OF ORGANIC CHEMISTRY

Enol Acetates: Versatile Substrates for the Enantioselective Intermolecular Tsuji Allylation

(2018) Ji Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(II)-Catalyzed Asymmetric Photoredox Reactions: Enantioselective Alkylation of Imines Driven by Visible Light

(2018) Yanjun Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Enantioselective Si–H Bond Insertions

(2018) Haorui Gu et al.   ORGANIC LETTERS

Stereoselective Allylic Alkylation of 1-Pyrroline-5-carboxylic Esters via a Pd/Cu Dual Catalysis

(2018) Penglin Liu et al.   ORGANIC LETTERS

Enantioselective [3 + 2] Cycloaddition Reaction of Ethynylethylene Carbonates with Malononitrile Enabled by Organo/Metal Cooperative Catalysis

(2018) Yu-Chen Zhang et al.   ORGANIC LETTERS

Enantioselective Aromatic Sulfide Oxidation and Tandem Kinetic Resolution Using Aqueous H2O2and Chiral Iron-Bis(oxazolinyl)bipyridine Catalysts

(2017) Angela Jalba et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Application of a One-Pot Friedel-Crafts Alkylation/Michael Addition Methodology to the Asymmetric Synthesis of Ergoline Derivatives

(2017) Christina Despotopoulou et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Fast, solvent-free and highly enantioselective fluorination of β-keto esters catalyzed by chiral copper complexes in a ball mill

(2017) Yifeng Wang et al.   GREEN CHEMISTRY

Iron-Catalyzed Asymmetric Nitro-Mannich Reaction

(2017) Agata Dudek et al.   JOURNAL OF ORGANIC CHEMISTRY

Fluorous l-Carbidopa Precursors: Highly Enantioselective Synthesis and Computational Prediction of Bioactivity

(2017) Albert Granados et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantiodivergent Synthesis of Tertiary α-Aryl 1-Indanones: Evidence Toward Disparate Mechanisms in the Palladium-Catalyzed Decarboxylative Asymmetric Protonation

(2017) Cian Kingston et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective and Site-Specific Allylic Alkylation of Amino Acids and Small Peptides via a Pd/Cu Dual Catalysis

(2017) Xiaohong Huo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Cobalt-Catalyzed Hydrosilylation of Alkenes

(2017) Biao Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Intermolecular Addition of Aliphatic Amines to Acyclic Dienes with a Pd–PHOX Catalyst

(2017) Nathan J. Adamson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of (+)-Pancratistatins via Catalytic Desymmetrization of Benzene

(2017) Lucas W. Hernandez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Dearomative syn-1,4-Carboamination

(2017) Mikiko Okumura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling To Access 1,1-Diarylalkanes

(2017) Kelsey E. Poremba et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes

(2017) James R. Smith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Enantioselective Reductive Cross-Coupling of Styrenyl Aziridines

(2017) Brian P. Woods et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric conjugate additions of 2-substituted benzofuran-3(2H)-ones to α,β-unsaturated ketones catalyzed by chiral copper complexes

(2017) Haojiang Wang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Pd(0)-Catalysed asymmetric reductive Heck-type cyclization of (Z)-1-iodo-1,6-dienes and enantioselective synthesis of quaternary tetrahydropyridines

(2017) Longlei Hou et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective copper catalysed intramolecular C–H insertion reactions of α-diazo-β-keto sulfones, α-diazo-β-keto phosphine oxides and 2-diazo-1,3-diketones; the influence of the carbene substituent

(2017) Amy E. Shiely et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Three-Step Synthesis of Homo-β-proline: A Donor–Acceptor Cyclopropane as Key Intermediate

(2017) Ludwig K. A. Pilsl et al.   ORGANIC LETTERS

Nickel Catalyzed Regio-, Diastereo-, and Enantioselective Cross-Coupling of 3,4-Epoxyalcohol with Aryl Iodides

(2017) Amit Banerjee et al.   ORGANIC LETTERS

Iridium-Catalyzed Asymmetric Hydrogenation of 2H-Chromenes: A Highly Enantioselective Approach to Isoflavan Derivatives

(2017) Jingzhao Xia et al.   ORGANIC LETTERS

Enantioselective and Diastereoselective Construction of Chiral Amino Alcohols by Iridium–f-Amphox-Catalyzed Asymmetric Hydrogenation via Dynamic Kinetic Resolution

(2017) Weilong Wu et al.   ORGANIC LETTERS

Development of Biligands Magnesium Catalysis in Asymmetric Conjugate Reactions of C3-Pyrrolyl-Oxindoles

(2017) Kezhou Wang et al.   ORGANIC LETTERS

Enantioselective Iridium-Catalyzed Hydrogenation of α-Keto Amides to α-Hydroxy Amides

(2017) Guoxian Gu et al.   ORGANIC LETTERS

Total Synthesis of (−)-Rhazinilam and Formal Synthesis of (+)-Eburenine and (+)-Aspidospermidine: Asymmetric Cu-Catalyzed Propargylic Substitution

(2017) Andrej Shemet et al.   ORGANIC LETTERS

Asymmetric Friedel–Crafts/Michael Reaction of Indoles and Pyrroles with Coumarin-3-carbonylates

(2017) Irina Beletskaya et al.   SYNTHESIS-STUTTGART

Synthesis of [2.2]paracyclophane-based bidentate oxazoline–carbene ligands for the asymmetric 1,2-silylation of N -tosylaldimines

(2017) Xichao Wang et al.   TETRAHEDRON-ASYMMETRY

Enantioselective, convergent synthesis of the ineleganolide core by a tandem annulation cascade

(2017) Robert A. Craig et al.   Chemical Science

Enantioselective Narasaka–Heck cyclizations: synthesis of tetrasubstituted nitrogen-bearing stereocenters

(2017) Nicholas J. Race et al.   Chemical Science

Utilization of CO2 as a C1 Building Block in a Tandem Asymmetric A3 Coupling-Carboxylative Cyclization Sequence to 2-Oxazolidinones

(2017) Xiao-Tong Gao et al.   ACS Catalysis

The facile and stereoselective synthesis of pyrrolidine β-amino acids via copper(i)-catalyzed asymmetric 1,3-dipolar cycloaddition

(2017) Fu-Sheng He et al.   Organic Chemistry Frontiers

Asymmetric hydrogenation of α-hydroxy ketones with an iridium/f-amphox catalyst: efficient access to chiral 1,2-diols

(2017) Weilong Wu et al.   Organic Chemistry Frontiers

Iridium catalysts with modular axial-unfixed biphenyl phosphine–oxazoline ligands: asymmetric hydrogenation of α,β-unsaturated carboxylic acids

(2017) Qian Wang et al.   Organic Chemistry Frontiers

Ir/BiphPHOX-catalyzed asymmetric hydrogenation of 3-substituted 2,5-dihydropyrroles and 2,5-dihydrothiophene 1,1-dioxides

(2017) Ke Meng et al.   Organic Chemistry Frontiers

Ni(ii)-Catalyzed enantioselective Mukaiyama–Mannich reaction between silyl enol ethers and cyclic N-sulfonyl α-ketiminoesters

(2017) Lei Xie et al.   Organic Chemistry Frontiers

Cu(i)-catalyzed Michael addition of ketiminoesters to β-trifluoromethyl β,β-disubstituted enones: rapid access to 1-pyrrolines bearing a quaternary all-carbon stereocenter

(2017) Bing Liu et al.   Organic Chemistry Frontiers

Efficient access to chiral 1,2-amino alcohols via Ir/f-amphox-catalyzed asymmetric hydrogenation of α-amino ketones

(2017) Yang Hu et al.   Organic Chemistry Frontiers

Catalytic Enantioselective Cyano-Trifluoromethylation of Styrenes

(2017) Wanxing Sha et al.   ChemistrySelect

Palladium-Catalyzed Highly Stereoselective Dearomative [3 + 2] Cycloaddition of Nitrobenzofurans

(2017) Qiang Cheng et al.   Chem

Palladium(II)-Catalyzed Enantioselective Reactions Using COP Catalysts

(2016) Jeffrey S. Cannon et al.   ACCOUNTS OF CHEMICAL RESEARCH

Development of a Continuous-Flow Microreactor for Asymmetric Sulfoxidation Using a Biomimetic Manganese Catalyst

(2016) Wen Dai et al.   ADVANCED SYNTHESIS & CATALYSIS

Friedel-Crafts Reaction of Indoles with Isatin-Derived β,γ-Unsaturated α-Keto Esters Using a BINOL-Derived Bisoxazoline (BOX)/Copper(II) Complex as Catalyst

(2016) Nai-Kai Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Copper(II)-Catalyzed Conjugate Addition of Indoles to β-Substituted Unsaturated Acyl Phosphonates

(2016) Hong-Li Ma et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper(I)-Catalyzed Asymmetric 1,3-Dipolar [3+4] Cycloaddition of Nitrones with Azoalkenes

(2016) Liang Wei et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Copper-Catalyzed Intramolecular N−H Bond Insertion: Synthesis of Chiral 2-Carboxytetrahydroquinolines

(2016) Xiao-Guang Song et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper(II)-Catalyzed Asymmetric 1,3-Dipolar [3+4] Cycloaddition and Kinetic Resolution of Azomethine Imines with Azoalkenes

(2016) Liang Wei et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Palladium-Catalyzed Oxidative β,β-Fluoroarylation of α,β-Unsaturated Carbonyl Derivatives

(2016) Javier Miró et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Pd-Catalyzed Allylic Alkylation Reactions of Dihydropyrido[1,2-a ]indolone Substrates: Efficient Syntheses of (−)-Goniomitine, (+)-Aspidospermidine, and (−)-Quebrachamine

(2016) Beau P. Pritchett et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective and Diastereoselective Allylic Alkylation with Fluoroenolates: Efficient Access to C3-Fluorinated and All-Carbon Quaternary Oxindoles

(2016) Kaluvu Balaraman et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation

(2016) Yuki Naganawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Allylic C−H Oxidation of Terminal Olefins to Isochromans by Palladium(II)/Chiral Sulfoxide Catalysis

(2016) Stephen E. Ammann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cy-SaBOX/Copper(II)-Catalyzed Highly Diastereo- and Enantioselective Synthesis of Bicyclic N,O Acetals

(2016) Qiong-Jie Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Iridium-Catalyzed Hydrogenation of Cyclic Enamides

(2016) Ernest Salomó et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Dearomative [3+2] Cycloaddition Reactions of Benzothiazoles

(2016) Dong-Chao Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Construction of Chiral Tri- and Tetra-Arylmethanes Bearing Quaternary Carbon Centers: Copper-Catalyzed Enantioselective Propargylation of Indoles with Propargylic Esters

(2016) Kouhei Tsuchida et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective synthesis of quaternary α-aminophosphonates by Pd-catalyzed arylation of cyclic α-ketiminophosphonates with arylboronic acids

(2016) Zhong Yan et al.   CHEMICAL COMMUNICATIONS

Highly stereoselective cyclopropanation of diazo Weinreb amides catalyzed by chiral Ru(ii)–Amm–Pheox complexes

(2016) Soda Chanthamath et al.   CHEMICAL COMMUNICATIONS

Copper(I)-Catalyzed Asymmetric Dearomatization of Indole Acetamides with 3-Indolylphenyliodonium Salts

(2016) Chuan Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Dual Palladium(II)/Tertiary Amine Catalysis for Asymmetric Regioselective Rearrangements of Allylic Carbamates

(2016) Johannes Moritz Bauer et al.   CHEMISTRY-A EUROPEAN JOURNAL

MgII-Mediated Catalytic Asymmetric Dearomatization (CADA) Reaction of β-Naphthols with Dialkyl Acetylenedicarboxylates

(2016) Linqing Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Hydrogenation of Isoxazolium Triflates with a Chiral Iridium Catalyst

(2016) Ryuhei Ikeda et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Asymmetric Arylation of Trifluoromethylated/Perfluoroalkylated 2-Quinazolinones with High Enantioselectivity

(2016) Bo Zhou et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium-Catalyzed Asymmetric Hydrogenation of Unfunctionalized Exocyclic C=C Bonds

(2016) Jingzhao Xia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Noncovalent Substrate-Directed Enantioselective Heck Reactions: Synthesis of S- and P-Stereogenic Heterocycles

(2016) Francisco de Azambuja et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Construction of Pyrrolidines Bearing a Trifluoromethylated Quaternary Stereogenic Center via CuI -Catalyzed 1,3-Dipolar Cycloaddition of Azomethine Ylides with β-CF3 -β,β-Disubstituted Nitroalkenes

(2016) Li-Wei Tang et al.   Chemistry-An Asian Journal

Kinetic Resolution of Racemic and Branched Monosubstituted Allylic Acetates by a Ruthenium-Catalyzed Regioselective Allylic Etherification

(2016) Toru Shinozawa et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Three-Component Coupling Reaction of Alkyne, Enone, and Aldehyde Catalyzed by Chiral Phebox Ruthenium Catalysts

(2016) Shino Ubukata et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Friedel–Crafts Alkylation Reactions of 3-Substituted Indoles with Electron-Deficient Alkenes

(2016) Jian-Quan Weng et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Syntheses of Medicinally Important Isoindolinones (S)-PD 172938, (R)-JM 1232, and Related Structures

(2016) Arun Suneja et al.   JOURNAL OF ORGANIC CHEMISTRY

Mechanistic Studies and Expansion of the Substrate Scope of Direct Enantioselective Alkynylation of α-Ketiminoesters Catalyzed by Adaptable (Phebox)Rhodium(III) Complexes

(2016) Kazuhiro Morisaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Construction of Cyclobutanes: A New and Concise Approach to the Total Synthesis of (+)-Piperarborenine B

(2016) Jiang-Lin Hu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Asymmetric Kumada Cross-Coupling of Symmetric Cyclic Sulfates

(2016) Meredith S. Eno et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu(I)-Catalyzed Asymmetric Multicomponent Cascade Inverse Electron-Demand Aza-Diels–Alder/Nucleophilic Addition/Ring-Opening Reaction Involving 2-Methoxyfurans as Efficient Dienophiles

(2016) Rong Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric [4 + 1] Annulation of Sulfur Ylides with Copper–Allenylidene Intermediates

(2016) Qiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Trisubstituted Allenes via Cu(I)-Catalyzed Coupling of Diazoalkanes with Terminal Alkynes

(2016) Wen-Dao Chu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Nickel-Catalyzed anti-Carbometallative Cyclizations of Alkynyl Electrophiles Enabled by Reversible Alkenylnickel E/Z Isomerization

(2016) Christopher Clarke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Photocatalytic [3 + 2] Cycloadditions of Aryl Cyclopropyl Ketones

(2016) Adrian G. Amador et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bifunctional Photocatalysts for Enantioselective Aerobic Oxidation of β-Ketoesters

(2016) Wei Ding et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective total synthesis of the highly selective sphingosine-1-receptor VPC01091 by the Heck desymmetrization of a non-activated cyclopentene-fused spiro-pyrrolidinone

(2016) Ismat Ullah Khan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transmetal-Catalyzed Enantioselective Cross-Coupling Reaction of Racemic Secondary Benzylic Bromides with Organoaluminum Reagents

(2016) Hong Fang et al.   ORGANIC LETTERS

A Second-Generation Synthesis of the Cyanthiwigin Natural Product Core

(2016) Kelly E. Kim et al.   ORGANIC LETTERS

Enantioselective, Copper-Catalyzed Alkynylation of Ketimines To Deliver Isoquinolines with α-Diaryl Tetrasubstituted Stereocenters

(2016) Srimoyee Dasgupta et al.   ORGANIC LETTERS

Chromium-Catalyzed Asymmetric Dearomatization Addition Reactions of Halomethyl Heteroarenes

(2016) Qingshan Tian et al.   ORGANIC LETTERS

Palladium-Catalyzed Enantioselective Three-Component Synthesis of α-Arylglycines

(2016) Tamara Beisel et al.   ORGANIC LETTERS

Asymmetric Intramolecular Desymmetrization of meso-α,α′-Diazido Alcohols with Aryldiazoacetates: Assembly of Chiral C3 Fragments with Three Continuous Stereocenters

(2016) Jin-Bao Qiao et al.   ORGANIC LETTERS

The Construction of Chiral Fused Azabicycles Using a Pd-Catalyzed Allylic Substitution Cascade and Asymmetric Desymmetrization Strategy

(2016) Qianjin An et al.   ORGANIC LETTERS

Cobalt-Catalyzed Asymmetric Hydrogenation of 1,1-Diarylethenes

(2016) Jianhui Chen et al.   ORGANIC LETTERS

Copper-Catalyzed Aerobic Enantioselective Cross-Dehydrogenative Coupling of N-Aryl Glycine Esters with Terminal Alkynes

(2016) Zhiyu Xie et al.   ORGANIC LETTERS

Iridium Catalysts with f-Amphox Ligands: Asymmetric Hydrogenation of Simple Ketones

(2016) Weilong Wu et al.   ORGANIC LETTERS

Synthesis of NHC-Oxazoline Pincer Complexes of Rh and Ru and Their Catalytic Activity for Hydrogenation and Conjugate Reduction

(2016) Jun-ichi Ito et al.   ORGANOMETALLICS

Enantioselective photochemistry through Lewis acid–catalyzed triplet energy transfer

(2016) Travis R. Blum et al.   SCIENCE

Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay

(2016) Wen Zhang et al.   SCIENCE

Dual-Stereocontrol Asymmetric Cobalt-Catalyzed Hydroboration of Sterically Hindered Styrenes

(2016) Heyi Zhang et al.   ACS Catalysis

Cu(I)-Catalyzed Chemoselective and Stereoselective [3 + 3] Cycloaddition of Azomethine Ylides with 2-Indolylnitroethylenes: Facile Access to Highly Substituted Tetrahydro-γ-Carbolines

(2016) Wu-Lin Yang et al.   ACS Catalysis

Stereoselective 1,6-Conjugate Addition/Annulation of para-Quinone Methides with Vinyl Epoxides/Cyclopropanes

(2016) Chao Ma et al.   ACS Catalysis

Enantioselective Construction of Cyclic Indolyl α-Amino Estersviaa Friedel-Crafts Alkylation Reaction

(2015) Liang Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct Asymmetric Dearomatization of 2-Naphthols by Scandium-Catalyzed Electrophilic Amination

(2015) Jiang Nan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of 3a-Amino-Pyrroloindolines by Copper-Catalyzed Direct Asymmetric Dearomative Amination of Tryptamines

(2015) Chuan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Enantioselective Dearomatization Reaction of β-Naphthol Usingmeso-Aziridine: A Bifunctional In Situ Generated Magnesium Catalyst

(2015) Dongxu Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Application of a CC Bond-Forming Conjugate Addition Reaction in Asymmetric Dearomatization of β-Naphthols

(2015) Dongxu Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Copper(I)-Catalyzed Alkynylation of Oxocarbenium Ions to Set Diaryl Tetrasubstituted Stereocenters

(2015) Srimoyee Dasgupta et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Axially Chiral Isoquinolones: Nickel-Catalyzed Denitrogenative Transannulation

(2015) Zhi-Jia Fang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Quaternary Stereogenic Centers through Enantioselective Heck Arylation of Acyclic Olefins with Aryldiazonium Salts: Application in a Concise Synthesis of (R)-Verapamil

(2015) Caio C. Oliveira et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereospecific SN2@P reactions: novel access to bulky P-stereogenic ligands

(2015) Sílvia Orgué et al.   CHEMICAL COMMUNICATIONS

Enantioselective synthesis of arylglycine derivatives by direct C–H oxidative cross-coupling

(2015) Xiao-Hong Wei et al.   CHEMICAL COMMUNICATIONS

Iron-catalyzed asymmetric hydrosilylation of ketones

(2015) Ziqing Zuo et al.   CHEMICAL COMMUNICATIONS

Cobalt-catalyzed asymmetric hydroboration of aryl ketones with pinacolborane

(2015) Jun Guo et al.   CHEMICAL COMMUNICATIONS

Synthesis of Ferrocene Oxazoline N,O ligands and Their Application in Asymmetric Ethyl- and Phenylzinc Additions to Aldehydes

(2015) Chris Nottingham et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Bis(oxazoline) Ligands Possessing C-5 gem-Disubstitution and Their Application in Asymmetric Friedel–Crafts Alkylations

(2015) Steven O’Reilly et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Approach to Polycyclic Polyprenylated Acylphloroglucinols via Catalytic Asymmetric Intramolecular Cyclopropanation

(2015) Yuta Uetake et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Copper-Catalyzed Alkynylation of Benzopyranyl Oxocarbenium Ions

(2015) Harathi D. Srinivas et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric H2O-Nucleophilic Ring Opening of D–A Cyclopropanes: Catalyst Serves as a Source of Water

(2015) Qi-Kai Kang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Divergent Addition Reactions of Enoldiazoacetamides with Nitrones

(2015) Qing-Qing Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoconvergent Negishi Arylations of Racemic Secondary Alkyl Electrophiles: Differentiating between a CF3 and an Alkyl Group

(2015) Yufan Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes

(2015) Ying He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Annulation of Donor–Acceptor Cyclopropanes with Dienes

(2015) Hao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Propargylic Etherification of Propargylic Esters with Alcohols

(2015) Kazunari Nakajima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron Achieves Noble Metal Reactivity and Selectivity: Highly Reactive and Enantioselective Iron Complexes as Catalysts in the Hydrosilylation of Ketones

(2015) Tim Bleith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Conjugate Additions of α-Amino Radicals via Cooperative Photoredox and Lewis Acid Catalysis

(2015) Laura Ruiz Espelt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concise Enantioselective Synthesis of Oxygenated Steroids via Sequential Copper(II)-Catalyzed Michael Addition/Intramolecular Aldol Cyclization Reactions

(2015) Nathan R. Cichowicz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Polytopic bis(oxazoline)-based ligands for recoverable catalytic systems applied to the enantioselective Henry reaction

(2015) Beatriz Angulo et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Synthesis of α-exo-Methylene γ-Butyrolactones via Chromium Catalysis

(2015) Weiqiang Chen et al.   ORGANIC LETTERS

Enantioselective Synthesis of Dialkylated N-Heterocycles by Palladium-Catalyzed Allylic Alkylation

(2015) Yoshitaka Numajiri et al.   ORGANIC LETTERS

A Porphyrin-Inspired Iron Catalyst for Asymmetric Epoxidation of Electron-Deficient Olefins

(2015) Wen Dai et al.   ORGANIC LETTERS

Copper(II)-Catalyzed Enantioselective Intramolecular Cyclization of N-Alkenylureas

(2015) Shaomin Fu et al.   ORGANIC LETTERS

Palladium Catalyzed Asymmetric Allylation of 3-OBoc-Oxindoles: An Efficient Synthesis of 3-Allyl-3-hydroxyoxindoles

(2015) Samydurai Jayakumar et al.   ORGANIC LETTERS

Palladium-Catalyzed Enantioselective Three-Component Synthesis of α-Substituted Amines

(2015) Tamara Beisel et al.   ORGANIC LETTERS

Catalytic Asymmetric [3 + 2] Cyclization Reactions of 3-Isothiocyanato Oxindoles and Alkynyl Ketones Via an in Situ Generated Magnesium Catalyst

(2015) Linqing Wang et al.   ORGANIC LETTERS

Zn-Catalyzed Diastereo- and Enantioselective Cascade Reaction of 3-Isothiocyanato Oxindoles and 3-Nitroindoles: Stereocontrolled Syntheses of Polycyclic Spirooxindoles

(2015) Jian-Qiang Zhao et al.   ORGANIC LETTERS

Calcium-Catalyzed Asymmetric Synthesis of 3-Tetrasubstituted Oxindoles: Efficient Construction of Adjacent Quaternary and Tertiary Chiral Centers

(2015) Shota Shimizu et al.   ORGANIC LETTERS

Direct Asymmetric Synthesis of β-Bis-Aryl-α-Amino Acid Esters via Enantioselective Copper-Catalyzed Addition of p-Quinone Methides

(2015) Fu-Sheng He et al.   ACS Catalysis

Side Arm Strategy for Catalyst Design: Modifying Bisoxazolines for Remote Control of Enantioselection and Related

(2014) Saihu Liao et al.   ACCOUNTS OF CHEMICAL RESEARCH

6-Azabicyclo[3.2.1]octanesviaCopper-Catalyzed Enantioselective Alkene Carboamination

(2014) Barbara J. Casavant et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Hydrosilylation of Ketones Catalyzed by Zinc Acetate with Hindered Pybox Ligands

(2014) Daniel Łowicki et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Enantioselective Carboannulation with Allylsilanes

(2014) Nicolas R. Ball-Jones et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

SpinPhox/Iridium(I)-Catalyzed Asymmetric Hydrogenation of Cyclic α-Alkylidene Carbonyl Compounds

(2014) Xu Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Palladium-Catalyzed Insertion of α-Aryl-α-diazoacetates into the OH Bonds of Phenols

(2014) Xiu-Lan Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Iron-Catalyzed Intramolecular Cyclopropanation Reactions

(2014) Jun-Jie Shen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Inverse Electron Demand Hetero-Diels-Alder Reaction with Allylsilanes

(2014) Yuki Matsumura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of α-Secondary and α-Tertiary Piperazin-2-ones and Piperazines by Catalytic Asymmetric Allylic Alkylation

(2014) Katerina M. Korch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Carbonyl-Ene Reactions of 2,3-Diketoesters: Efficient and Atom-Economical Process to Functionalized Chiral α-Hydroxy-β-Ketoesters

(2014) Phong M. Truong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Hydrogenation of α,β-Unsaturated Nitriles with Base-Activated Iridium N,P Ligand Complexes

(2014) Marc-André Müller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Cascade Reaction to Allylic Sulfonamides from Allylic Alcohols by Palladium(II)/Base-Catalyzed Rearrangement of Allylic Carbamates

(2014) Johannes Moritz Bauer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Allylic Alkylation of Simple Ketones with Allylic Alcohols and Its Mechanistic Study

(2014) Xiaohong Huo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Synthesis of [2,3]-Fused Indoline Heterocycles through Inverse-Electron-Demand Aza-Diels-Alder Reaction of Indoles with Azoalkenes

(2014) Min-Chao Tong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Alkynylation/Lactamization Cascade: An Expeditious Entry to Enantiomerically Enriched Isoindolinones

(2014) Vishnumaya Bisai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pd-catalyzed highly regio-, diastereo-, and enantioselective allylic alkylation of α-fluorophosphonates

(2014) Ying Huang et al.   CHEMICAL COMMUNICATIONS

Catalytic asymmetric aminolactonization of 1,2-disubstituted alkenoic acid esters: Efficient construction of aminolactones with an all-carbon quaternary stereo-centre

(2014) Saumen Hajra et al.   CHEMICAL COMMUNICATIONS

A rapid and divergent access to chiral azacyclic nucleoside analogues via highly enantioselective 1,3-dipolar cycloaddition of β-nucleobase substituted acrylates

(2014) Qi-Liang Yang et al.   CHEMICAL COMMUNICATIONS

Highly enantioselective aza-Henry reaction with isatin N-Boc ketimines

(2014) Melireth Holmquist et al.   CHEMICAL COMMUNICATIONS

Enantioselective intramolecular propargylic amination using chiral copper–pybox complexes as catalysts

(2014) Masashi Shibata et al.   CHEMICAL COMMUNICATIONS

A Highly Stereoselective and Flexible Strategy for the Convergent Synthesis of Long-Chain Polydeoxypropionates: Application towards the Synthesis of the Glycolipid Membrane Components Hydroxyphthioceranic and Phthioceranic Acid

(2014) Matthias C. Pischl et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Stereoselective Switch: Enantiodivergent Approach to the Synthesis of Isoflavanones

(2014) Robert Doran et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Cascade Michael Addition/Cyclization Reactions of 3-Nitro-2H-Chromenes with 3-Isothiocyanato Oxindoles: Efficient Synthesis of Functionalized Polycyclic Spirooxindoles

(2014) Fen Tan et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed One-Pot Denitrogenative-Dehydrogenative-Decarboxylative Coupling of β-Ketoacids with Trifluorodiazoethane: Facile Access to Trifluoromethylated Aldol Products

(2014) Heng-Ying Xiong et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic Enantioselective Amide Allylation of Isatins and Its Application in the Synthesis of 2-Oxindole Derivatives Spiro-Fused to the α-Methylene-γ-Butyrolactone Functionality

(2014) Masaki Takahashi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Synthesis of Spiroimines by Asymmetric Decarboxylative Alkylation/Isomerization/[3+2]-Cycloaddition Reaction of Azidoalkenes

(2014) Matt Rambla et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Asymmetric Addition to Isatins to give 3-Hydroxy-2-oxindoles by C-H Activation

(2014) Tao Deng et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

A Unified Stereodivergent Strategy for Prostaglandin and Isoprostanoid Synthesis

(2014) Matteo Valli et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Pd-Catalyzed Allylation of Acyclic α-Fluorinated Ketones

(2014) Wengui Wang et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Claisen Rearrangement of Gosteli-Type Allyl Vinyl Ethers: Total Synthesis of (−)-9,10-Dihydroecklonialactone B

(2014) Julia Becker et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Asymmetric Synthesis of Sterically Hindered Tertiary α-Aryl Ketones

(2014) Robert Doran et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Epoxidation of Olefins with Hydrogen Peroxide by an in Situ-Formed Manganese Complex

(2014) Wen Dai et al.   JOURNAL OF ORGANIC CHEMISTRY

Application of Bidentate Oxazoline–Carbene Ligands with Planar and Central Chirality in Asymmetric β-Boration of α,β-Unsaturated Esters

(2014) Zonghong Niu et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoconvergent Arylations and Alkenylations of Unactivated Alkyl Electrophiles: Catalytic Enantioselective Synthesis of Secondary Sulfonamides and Sulfones

(2014) Junwon Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Asymmetric Reductive Cross-Coupling Between Vinyl and Benzyl Electrophiles

(2014) Alan H. Cherney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Asymmetric [3 + 2] Annulation Reactions of Aminocyclopropanes

(2014) Florian de Nanteuil et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes

(2014) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Tertiary Alkyl Fluorides: Negishi Cross-Couplings of Racemic α,α-Dihaloketones

(2014) Yufan Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt–Bisoxazoline-Catalyzed Asymmetric Kumada Cross-Coupling of Racemic α-Bromo Esters with Aryl Grignard Reagents

(2014) Jianyou Mao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective palladium catalyzed conjugate additions of ortho-substituted arylboronic acids to β,β-disubstituted cyclic enones: total synthesis of herbertenediol, enokipodin A and enokipodin B

(2014) Jeffrey Buter et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic amide allylation of α-ketoesters: extremely high enantioselective synthesis of ester functionalised α-methylene-γ-butyrolactones

(2014) Masaki Takahashi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Synthesis of (−)-Aurantioclavine via Palladium-Catalyzed Intramolecular Allylic Amination

(2014) Satoshi Suetsugu et al.   ORGANIC LETTERS

Highly Stereoselective Synthesis of Cyclopropylphosphonates Catalyzed by Chiral Ru(II)-Pheox Complex

(2014) Soda Chanthamath et al.   ORGANIC LETTERS

Construction of the N1–C3 Linkage Stereogenic Centers by Catalytic Asymmetric Amination Reaction of 3-Bromooxindoles with Indolines

(2014) Hailong Zhang et al.   ORGANIC LETTERS

Enantioselective Addition of Nitromethane to 2-Acylpyridine N-Oxides. Expanding the Generation of Quaternary Stereocenters with the Henry Reaction

(2014) Melireth Holmquist et al.   ORGANIC LETTERS

Evaluation of Achiral Templates with Fluxional Brønsted Basic Substituents in Enantioselective Conjugate Additions

(2014) Shinya Adachi et al.   ORGANIC LETTERS

Copper-Catalyzed Asymmetric Hydroboration of α-Dehydroamino Acid Derivatives: Facile Synthesis of Chiral β-Hydroxy-α-amino Acids

(2014) Zhi-Tao He et al.   ORGANIC LETTERS

Cyclic Aldimines as Superior Electrophiles for Cu-Catalyzed Decarboxylative Mannich Reaction of β-Ketoacids with a Broad Scope and High Enantioselectivity

(2014) Heng-Xia Zhang et al.   ORGANIC LETTERS

Catalytic Asymmetric Assembly of C3-Monosubstituted Chiral Carbazolones and Concise Formal Synthesis of (−)-Aspidofractinine: Application of Enantioselective Pd-Catalyzed Decarboxylative Protonation of Carbazolones

(2014) Ruirui Zhao et al.   ORGANIC LETTERS

Asymmetric Friedel–Crafts Alkylation of α-Substituted β-Nitroacrylates: Access to β2,2-Amino Acids Bearing Indolic All-Carbon Quaternary Stereocenters

(2014) Jian-Quan Weng et al.   ORGANIC LETTERS

Hydrogen-Bond-Activated Palladium-Catalyzed Allylic Alkylation via Allylic Alkyl Ethers: Challenging Leaving Groups

(2014) Xiaohong Huo et al.   ORGANIC LETTERS

Enantioposition-Selective Copper-Catalyzed Azide–Alkyne Cycloaddition for Construction of Chiral Biaryl Derivatives

(2014) Takao Osako et al.   ORGANIC LETTERS

Catalytic Enantioselective Desymmetrization of 1,3-Diazido-2-propanol via Intramolecular Interception of Alkyl Azides with Diazo(aryl)acetates

(2014) Xiu-Ping Wu et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Regio- and Enantioselective Allylic Amination of Racemic 1-Arylallyl Esters

(2014) Motoi Kawatsura et al.   ORGANIC LETTERS

Iminopyridine Oxazoline Iron Catalyst for Asymmetric Hydroboration of 1,1-Disubtituted Aryl Alkenes

(2014) Jianhui Chen et al.   ORGANIC LETTERS

Single-electron transmetalation in organoboron cross-coupling by photoredox/nickel dual catalysis

(2014) J. C. Tellis et al.   SCIENCE

Recent Applications of C 1-Symmetric Bis(oxazoline)-Containing Ligands in Asymmetric Catalysis

(2014) Patrick Guiry et al.   SYNTHESIS-STUTTGART

Iron-catalyzed kinetic resolution of N-sulfonyl oxaziridines

(2014) Kevin S. Williamson et al.   Chemical Science

Bis(oxazoline)-copper catalyzed enantioselective hydrophosphonylation of aldehydes

(2014) Tao Deng et al.   RSC Advances

Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes

(2014) Jianhui Chen et al.   Organic Chemistry Frontiers

Copper-Catalyzed Asymmetric Alkylation of β-Keto Esters with Xanthydrols

(2013) Paz Trillo et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Enantioselective Inverse Electron-Demand Hetero-Diels-Alder Reactions of Diazadienes with Enol Ethers: Efficient Synthesis of Chiral Pyridazines

(2013) Shuang Gao et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthesis of Glutamic Acid and Highly Functionalized Pyrrolidine Derivatives by Utilizing Tunable Calcium Catalysts for Chemoselective Asymmetric 1,4-Addition and [3+2] Cycloaddition Reactions

(2013) Martin Hut'ka et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantio- and Diastereoselective Vinylogous Mukaiyama Aldol Reactions of α-Keto Phosphonates with 2-(Trimethylsilyloxy)- furan Catalyzed by Bis(oxazoline)-Copper Complexes

(2013) Gang Hou et al.   ADVANCED SYNTHESIS & CATALYSIS

Iridium-Catalyzed Asymmetric Hydrogenation of α-Alkylidene Succinimides

(2013) Yuanyuan Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective [3+2] Annulation of Cyclic Enol Silyl Ethers with Donor-Acceptor Cyclopropanes: Accessing3a-Hydroxy [n.3.0]Carbobicycles

(2013) Hao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Construction of α-Quaternary Cyclobutanones by Catalytic Asymmetric Allylic Alkylation

(2013) Corey M. Reeves et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Diboration of Terminal Alkenes with a Rhodium Catalyst and Subsequent Oxidation: Enantioselective Synthesis of Optically Active 1,2-Diols

(2013) Kenji Toribatake et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Nitrene Transfer to Sulfides Catalyzed by a Chiral Iron Complex

(2013) Jun Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Palladium-Catalyzed Decarboxylative Allylation of Carbazolones: Total Synthesis of (−)-Aspidospermidine and (+)-Kopsihainanine A

(2013) Zeqian Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Rearrangement of Allylic Oxonium Ylides: Efficient Synthesis of Highly Functionalized Dihydrofuran-3-ones

(2013) Junkai Fu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper-Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes

(2013) Rong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Friedel-Crafts Alkylation/N-Hemiacetalization Cascade Reaction with Indoles

(2013) Hong-Gang Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper/Palladium-Catalyzed 1,4 Reduction and Asymmetric Allylic Alkylation of α,β-Unsaturated Ketones: Enantioselective Dual Catalysis

(2013) Fady Nahra et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Palladium-Catalyzed Decarboxylative Allylation of Carbazolones and Indolones: Formal Synthesis of (+)-Kopsihainanine A

(2013) Christopher J. Gartshore et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Recyclable Self-Supported Chiral Catalysts for the Enantioselective α-Hydrazination of β-Ketoesters

(2013) Maria Torres et al.   ChemCatChem

Copper-catalyzed asymmetric 1,4-conjugate addition of Grignard reagents to linear α,β,γ,δ-unsaturated ketones

(2013) Zhenni Ma et al.   CHEMICAL COMMUNICATIONS

Asymmetric formation of tert-alkylamines from serinols by a dual function catalyst

(2013) Young Suk You et al.   CHEMICAL COMMUNICATIONS

Enantio- and diastereoselective palladium catalysed arylative and vinylative allene carbocyclisation cascades

(2013) Meiling Li et al.   CHEMICAL COMMUNICATIONS

P,N ligands in asymmetric catalysis

(2013) Michael P. Carroll et al.   CHEMICAL SOCIETY REVIEWS

Expanding Insight into Asymmetric Palladium-Catalyzed Allylic Alkylation of N-Heterocyclic Molecules and Cyclic Ketones

(2013) Nathan B. Bennett et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Conjugate Addition of Malonate Esters to α,β-UnsaturatedN-Sulfonyl Imines: An Expeditious Route to Chiral δ-Aminoesters and Piperidones

(2013) Miguel Espinosa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh-Catalyzed Direct Enantioselective Alkynylation of α-Ketiminoesters

(2013) Kazuhiro Morisaki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Imidative Kinetic Resolution of Racemic Sulfoxides

(2013) Jun Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Boxmi Complexes as Highly Enantioselective Catalysts for Electrophilic Trifluoromethylthiolations

(2013) Qing-Hai Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Efficient Catalytic Enantioselective Mannich Reaction of Malonates withN-tert-Butoxycarbonyl Imines by Using Yb(OTf)3/Pybox Catalysts at Room Temperature

(2013) Babak Karimi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Alkylation of Allyl Acetates Using Tartrate-Derived Bioxazoline Ligands

(2013) Samydurai Jayakumar et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective LaIII-pyBOX-Catalyzed Nitro-Michael Addition to (E)-2-Azachalcones

(2013) Gonzalo Blay et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Fluorous chiral bis(oxazolines): Synthesis and application in asymmetric Henry reaction

(2013) Tao Deng et al.   JOURNAL OF FLUORINE CHEMISTRY

Intermolecular Enantioselective Heck–Matsuda Arylations of Acyclic Olefins: Application to the Synthesis of β-Aryl-γ-lactones and β-Aryl Aldehydes

(2013) Caio C. Oliveira et al.   JOURNAL OF ORGANIC CHEMISTRY

Two Approaches toward the Formal Total Synthesis of Oseltamivir Phosphate (Tamiflu): Catalytic Enantioselective Three-Component Reaction Strategy and l-Glutamic Acid Strategy

(2013) Kaliyamoorthy Alagiri et al.   JOURNAL OF ORGANIC CHEMISTRY

Chiral Lewis Acid Catalyzed Asymmetric Cycloadditions of Carbonyl Ylides Generated from Diazoimide Derivatives and Their Synthetic Applications to Indolizidine Alkaloids

(2013) Hiroyuki Suga et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of Asymmetric Deacylative Allylation

(2013) Alexander J. Grenning et al.   JOURNAL OF ORGANIC CHEMISTRY

A Highly Efficient and Enantioselective Intramolecular Cannizzaro Reaction under TOX/Cu(II) Catalysis

(2013) Pan Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Iron-Catalyzed Azidation of β-Keto Esters and Oxindoles

(2013) Qing-Hai Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Reductive Acyl Cross-Coupling: Synthesis of Enantioenriched Acyclic α,α-Disubstituted Ketones

(2013) Alan H. Cherney et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel/Bis(oxazoline)-Catalyzed Asymmetric Negishi Arylations of Racemic Secondary Benzylic Electrophiles to Generate Enantioenriched 1,1-Diarylalkanes

(2013) Hien-Quang Do et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Zirconium-Catalyzed Cyclization of Aminoalkenes

(2013) Kuntal Manna et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Copper(I)-Catalyzed Azide–Alkyne Cycloaddition to Quaternary Oxindoles

(2013) Feng Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Construction of Trifluoromethylated All-Carbon Quaternary Stereocenters via Nickel-Catalyzed Friedel–Crafts Alkylation Reaction

(2013) Jian-Rong Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed B–H Bond Insertion Reaction: A Highly Efficient and Enantioselective C–B Bond-Forming Reaction with Amine–Borane and Phosphine–Borane Adducts

(2013) Qing-Qing Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Mukaiyama–Michael with 2-enoyl pyridine N-oxides catalyzed by PYBOX-DIPH-Zn(ii)-complexes at ambient temperature

(2013) Subhrajit Rout et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective synthesis of 3,4-dihydropyran derivatives via a Michael addition reaction catalysed by chiral pybox–diph–Zn(ii) complex

(2013) Sumit K. Ray et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective synthesis of 3-hydroxy oxindoles by ytterbium-catalysed decarboxylative addition of β-ketoacids to isatins

(2013) Zhiqiang Duan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic, enantioselective 1,3-dipolar cycloadditions of nitrile imines with methyleneindolinones

(2013) Anthony L. Gerten et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

The synthesis of chiral β-aryl-α,β-unsaturated amino alcohols via a Pd-catalyzed asymmetric allylic amination

(2013) Mao Quan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Iron(II)-Catalyzed Asymmetric Intramolecular Aminohydroxylation of Indoles

(2013) Yong-Qiang Zhang et al.   ORGANIC LETTERS

Asymmetric Synthesis of l-Carbidopa Based on a Highly Enantioselective α-Amination

(2013) Àlex Pericas et al.   ORGANIC LETTERS

Distinctive Meta-Directing Group Effect for Iridium-Catalyzed 1,1-Diarylalkene Enantioselective Hydrogenation

(2013) Elizabeth N. Bess et al.   ORGANIC LETTERS

Iridium-Catalyzed Enantioselective Hydrogenation of α,β-Unsaturated Carboxylic Acids with Tetrasubstituted Olefins

(2013) Song Song et al.   ORGANIC LETTERS

Construction of Spiro-Fused 2-Oxindole/α-Methylene- γ-Butyrolactone Systems with Extremely High Enantioselectivity via Indium-Catalyzed Amide Allylation of N-Methyl Isatin

(2013) Yusuke Murata et al.   ORGANIC LETTERS

Asymmetric Hetero-Diels–Alder Reaction of Danishefsky’s Dienes with α-Carbonyl Esters Catalyzed by an Indium(III)–PyBox Complex

(2013) Bei Zhao et al.   ORGANIC LETTERS

Enantioselective Nickel-Catalyzed Michael Additions of 2-Acetylazaarenes to Nitroalkenes

(2013) Alain J. Simpson et al.   ORGANIC LETTERS

Asymmetric Oxidation Catalysis by a Porphyrin-Inspired Manganese Complex: Highly Enantioselective Sulfoxidation with a Wide Substrate Scope

(2013) Wen Dai et al.   ORGANIC LETTERS

Asymmetric Epoxidation of Alkenes Catalyzed by a Porphyrin-Inspired Manganese Complex

(2013) Wen Dai et al.   ORGANIC LETTERS

Azidation of β-Keto Esters and Silyl Enol Ethers with a Benziodoxole Reagent

(2013) Maria Victoria Vita et al.   ORGANIC LETTERS

Asymmetric Synthesis of Indole Homo-Michael Adducts via Dynamic Kinetic Friedel–Crafts Alkylation with Cyclopropanes

(2013) Steven M. Wales et al.   ORGANIC LETTERS

Application of tartarate derived bidentate bioxazolines in enantioselective addition of terminal alkynes to imines

(2013) Kaluvu Balaraman et al.   TETRAHEDRON LETTERS

A robust Ru-PNNP catalyst system for the asymmetric hydrogenation of α,β-unsaturated ketones to allylic alcohol

(2013) Sheng-Mei Lu et al.   TETRAHEDRON LETTERS

Iridium(iii)-bis(oxazolinyl)phenyl catalysts for enantioselective C–H functionalization

(2013) Clayton P. Owens et al.   Chemical Science

Water-Soluble Chiral Ruthenium(II) Phenyloxazoline Complex: Reusable and Highly Enantioselective Catalyst for Intramolecular Cyclopropanation Reactions

(2012) Abdel-Moneim Abu-Elfotoh et al.   ADVANCED SYNTHESIS & CATALYSIS

Access to Both Enantiomers of α-Chloro-β-keto Esters with a Single Chiral Ligand: Highly Efficient Enantioselective Chlorination of Cyclic β-Keto Esters Catalyzed by Chiral Copper(II) and Zinc(II) Complexes of a Spiro-2,2′-bischroman-Based Bisoxazoline Li

(2012) Jie Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Carboxy-Directed Asymmetric Hydrogenation of 1,1-Diarylethenes and 1,1-Dialkylethenes

(2012) Song Song et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective 5-endo-dig Carbocyclization of β-Ketoesters with Internal Alkynes Employing a Four-Component Catalyst System

(2012) Satoru Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Chiral Cagelike Copper(I) Catalyst for the Highly Enantioselective Synthesis of 1,1-Cyclopropane Diesters

(2012) Chao Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Alkene Aminohalogenation/Cyclization Involving Atom Transfer

(2012) Michael T. Bovino et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective [3+3] Cycloaddition of Aromatic Azomethine Imines with Cyclopropanes Directed by π-π Stacking Interactions

(2012) You-Yun Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Synthesis of Allenyl Oxindoles and Spirooxindoles by a Catalytic Enantioselective Saucy-Marbet Claisen Rearrangement

(2012) Trung Cao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective alkylation of β-keto phosphonates by direct use of diaryl methanols as electrophiles

(2012) Masashi Shibata et al.   CHEMICAL COMMUNICATIONS

General switch in regioselectivity in the Mukaiyama aldol reaction of silyloxyfuran with aldehydes in aqueous solvents

(2012) Marta Woyciechowska et al.   CHEMICAL COMMUNICATIONS

Enantioselective synthesis of (−)-paeonilide

(2012) Klaus Harrar et al.   CHEMICAL COMMUNICATIONS

Enantioselective construction of sterically hindered tertiary α-aryl ketones: a catalytic asymmetric synthesis of isoflavanones

(2012) Michael P. Carroll et al.   CHEMICAL COMMUNICATIONS

Direct Conjugate Addition of Alkynes with α,β-Unsaturated Carbonyl Compounds Catalyzed by NCN-Pincer Ru Complexes

(2012) Jun-ichi Ito et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Iridium-Catalyzed Hydrogenation of α,β-Unsaturated Esters

(2012) Jia-Qi Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Optically Active Oxazoline Derivatives via Catalytic Asymmetric Desymmetrization of 1,3-Diols

(2012) Yutaro Tsuda et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Addition of Cyclic Enol Silyl Ethers to 2-Alkenoyl-Pyridine-N-Oxides Catalysed by CuII-Bis(oxazoline) Complexes

(2012) Alessandro Livieri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Asymmetric Quaternary Stereocenter Formation

(2012) Aditya L. Gottumukkala et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective [4+2] Cycloadditions of 2-Vinyl-1 H-indoles with 3-Nitro-2 H-chromenes Catalyzed by a Zn(OTf)2/Bis(oxazoline) Complex: An Efficient Approach to Fused Heterocycles with a Quaternary Stereocenter

(2012) Fen Tan et al.   Chemistry-An Asian Journal

Asymmetric Friedel-Crafts Alkylation of Indoles with Nitrodienes and 2-Propargyloxy-β-nitrostyrenes Catalyzed by Diphenylamine-Linked Bis(oxazoline)-Zn­(OTf)2 Complexes

(2012) Jiahuan Peng et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

The Asymmetric Formal Hetero-Diels-Alder Reaction of Methyl (E)-4-Aryl-2-oxo-3-butenoates Catalyzed by [Sc(OTf)3/pybox] Complexes

(2012) Giovanni Desimoni et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of Coumarin Derivatives by PYBOX-DIPH-Zn(II) Complex Catalyzed Michael Reaction

(2012) Sumit K. Ray et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of Optically Active 3,3-Diarylpropanoates by Conjugate Hydrosilylation with Chiral Rh-bis(oxazolinyl)phenyl Catalysts

(2012) Kengou Itoh et al.   JOURNAL OF ORGANIC CHEMISTRY

Regio- and Enantioselective Palladium-Catalyzed Allylic Alkylation of Nitromethane with Monosubstituted Allyl Substrates: Synthesis of (R)-Rolipram and (R)-Baclofen

(2012) Xiao-Fei Yang et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium(II)-Catalyzed Enantioselective Arylation of α-Imino Esters

(2012) Jiayan Chen et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of Catalysts for the Stereoselective Hydrogenation of α,β-Unsaturated Ketones

(2012) Frauke Maurer et al.   JOURNAL OF ORGANIC CHEMISTRY

A Non-Heme Iron(III) Complex with Porphyrin-like Properties That Catalyzes Asymmetric Epoxidation

(2012) Takashi Niwa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Allylic Amination of Unactivated Terminal Olefins via an Ene Reaction/[2,3]-Rearrangement

(2012) Hongli Bao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Copper-Catalyzed Alkylation of β-Ketoesters and Subsequent Cyclization to Spirolactones/Bi-spirolactones

(2012) Qing-Hai Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Copper-Catalyzed Construction of Aryl Pyrroloindolines via an Arylation–Cyclization Cascade

(2012) Shaolin Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Reaction Mechanism of the Enantioselective Tsuji Allylation: Inner-Sphere and Outer-Sphere Pathways, Internal Rearrangements, and Asymmetric C–C Bond Formation

(2012) John A. Keith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective O-Nitrosocarbonyl Aldol Reaction of β-Dicarbonyl Compounds

(2012) Mahiuddin Baidya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Paramagnetic Palladacycles with PdIII Centers Are Highly Active Catalysts for Asymmetric Aza-Claisen Rearrangements

(2012) Simon H. Eitel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of α-Oxy Amides via Umpolung Amide Synthesis

(2012) Matthew W. Leighty et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Synthesis of Secondary Nitriles via Stereoconvergent Negishi Arylations and Alkenylations of Racemic α-Bromonitriles

(2012) Junwon Choi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Intramolecular Alkene Amination/Intermolecular Heck-Type Coupling Cascade

(2012) Timothy W. Liwosz et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diastereo- and Enantioselective Pd(II)-Catalyzed Additions of 2-Alkylazaarenes to N-Boc Imines and Nitroalkenes

(2012) Daniel Best et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron Catalyzed Asymmetric Oxyamination of Olefins

(2012) Kevin S. Williamson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Side-Arm-Promoted Highly Enantioselective Ring-Opening Reactions and Kinetic Resolution of Donor–Acceptor Cyclopropanes with Amines

(2012) You-Yun Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Copper-Catalyzed Electrophilic Trifluoromethylation of β-Ketoesters

(2012) Qing-Hai Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective construction of the tetracyclic core of Cryptotrione

(2012) Song Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective Friedel–Crafts alkylation of indoles with 2-enoylpyridine-N-oxides catalyzed by glucoBOX-Cu(ii) complex

(2012) Jimil George et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Friedel–Crafts alkylation of indoles with 3-nitro-2H-chromenes catalyzed by diphenylamine-linked bis(oxazoline) and bis(thiazoline) Zn(II) complexes

(2012) Yang Jia et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

A New Approach to the Synthesis of Peptidomimetic Renin Inhibitors: Palladium-Catalyzed Asymmetric Allylation of Acyclic Alkyl Aryl Ketones

(2012) Stephen Hanessian et al.   ORGANIC LETTERS

An Enantioselective Total Synthesis of Helioporins C and E

(2012) Wibke Lölsberg et al.   ORGANIC LETTERS

{1,6}-Transannular Catalytic Asymmetric Gosteli–Claisen Rearrangement

(2012) Tobias Jaschinski et al.   ORGANIC LETTERS

Highly Enantioselective Synthesis of 2,3-Dihydroquinazolinones through Intramolecular Amidation of Imines

(2012) Muthuraj Prakash et al.   ORGANIC LETTERS

Enantioselective Cyclopropanation of Indoles: Construction of All-Carbon Quaternary Stereocenters

(2012) Gülsüm Özüduru et al.   ORGANIC LETTERS

Scandium(III)-Catalyzed Enantioselective Allylation of Isatins Using Allylsilanes

(2012) Nadine V. Hanhan et al.   ORGANIC LETTERS

Asymmetric Henry Reaction Catalyzed by Novel Chiral Bioxazolines from Tartaric Acid

(2012) Venkitasamy Kesavan et al.   SYNTHESIS-STUTTGART

Naphthyl-substituted bisoxazoline and pyridylbisoxazoline–copper(I) catalysts for asymmetric allylic oxidation

(2012) Ziniu Zhou et al.   TETRAHEDRON LETTERS

A reagent based DOS strategy via Evans chiral auxiliary: highly stereoselective Michael reaction towards optically active quinolizidinones, piperidinones and pyrrolidinones

(2012) Subhabrata Sen et al.   RSC Advances

Iron-Catalyzed CH Fuctionalization of Indoles

(2011) Yan Cai et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Conjugate Addition of Glycine Derivatives under Copper Catalysis

(2011) Mark Strohmeier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Alkynylation of C1-Substituted C,N-Cyclic Azomethine Imines by CuI/Chiral Brønsted Acid Co-Catalyst

(2011) Takuya Hashimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Activation of a C sp 3H Bond Adjacent to a Nitrogen Atom: A Versatile Approach to Optically Active α-Alkyl α-Amino Acids and C1-Alkylated Tetrahydroisoquinoline Derivatives

(2011) Gen Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C1-Symmetric Rh/Phebox-Catalyzed Asymmetric Alkynylation of α-Ketoesters

(2011) Takashi Ohshima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric [3+2] Annulation of Allylsilanes with Isatins: Synthesis of Spirooxindoles

(2011) Nadine V. Hanhan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Catalytic Enantioselective Total Synthesis of (+)-Liphagal

(2011) Joshua J. Day et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Highly Enantioselective Zirconium Catalyst for Intramolecular Alkene Hydroamination: Significant Isotope Effects on Rate and Stereoselectivity

(2011) Kuntal Manna et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ring-Contraction Strategy for the Practical, Scalable, Catalytic Asymmetric Synthesis of Versatile γ-Quaternary Acylcyclopentenes

(2011) Allen Y. Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A non-iterative, flexible, and highly stereoselective synthesis of polydeoxypropionates—synthesis of (+)-vittatalactone

(2011) Christian F. Weise et al.   CHEMICAL COMMUNICATIONS

A highly efficient kinetic resolution of Morita–Baylis–Hillman adducts achieved by N–Ar axially chiral Pd-complexes catalyzed asymmetric allylation

(2011) Feijun Wang et al.   CHEMICAL COMMUNICATIONS

Catalytic enantioselective synthesis of A-86929, a dopamine D1 agonist

(2011) Saumen Hajra et al.   CHEMICAL COMMUNICATIONS

Enhancement of enantioselectivity by alcohol additives in asymmetric hydrogenation with bis(oxazolinyl)phenyl ruthenium catalysts

(2011) Jun-ichi Ito et al.   CHEMICAL COMMUNICATIONS

Update 1 of:C2-Symmetric Chiral Bis(oxazoline) Ligands in Asymmetric Catalysis

(2011) Giovanni Desimoni et al.   CHEMICAL REVIEWS

The Catalytic Asymmetric Diels-Alder Reactions and Post-cycloaddition Reductive Transpositions of 1-Hydrazinodienes

(2011) Hao Xie et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Enantioselective Asymmetric Isomerization of Primary Allylic Alcohols with an Iridium-N,P Complex

(2011) Jia-Qi Li et al.   CHEMISTRY-A EUROPEAN JOURNAL

Total Syntheses of Cyanthiwigins B, F, and G

(2011) John A. Enquist et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Active Ruthenium(II) Complex Catalysts Bearing an Unsymmetrical NNN Ligand in the (Asymmetric) Transfer Hydrogenation of Ketones

(2011) Wenjing Ye et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Copper-Catalysed Propargylic Substitution: Synthetic Scope Study and Application in Formal Total Syntheses of (+)-Anisomycin and (−)-Cytoxazone

(2011) Remko J. Detz et al.   CHEMISTRY-A EUROPEAN JOURNAL

The Synthesis of a New Class of Chiral Pincer Ligands and Their Applications in Enantioselective Catalytic Fluorinations and the Nozaki-Hiyama-Kishi Reaction

(2011) Qing-Hai Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Thiazoline-Oxazoline Ligands and Their Application in Asymmetric Catalysis

(2011) Seán C. McKeon et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Kinetic Resolution of Racemic α-tert-Alkyl-α-hydroxy Esters by Enantiomer-Selective Carbamoylation

(2011) Nobuhito Kurono et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Friedel−Crafts Alkylation of Indoles with Trifluoroethylidene Malonates by Copper−Bis(oxazoline) Complexes: Construction of Trifluoromethyl-Substituted Stereogenic Tertiary Carbon Center

(2011) Lele Wen et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic Enantioselective Aziridoarylation of Aryl Cinnamyl Ethers toward Synthesis oftrans-3-Amino-4-arylchromans

(2011) Saumen Hajra et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective α-Arylation of Carbonyls via Cu(I)-Bisoxazoline Catalysis

(2011) James S. Harvey et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective α-Arylation ofN-Acyloxazolidinones with Copper(II)-bisoxazoline Catalysts and Diaryliodonium Salts

(2011) Aurélien Bigot et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of the Spirocyclic Imine Marine Toxin (−)-Gymnodimine and an Unnatural C4-Epimer

(2011) Ke Kong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Additions to Oxocarbenium Ions: Alkynylation of Isochroman Acetals

(2011) Prantik Maity et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Well-Defined Binuclear Chiral Spiro Copper Catalysts for Enantioselective N–H Insertion

(2011) Shou-Fei Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of All-Carbon Quaternary Stereocenters via Desymmetrization of 2,2-Disubstituted 1,3-Propanediols

(2011) Ji Young Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective construction of quaternary N-heterocycles by palladium-catalysed decarboxylative allylic alkylation of lactams

(2011) Douglas C. Behenna et al.   Nature Chemistry

Asymmetric synthesis of chiral trifluoromethylated heliotridane via highly catalytic asymmetric Friedel–Crafts alkylation with β-trifluoromethylated acrylates and pyrroles

(2011) Yiyong Huang et al.   NEW JOURNAL OF CHEMISTRY

A Catalytic, Asymmetric Formal Synthesis of (+)-Hamigeran B

(2011) Herschel Mukherjee et al.   ORGANIC LETTERS

Enantioselective Michael Addition of Malonates to 2-EnoylpyridineN-Oxides Catalyzed by Chiral Bisoxazoline–Zn(II) Complex

(2011) Sumit K. Ray et al.   ORGANIC LETTERS

Enantioselective and Regioselective Indium(III)-Catalyzed Addition of Pyrroles to Isatins

(2011) Elisa G. Gutierrez et al.   ORGANIC LETTERS

Decarbonylative Cycloaddition of Phthalic Anhydrides with Allenes

(2011) Yosuke Ochi et al.   ORGANIC LETTERS

Fragment-Based Reaction Discovery of Non-Ene-Type Carbon-Carbon Bond-Forming Reactions: Catalytic Asymmetric Oxetane Synthesis by Screening Olefinic Reactants without Allylic Hydrogen

(2011) Koichi Mikami et al.   SYNLETT

Enantioselective Copper-Catalyzed O-H Insertion of α-Diazo Phosphonates

(2011) Qi-Lin Zhou et al.   SYNLETT

Modification of Pseudo-C3-Symmetric Trisoxazoline and Its Application to the Friedel-Crafts Alkylation of Indoles and Pyrrole with Alkylidene Malonates

(2011) Xiu-Li Sun et al.   SYNLETT

Synthesis of planar chiral imidazo[1,5-a]pyridinium salts based on [2.2]paracyclophane for asymmetric β-borylation of enones

(2011) Bing Hong et al.   TETRAHEDRON-ASYMMETRY

Spiro-2,2′-bichroman-based bisoxazoline (SPANbox) ligands for ZnII-catalyzed enantioselective hydroxylation of β-keto esters and 1,3-diester

(2011) Jie Li et al.   Chemical Science

Concerted C–N/C–H Bond Formation in Highly Enantioselective Yttrium(III)-Catalyzed Hydroamination

(2011) Kuntal Manna et al.   ACS Catalysis

A Novel D2-Symmetrical Chiral Tetraoxazoline Ligand for Highly Enantioselective Hydrosilylation of Aromatic Ketones

(2010) Wei Jie Li et al.   ADVANCED SYNTHESIS & CATALYSIS

A Thiourea-Oxazoline Library with Axial Chirality: Ligand Synthesis and Studies of the Palladium-Catalyzed Enantioselective Bis(methoxycarbonylation) of Terminal Olefins

(2010) Ying-Xiang Gao et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Carbonyl-Ene Reactions of Trifluoropyruvate in Ionic Liquid via a Recyclable Indium(III)-Pybox Complex

(2010) Jun Feng Zhao et al.   ADVANCED SYNTHESIS & CATALYSIS

Asymmetric Nazarov Reaction Catalyzed by Chiral Tris(oxazoline)/Copper(II)

(2010) Peng Cao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Iron-Catalyzed Hydrosilane Reduction of Ketones: Effect of Zinc Metal upon the Absolute Configuration

(2010) Tomohiko Inagaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Inter- and Intramolecular Cyclopropanation Reactions Catalyzed by a Reusable Macroporous-Polymer-Supported Chiral Ruthenium(II)/Phenyloxazoline Complex

(2010) Abdel-Moneim Abu-Elfotoh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Oxidative Cross-Coupling Reaction of 3-Indolylmethyl CH Bonds with 1,3-Dicarbonyls Using a Chiral Lewis Acid-Bonded Nucleophile to Control Stereochemistry

(2010) Chang Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bis(oxazolines) based on glycopyranosides – steric, configurational and conformational influences on stereoselectivity

(2010) Tobias Minuth et al.   Beilstein Journal of Organic Chemistry

Asymmetric hydrogenation of ketones catalyzed by a ruthenium(ii)-indan–ambox complex

(2010) Wei Li et al.   CHEMICAL COMMUNICATIONS

Highly regio- and enantioselective catalytic asymmetric hydroboration of α-substituted styrenyl derivatives

(2010) Clément Mazet et al.   CHEMICAL COMMUNICATIONS

Enantioselective Reduction of Ketones and Imines Catalyzed by (CN-Box)ReV-Oxo Complexes

(2010) Kristine A. Nolin et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Cycloadditions of 2-Alkenoylpyridine-N-oxides Catalysed by a Bis(oxazoline)/CuII Complex: Structure of the Reactive Intermediate

(2010) Alessandro Livieri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chiral Bis(oxazolinyl)phenyl RuII Catalysts for Highly Enantioselective Cyclopropanation

(2010) Jun-ichi Ito et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron- and Cobalt-Catalyzed Asymmetric Hydrosilylation of Ketones and Enones with Bis(oxazolinylphenyl)amine Ligands

(2010) Tomohiko Inagaki et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium-Catalyzed Asymmetric Hydrogenation of N-Protected Indoles

(2010) Alejandro Baeza et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Synthesis of (1,3-Butadien-2-yl)methanols from Aldehydes via [1-(Silylmethyl)allenyl]methanols

(2010) María Durán-Galván et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Synthesis of 3,4-Chromanediones via Asymmetric Rearrangement of 3-Allyloxyflavones

(2010) Jean-Charles Marié et al.   JOURNAL OF ORGANIC CHEMISTRY

Development of Bifunctional Aza-Bis(oxazoline) Copper Catalysts for Enantioselective Henry Reaction

(2010) Kai Lang et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective [2 + 2 + 2] Cycloaddition Reaction of Isocyanates and Allenes Catalyzed by Nickel

(2010) Tomoya Miura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Intramolecular Copper Catalyzed C−H Insertion Reactions of α-Diazosulfones

(2010) Christopher J. Flynn et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Flexible Synthesis of Chiral Azacycles via Iridium-Catalyzed Hydrogenation

(2010) J. Johan Verendel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Cationic Polyene Cyclization vs Enantioselective Intramolecular Carbonyl−Ene Reaction

(2010) Yu-Jun Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Asymmetric Protonation of Chiral Calcium Enolates via 1,4-Addition of Malonates

(2010) Thomas Poisson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel/Bis(oxazoline)-Catalyzed Asymmetric Kumada Reactions of Alkyl Electrophiles: Cross-Couplings of Racemic α-Bromoketones

(2010) Sha Lou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Copper-Catalyzed Intramolecular O−H Insertion: An Efficient Approach to Chiral 2-Carboxy Cyclic Ethers

(2010) Shou-Fei Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dynamic Kinetic Asymmetric Synthesis of Substituted Pyrrolidines from Racemic Cyclopropanes and Aldimines: Reaction Development and Mechanistic Insights

(2010) Andrew T. Parsons et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of New C2- Symmetric Fluoren-9-ylidene Malonate Derived Bis(oxazoline) Ligands and Their Application in Friedel-Crafts Reactions

(2010) Jing Li et al.   MOLECULES

A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres

(2010) Jan Streuff et al.   Nature Chemistry

Enantioselective iron-catalysed O–H bond insertions

(2010) Shou-Fei Zhu et al.   Nature Chemistry

Asymmetric copper-catalysed intramolecular C–H insertion reactions of α-diazo-β-keto sulfones

(2010) Catherine N. Slattery et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Direct Alkynylation Catalyzed by Chiral Ru−Bis(oxazolinyl)phenyl Complexes

(2010) Jun-ichi Ito et al.   ORGANIC LETTERS

Diastereo- and Enantioselective Synthesis of α,γ-Diaminobutyric Acid Derivatives via Cu-Catalyzed Asymmetric Michael Reaction

(2010) Qing Li et al.   ORGANIC LETTERS

Highly Enantioselective Nitrone Cycloadditions with 2-Alkenoyl PyridineN-Oxides Catalyzed by Cu(II)−BOX Complexes

(2010) Santiago Barroso et al.   ORGANIC LETTERS

Dinuclear Allylpalladium Complexes ofC2-Symmetric Pyrazolate-Bridged Bis(oxazoline) Ligands (pyrbox's): Structures, Dynamic Behavior, and Application in Asymmetric Allylic Alkylation

(2010) Arne Ficks et al.   ORGANOMETALLICS

Rhodium-Catalyzed Asymmetric Hydrosilylation of Ketones Employing a New Ligand Embodying the Bis(oxazolinyl)pyridine Moiety

(2010) J. Jayashankaran et al.   SYNLETT

Asymmetric Synthesis of Indolines Bearing a Benzylic Quaternary Stereocenter through Intramolecular Arylcyanation of Alkenes

(2010) Yoshiaki Nakao et al.   SYNLETT

Carbohydrate-Derived Bis(oxazoline) Ligand in the Total Synthesis of Grenadamide

(2010) Mike Boysen et al.   SYNTHESIS-STUTTGART

Synthesis of novel chiral oxazoline-Schiff base ligands for the catalytic asymmetric chlorination of β-keto esters

(2010) Ming-Hui Qi et al.   TETRAHEDRON-ASYMMETRY

Highly Enantioselective Construction of the α-Chiral Center of AmidesviaIridium-Catalyzed Hydrogenation of α,β-Unsaturated Amides

(2009) Wei-Jing Lu et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Enantioselective Iridium-Catalyzed Hydrogenation of Trisubstituted Olefins, α,β-Unsaturated Ketones and Imines with Chiral Benzylic Substituted P,N Ligands

(2009) Wei-Jing Lu et al.   ADVANCED SYNTHESIS & CATALYSIS

Catalytic Asymmetric Synthesis of Substituted 3-Hydroxy-2-Oxindoles

(2009) Nadine V. Hanhan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First Regio- and Enantioselective Chromium-Catalyzed Homoallenylation of Aldehydes

(2009) Vincent Coeffard et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Olefin-Oxazolines (OlefOx): Highly Modular, Easily Tunable Ligands for Asymmetric Catalysis

(2009) Björn T. Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A novel planar chiral N-heterocyclic carbene–oxazoline ligand for the asymmetric hydrosilylation of ketones

(2009) Yongqing Kuang et al.   CATALYSIS COMMUNICATIONS

NeoPHOX—an easily accessible P,N-ligand for iridium-catalyzed asymmetric hydrogenation: preparation, scope and application in the synthesis of demethyl methoxycalamenene

(2009) Marcus G. Schrems et al.   CHEMICAL COMMUNICATIONS

Iridium-catalyzed enantioselective hydrogenation of vinyl boronates

(2009) Alexander Paptchikhine et al.   CHEMICAL COMMUNICATIONS

Asymmetric β-boration of α,β-unsaturated carbonyl compounds promoted by chiral rhodium–bisoxazolinylphenyl catalysts

(2009) Takushi Shiomi et al.   CHEMICAL COMMUNICATIONS

Highly enantioselective hydrogenation of α-aryl-β-substituted acrylic acids catalyzed by Ir-SpinPHOX

(2009) Yi Zhang et al.   CHEMICAL COMMUNICATIONS

Bis(oxazolinyl)phenyl transition-metal complexes: asymmetric catalysis and some reactions of the metals

(2009) Hisao Nishiyama et al.   CHEMICAL COMMUNICATIONS

Recent Applications of Oxazoline-Containing Ligands in Asymmetric Catalysis

(2009) Gráinne C. Hargaden et al.   CHEMICAL REVIEWS

The Asymmetric Aza-Claisen Rearrangement: Development of Widely Applicable Pentaphenylferrocenyl Palladacycle Catalysts

(2009) Daniel F. Fischer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iridium-Catalyzed Asymmetric Hydrogenation of Unfunctionalized Enamines

(2009) Alejandro Baeza et al.   CHEMISTRY-A EUROPEAN JOURNAL

A DBFOX-Ph-Based Combinatorial Catalyst for Enantioselective Fluorination of Aryl Acetyl and 3-Butenoyl Thiazolidinones

(2009) Dhande Sudhakar Reddy et al.   Chemistry-An Asian Journal

The Synthesis of New HetPHOX Ligands and Their Application to the Intermolecular Asymmetric Heck Reaction

(2009) Martin O. Fitzpatrick et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

New Thiazoline–Oxazoline Ligands and Their Application in the Asymmetric Friedel–Crafts Reaction

(2009) Seán C. McKeon et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Chiral (Sulfinyl)furyloxazoline Ligands and Its Application to Enantioselective Palladium-Catalyzed Allylic Alkylation

(2009) Yoshitsugu Arai et al.   HETEROCYCLES

New chiral ferrocenyloxazolines: The first planar chiral triferrocenylmethane derivative and its use in asymmetric catalysis

(2009) José Ramon Garabatos-Perera et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Toolbox Approach to the Search for Effective Ligands for Catalytic Asymmetric Cr-Mediated Coupling Reactions

(2009) Haibing Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

New Syntheses of E7389 C14−C35 and Halichondrin C14−C38 Building Blocks: Reductive Cyclization and Oxy-Michael Cyclization Approaches

(2009) Cheng-Guo Dong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Dramatic Improvement in Catalyst Loadings and Molar Ratios of Coupling Partners for Ni/Cr-Mediated Coupling Reactions: Heterobimetallic Catalysts

(2009) Xiang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rational Design of Highly Effective Asymmetric Diels−Alder Catalysts Bearing 4,4′-Sulfonamidomethyl Groups

(2009) Akira Sakakura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Kinetic Resolution of 2,3-Dihydro-2-substituted 4-Quinolones by Palladium-Catalyzed Asymmetric Allylic Alkylation

(2009) Bai-Lin Lei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Synthesis of Tetrahydrofurans: A Dynamic Kinetic Asymmetric [3 + 2] Cycloaddition of Racemic Cyclopropanes and Aldehydes

(2009) Andrew T. Parsons et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

New Syntheses of E7389 C14−C35 and Halichondrin C14−C38 Building Blocks: Double-Inversion Approach

(2009) Dae-Shik Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Intramolecular Redox Reactions: Ring-Fused Tetrahydroquinolines

(2009) Sandip Murarka et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of 3,4-Dihydroisoquinolin-1(2H)-ones by Nickel-Catalyzed Denitrogenative Annulation of 1,2,3-Benzotriazin-4(3H)-ones with Allenes

(2009) Motoshi Yamauchi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Antiselective and Enantioselective Reductive Coupling of Enones and Aromatic Aldehydes with Chiral Rh(Phebox) Catalysts

(2009) Takushi Shiomi et al.   ORGANIC LETTERS

Catalytic Enantioselective Cr-Mediated Propargylation: Application to Halichondrin Synthesis

(2009) Songbai Liu et al.   ORGANIC LETTERS

Use of 5,5-(Dimethyl)-i-Pr-PHOX as a Practical Equivalent tot-Bu-PHOX in Asymmetric Catalysis

(2009) Étienne Bélanger et al.   ORGANIC LETTERS

Highly Enantioselective Cu-Catalyzed Conjugate Addition−Elimination of Activated Allylic Acetates with Glycine Derivatives

(2009) Chun-Gen Chen et al.   ORGANIC LETTERS

Iridium-Catalyzed Asymmetric Hydrogenation of Vinyl Ethers

(2008) Ye Zhu et al.   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Enolate Protonations: Friedel-Crafts Reactions with α-Substituted Acrylates

(2008) Mukund P. Sibi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iridium-Catalyzed Highly Enantioselective Hydrogenation of the CC Bond of α, β-Unsaturated Ketones

(2008) Wei-Jing Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Palladium-Catalyzed Alkylation of Acyclic Amides

(2008) Kai Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric Palladium-Catalyzed Intramolecular α-Arylation of Aldehydes

(2008) Jorge García-Fortanet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Alkylation of Substituted Dioxanone Enol Ethers: Ready Access to C(α)-Tetrasubstituted Hydroxyketones, Acids, and Esters

(2008) Masaki Seto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Enantioselective Synthesis of Optically Active Ketones by Iridium-Catalyzed Asymmetric Hydrogenation

(2008) Sheng-Mei Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Dynamic Kinetic Asymmetric Transformation in the α-Hydroxylation of Racemic Malonates and Its Application to Biologically Active Molecules

(2008) Dhande Sudhakar Reddy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

DBFOX-Ph/metal complexes: Evaluation as catalysts for enantioselective fluorination of 3-(2-arylacetyl)-2-thiazolidinones

(2008) Takehisa Ishimaru et al.   Beilstein Journal of Organic Chemistry

Unexpected effect of the fluorine atom on the optimal ligand-to-palladium ratio in the enantioselective Pd-catalyzed allylation reaction of fluorinated enol carbonates

(2008) Étienne Bélanger et al.   CHEMICAL COMMUNICATIONS

A new NCN pincer ruthenium complex and its catalytic activity for enantioselective hydrogenation of ketones

(2008) Jun-ichi Ito et al.   CHEMICAL COMMUNICATIONS

Chiral Boron-Bridged Bisoxazoline (Borabox) Ligands: Structures and Reactivities of Pd and Cu Complexes

(2008) Valentin Köhler et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Friedel–Crafts Alkylation of Electron‐Rich N‐Heterocycles with Nitroalkenes Catalyzed by Diphenylamine‐Tethered Bis(oxazoline) and Bis(thiazoline) ZnIIComplexes

(2008) Han Liu et al.   Chemistry-An Asian Journal

Asymmetric Henry Reactions Catalyzed by Metal Complexes of Chiral Boron-Bridged Bisoxazoline (borabox) Ligands

(2008) Aurélie Toussaint et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Second-Generation DBFOX Ligands for the Synthesis of β-Substituted α-Amino Acids via Enantioselective Radical Conjugate Additions

(2008) Biplab Banerjee et al.   JOURNAL OF ORGANIC CHEMISTRY

Asymmetric Hydrogenation of Di and Trisubstituted Enol Phosphinates with N,P-Ligated Iridium Complexes

(2008) Pradeep Cheruku et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of the Strychnos Alkaloid (+)-Minfiensine: Tandem Enantioselective Intramolecular Heck−Iminium Ion Cyclization

(2008) Amy B. Dounay et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Meerwein−Eschenmoser Claisen Rearrangement: Asymmetric Synthesis of Allyl Oxindoles

(2008) Elizabeth C. Linton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Arylcyanation of Alkenes Catalyzed by Nickel/AlMe2Cl

(2008) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation

(2008) John A. Enquist Jr et al.   NATURE

Iterative Cr-Mediated Catalytic Asymmetric Allylation To Synthesizesyn/syn- andanti/anti-1,3,5-Triols

(2008) Zhiyu Zhang et al.   ORGANIC LETTERS

Further Improvement on Sulfonamide-Based Ligand for Catalytic Asymmetric 2-Haloallylation and Allylation

(2008) Zhiyu Zhang et al.   ORGANIC LETTERS

Homogeneous Pd-Catalyzed Enantioselective Decarboxylative Protonation

(2008) Smaranda C. Marinescu et al.   ORGANIC LETTERS

New Bis(oxazolinyl)phenyl−Ruthenium(II) Complexes and Their Catalytic Activity for Enantioselective Hydrogenation and Transfer Hydrogenation of Ketones

(2008) Jun-ichi Ito et al.   ORGANOMETALLICS

Enantioselective Rhodium-Catalyzed Alkylative Desymmetrization of 3,5-Dimethylglutaric Anhydride

(2008) Tomislav Rovis et al.   SYNTHESIS-STUTTGART

Desymmetrization-like Catalytic Enantioselective Fluorination of Malonates and Its Application to Pharmaceutically Attractive Molecules

(2007) Dhande Sudhakar Reddy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Catalytic Asymmetric Total Synthesis of Elatol

(2007) David E. White et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of non-symmetric bis(oxazoline)-containing ligands and their application in the catalytic enantioselective Nozaki–Hiyama–Kishi allylation of benzaldehyde

(2007) Gráinne C. Hargaden et al.   ORGANIC & BIOMOLECULAR CHEMISTRY