Catalytic Enantioselective Cyano-Trifluoromethylation of Styrenes

Synthesis of quaternary α-perfluoroalkyl lactams via electrophilic perfluoroalkylation

(2016) D. Katayev et al.   CHEMICAL COMMUNICATIONS

Next Generation of Fluorine-Containing Pharmaceuticals, Compounds Currently in Phase II–III Clinical Trials of Major Pharmaceutical Companies: New Structural Trends and Therapeutic Areas

(2016) Yu Zhou et al.   CHEMICAL REVIEWS

S -Trifluoromethylation of Thiols by Hypervalent Iodine Reagents: A Joint Experimental and Computational Study

(2016) Oliver Sala et al.   CHEMISTRY-A EUROPEAN JOURNAL

New Chiral Reagent for Installation of Pharmacophoric (S)- or (R)-2-(Alkoxyphosphono)-1-amino-2,2-difluoroethyl Groups

(2016) Chen Xie et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic asymmetric detrifluoroacetylative aldol reactions of aliphatic aldehydes for construction of C-F quaternary stereogenic centers

(2016) Lijun Zhang et al.   JOURNAL OF FLUORINE CHEMISTRY

A Dual-Catalytic Strategy To Direct Asymmetric Radical Aminotrifluoromethylation of Alkenes

(2016) Jin-Shun Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes via Radical Process

(2016) Fei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic cascade aldol–cyclization of tertiary ketone enolates for enantioselective synthesis of keto-esters with a C–F quaternary stereogenic center

(2016) Wanxing Sha et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Enantioselective cyanation of benzylic C–H bonds via copper-catalyzed radical relay

(2016) Wen Zhang et al.   SCIENCE

Development and Evaluation of Different Methods for Preparation of Fluorine-Containing (R)- and (S)-N-tert-Butanesulfinyl-aldimines

(2016) Chen Xie et al.   ChemistrySelect

Assembly of Fluorinated Quaternary Stereogenic Centers through Catalytic Enantioselective Detrifluoroacetylative Aldol Reactions

(2015) Chen Xie et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Asymmetric synthesis of quaternary α-fluoro-β-keto-amines via detrifluoroacetylative Mannich reactions

(2015) Chen Xie et al.   CHEMICAL COMMUNICATIONS

Simple access to β-trifluoromethyl-substituted ketones via copper-catalyzed ring-opening trifluoromethylation of substituted cyclopropanols

(2015) Dzmitry G. Kananovich et al.   CHEMICAL COMMUNICATIONS

Expanding the Scope of Hypervalent Iodine Reagents for Perfluoroalkylation: From Trifluoromethyl to Functionalized Perfluoroethyl

(2015) Václav Matoušek et al.   CHEMISTRY-A EUROPEAN JOURNAL

Small-Molecule Therapeutics for Ebola Virus (EBOV) Disease Treatment

(2015) Kunisuke Izawa et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of α,α-difluoro-β-amino carbonyl-containing sulfonamides and related compounds

(2015) Chen Xie et al.   JOURNAL OF FLUORINE CHEMISTRY

Synthesis of Trifluoromethyl-Containing Vicinal Diamines by Asymmetric Decarboxylative Mannich Addition Reactions

(2015) Lingmin Wu et al.   JOURNAL OF ORGANIC CHEMISTRY

Versatile Enantioselective Synthesis of Functionalized Lactones via Copper-Catalyzed Radical Oxyfunctionalization of Alkenes

(2015) Rong Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Trifluoromethylthiocyanation of Alkenes: Convenient Access to CF3-Containing Alkyl Thiocyanates

(2015) Zhaoli Liang et al.   ORGANIC LETTERS

Lewis Acid Catalyzed Synthesis of α-Trifluoromethyl Esters and Lactones by Electrophilic Trifluoromethylation

(2015) Dmitry Katayev et al.   ORGANIC LETTERS

A comprehensive examination of the self-disproportionation of enantiomers (SDE) of chiral amides via achiral, laboratory-routine, gravity-driven column chromatography

(2015) Yuya Suzuki et al.   RSC Advances

Generalized Approach to Asymmetric Synthesis of β-Substituted β-Amino Acids Bearing CHF2, CBrF2, and CClF2Groups

(2015) Yanling Dai et al.   Asian Journal of Organic Chemistry

Enantioselective CH Bond Functionalization Triggered by Radical Trifluoromethylation of Unactivated Alkene

(2014) Peng Yu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intermolecular Trifluoromethylazidation of Alkenes: Convenient Access to CF3-Containing Alkyl Azides

(2014) Fei Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Advances in Catalytic Enantioselective Fluorination, Mono-, Di-, and Trifluoromethylation, and Trifluoromethylthiolation Reactions

(2014) Xiaoyu Yang et al.   CHEMICAL REVIEWS

Good Partnership between Sulfur and Fluorine: Sulfur-Based Fluorination and Fluoroalkylation Reagents for Organic Synthesis

(2014) Chuanfa Ni et al.   CHEMICAL REVIEWS

Synthetic Methods for Compounds Having CF3–S Units on Carbon by Trifluoromethylation, Trifluoromethylthiolation, Triflylation, and Related Reactions

(2014) Xiu-Hua Xu et al.   CHEMICAL REVIEWS

Electrophilic Trifluoromethylation by Use of Hypervalent Iodine Reagents

(2014) Julie Charpentier et al.   CHEMICAL REVIEWS

Recent Advances in Trifluoromethylation Reactions with Electrophilic Trifluoromethylating Reagents

(2014) Sebastián Barata-Vallejo et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-catalyzed intermolecular cyanotrifluoromethylation of alkenes: Convenient synthesis of CF3-containing alkyl nitriles

(2014) Zhaoli Liang et al.   JOURNAL OF FLUORINE CHEMISTRY

Successful fluorine-containing herbicide agrochemicals

(2014) Tomoya Fujiwara et al.   JOURNAL OF FLUORINE CHEMISTRY

Recent advances in the trifluoromethylation methodology and new CF3-containing drugs

(2014) Wei Zhu et al.   JOURNAL OF FLUORINE CHEMISTRY

Copper-Catalyzed Intermolecular Trifluoromethylarylation of Alkenes: Mutual Activation of Arylboronic Acid and CF3+ Reagent

(2014) Fei Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Concise and scalable asymmetric synthesis of 5-(1-amino-2,2,2-trifluoroethyl)thiazolo[3,2-b][1,2,4]triazoles

(2014) Haibo Mei et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

The self-disproportionation of the enantiomers (SDE) of methyl n-pentyl sulfoxide via achiral, gravity-driven column chromatography: a case study

(2014) Alicja Wzorek et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Generalized access to fluorinated β-keto amino compounds through asymmetric additions of α,α-difluoroenolates to CF3-sulfinylimine

(2014) Chen Xie et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Operationally convenient method for preparation of sulfonamides containing α,α-difluoro-β-amino carbonyl moiety

(2014) Chen Xie et al.   TETRAHEDRON LETTERS

Catalytic Enantioselective Difluoroalkylation of Aldehydes

(2013) Peng Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Functionalization of Radical Intermediates in Redox Catalysis: Copper-Catalyzed Asymmetric Oxytrifluoromethylation of Alkenes

(2013) Rong Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Trifluoromethylation Reactions for the Synthesis of β-Trifluoromethylamines

(2013) Hiromichi Egami et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

Copper-Catalyzed Trifluoromethylation-Cyclization of Enynes: Highly Regioselective Construction of Trifluoromethylated Carbocycles and Heterocycles

(2013) Pin Gao et al.   CHEMISTRY-A EUROPEAN JOURNAL

One-Pot Synthesis of Hypervalent Iodine Reagents for Electrophilic Trifluoromethylation

(2013) Václav Matoušek et al.   JOURNAL OF ORGANIC CHEMISTRY

Fluorine Substituents Reduce Charge Recombination and Drive Structure and Morphology Development in Polymer Solar Cells

(2013) Andrew C. Stuart et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Intermolecular Cyanotrifluoromethylation of Alkenes

(2013) Yu-Tao He et al.   ORGANIC LETTERS

LDA-promoted asymmetric synthesis of β-trifluoromethyl-β-amino indanone derivatives with virtually complete stereochemical outcome

(2013) Chen Xie et al.   RSC Advances

Self-disproportionation of enantiomers via achiral chromatography: a warning and an extra dimension in optical purifications

(2012) Vadim A. Soloshonok et al.   CHEMICAL SOCIETY REVIEWS

Rhenium-Catalyzed Trifluoromethylation of Arenes and Heteroarenes by Hypervalent Iodine Reagents

(2012) Esteban Mejía et al.   ACS Catalysis

Copper-Catalyzed Trifluoromethylation of Unactivated Olefins

(2011) Andrew T. Parsons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organic fluorine compounds: a great opportunity for enhanced materials properties

(2011) Ricarda Berger et al.   CHEMICAL SOCIETY REVIEWS

Self-Disproportionation of Enantiomers via Sublimation; New and Truly Green Dimension in Optical Purification

(2011) Jianlin Han et al.   CURRENT ORGANIC SYNTHESIS

Reactivity of an electrophilic hypervalent iodine trifluoromethylation reagent with hydrogen phosphates—A mechanistic study

(2011) Nico Santschi et al.   JOURNAL OF FLUORINE CHEMISTRY

Electrophilic Trifluoromethylation ofS-Hydrogen Phosphorothioates

(2011) Nico Santschi et al.   JOURNAL OF ORGANIC CHEMISTRY

Recent Advances in Catalytic Enantioselective Fluorination Reactions

(2010) Sylvain Lectard et al.   ADVANCED SYNTHESIS & CATALYSIS

Rational application of self-disproportionation of enantiomers via sublimation—a novel methodological dimension for enantiomeric purifications

(2010) Hisanori Ueki et al.   TETRAHEDRON-ASYMMETRY

Highly Efficient Solar Cell Polymers Developed via Fine-Tuning of Structural and Electronic Properties

(2009) Yongye Liang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY