Enantioselective Palladium-Catalyzed Oxidative β,β-Fluoroarylation of α,β-Unsaturated Carbonyl Derivatives

Next Generation of Fluorine-Containing Pharmaceuticals, Compounds Currently in Phase II–III Clinical Trials of Major Pharmaceutical Companies: New Structural Trends and Therapeutic Areas

(2016) Yu Zhou et al.   CHEMICAL REVIEWS

Monofluorination of Organic Compounds: 10 Years of Innovation

(2015) Pier Alexandre Champagne et al.   CHEMICAL REVIEWS

Site-Selective Approach to β-Fluorination: Photocatalyzed Ring Opening of Cyclopropanols

(2015) Steven Bloom et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Enantioselective 1,1-Fluoroarylation of Aminoalkenes

(2015) Ying He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective 1,1-Arylborylation of Alkenes: Merging Chiral Anion Phase Transfer with Pd Catalysis

(2015) Hosea M. Nelson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Enabled Stereoselective β-C(sp3)–H Fluorination: Synthesis of Unnatural Enantiopure anti-β-Fluoro-α-amino Acids

(2015) Ru-Yi Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of Chiral β-Fluoro α-Amino Acids via Pd(II)-Catalyzed Fluorination of Unactivated Methylene C(sp3)–H Bonds: Scope and Mechanistic Studies

(2015) Qi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Site-Selective Fluorination of Unactivated C(sp3)–H Bonds

(2015) Jinmin Miao et al.   ORGANIC LETTERS

Efficient Palladium-Catalyzed C–H Fluorination of C(sp3)–H Bonds: Synthesis of β-Fluorinated Carboxylic Acids

(2015) Qihua Zhu et al.   ORGANIC LETTERS

A Convenient Photocatalytic Fluorination of Unactivated CH Bonds

(2014) Shira D. Halperin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective halogenative semi-pinacol rearrangement: a stereodivergent reaction on a racemic mixture

(2014) Fedor Romanov-Michailidis et al.   CHEMICAL COMMUNICATIONS

Selective fluorination of alkyl C–H bonds via photocatalysis

(2014) Choon Wee Kee et al.   CHEMICAL COMMUNICATIONS

Natural Occurrence of Organofluorine and Other Constituents from Streptomyces sp. TC1

(2014) Nanjundan Jaivel et al.   JOURNAL OF NATURAL PRODUCTS

Triethylborane-Initiated Radical Chain Fluorination: A Synthetic Method Derived from Mechanistic Insight

(2014) Cody Ross Pitts et al.   JOURNAL OF ORGANIC CHEMISTRY

Silver-Catalyzed Radical Fluorination of Alkylboronates in Aqueous Solution

(2014) Zhaodong Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Palladium-Catalyzed Directed Intermolecular Fluoroarylation of Styrenes

(2014) Eric P. A. Talbot et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photocatalyzed Benzylic Fluorination: Shedding “Light” on the Involvement of Electron Transfer

(2014) Steven Bloom et al.   ORGANIC LETTERS

A photocatalyzed aliphatic fluorination

(2014) Steven Bloom et al.   Chemical Science

Vanadium-catalyzed C(sp3)–H fluorination reactions

(2014) Ji-Bao Xia et al.   Organic Chemistry Frontiers

Enantioselective Organocatalytic Fluorination-Induced Wagner-Meerwein Rearrangement

(2013) Fedor Romanov-Michailidis et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fluorine in Pharmaceutical Industry: Fluorine-Containing Drugs Introduced to the Market in the Last Decade (2001–2011)

(2013) Jiang Wang et al.   CHEMICAL REVIEWS

A Two-Step Sequence to Ethyl α-Fluorocyclopropanecarboxylates Through MIRC Reaction of Ethyl Dichloroacetate and Highly Regioselective Fluorination

(2013) Min Zhang et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Metal-Catalyzed Benzylic Fluorination as a Synthetic Equivalent to 1,4-Conjugate Addition of Fluoride

(2013) Steven Bloom et al.   JOURNAL OF ORGANIC CHEMISTRY

Visible Light-Promoted Metal-Free C–H Activation: Diarylketone-Catalyzed Selective Benzylic Mono- and Difluorination

(2013) Ji-Bao Xia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(0)-Catalyzed 1,1-Diarylation of Ethylene and Allylic Carbonates

(2013) Vaneet Saini et al.   ORGANIC LETTERS

Iron(II)-Catalyzed Benzylic Fluorination

(2013) Steven Bloom et al.   ORGANIC LETTERS

Enantioselective fluoride ring opening of aziridines enabled by cooperative Lewis acid catalysis

(2013) Julia A. Kalow et al.   TETRAHEDRON

Rhodium-Catalyzed Enantioselective Nucleophilic Fluorination: Ring Opening of Oxabicyclic Alkenes

(2012) Jiangtao Zhu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed 1,1-Difunctionalization of Ethylene

(2012) Vaneet Saini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalyzed Enantioselective Fluorocyclizations

(2011) Oscar Lozano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Organocatalytic α-Fluorination of Cyclic Ketones

(2011) Piotr Kwiatkowski et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Regio- and Enantioselective Fluorination of Acyclic Allylic Halides

(2011) Matthew H. Katcher et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Palladium-Catalyzed Three-Component Cross-Coupling of Conjugated Dienes or Terminal Alkenes with Vinyl Triflates and Boronic Acids

(2011) Longyan Liao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Investigations of Cooperative Catalysis in the Enantioselective Fluorination of Epoxides

(2011) Julia A. Kalow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Electrophilic Fluorination Using an Anionic Chiral Phase-Transfer Catalyst

(2011) V. Rauniyar et al.   SCIENCE

Chemoselective fluorination of 2-hydroxy-3,4,7,8-tetrahydro-2H-chromen-5(6H)-ones using DAST

(2011) Helio G. Bonacorso et al.   TETRAHEDRON LETTERS

Palladium-Catalyzed Asymmetric Synthesis of Allylic Fluorides

(2010) Matthew H. Katcher et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of C−F Reductive Elimination from Palladium(IV) Fluorides

(2010) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Ring Opening of Epoxides by Fluoride Anion Promoted by a Cooperative Dual-Catalyst System

(2010) Julia A. Kalow et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Oxidative Arylhalogenation of Alkenes: Synthetic Scope and Mechanistic Insights

(2010) Dipannita Kalyani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Organometallic Fluorine Chemistry of Palladium and Rhodium: Studies toward Aromatic Fluorination

(2009) Vladimir V. Grushin   ACCOUNTS OF CHEMICAL RESEARCH

Synthesis and Reactivity of a Mono-σ-Aryl Palladium(IV) Fluoride Complex

(2009) Nicholas D. Ball et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Fluorination of Boronic Acids Mediated by Silver(I) Triflate

(2009) Takeru Furuya et al.   ORGANIC LETTERS

Palladium-Mediated Fluorination of Arylboronic Acids

(2008) Takeru Furuya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cinchona Alkaloid Catalyzed Enantioselective Fluorination of Allyl Silanes, Silyl Enol Ethers, and Oxindoles

(2008) Takehisa Ishimaru et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The highest oxidation states of the transition metal elements

(2008) Sebastian Riedel et al.   COORDINATION CHEMISTRY REVIEWS

Nucleophilic Fluorination of Triflates by Tetrabutylammonium Bifluoride

(2008) Kyu-Young Kim et al.   JOURNAL OF ORGANIC CHEMISTRY

Carbon−Fluorine Reductive Elimination from a High-Valent Palladium Fluoride

(2008) Takeru Furuya et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidatively Intercepting Heck Intermediates:  Pd-Catalyzed 1,2- and 1,1-Arylhalogenation of Alkenes

(2008) Dipannita Kalyani et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY