Enantioselective Palladium-Catalyzed Decarboxylative Allylation of Carbazolones: Total Synthesis of (−)-Aspidospermidine and (+)-Kopsihainanine A

Enantioselective Total Synthesis of the Reported Structures of (−)-9-epi-Presilphiperfolan-1-ol and (−)-Presilphiperfolan-1-ol: Structural Confirmation and Reassignment and Biosynthetic Insights

(2012) Allen Y. Hong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of Tertiary α-Hydroxyketones from Unfunctionalized Ketones: Palladium-Catalyzed Asymmetric Allylic Alkylation of Enolates

(2012) Barry M. Trost et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemical Synthesis of Aspidosperma Alkaloids Inspired by the Reverse of the Biosynthesis of the Rhazinilam Family of Natural Products

(2012) Lindsay McMurray et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Inter- and Intramolecular Formal [4+2] Cycloaddition of Cyclobutanones with Indoles and Total Synthesis of (±)-Aspidospermidine

(2012) Mizuki Kawano et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Asymmetric Allylic Alkylation of Cyclic Dienol Carbonates: Efficient Route to Enantioenriched γ-Butenolides Bearing an All-Carbon α-Quaternary Stereogenic Center

(2012) Jeremy Fournier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Occurrence, Biogenesis, and Synthesis of Biologically Active Carbazole Alkaloids

(2012) Arndt W. Schmidt et al.   CHEMICAL REVIEWS

Total Synthesis of (±)-Kopsihainanine A

(2012) Peng Jing et al.   CHEMISTRY-A EUROPEAN JOURNAL

Pd(II)-Catalyzed Regioselective 2-Alkylation of Indoles via a Norbornene-Mediated C–H Activation: Mechanism and Applications

(2012) Lei Jiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organocatalyzed Enantioselective Formal [4 + 2] Cycloaddition of 2,3-Disubstituted Indole and Methyl Vinyl Ketone

(2012) Quan Cai et al.   ORGANIC LETTERS

The Catalytic Enantioselective Total Synthesis of (+)-Liphagal

(2011) Joshua J. Day et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

(2011) Jaya Prakash Das et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

(2011) Jimmie D. Weaver et al.   CHEMICAL REVIEWS

Collective synthesis of natural products by means of organocascade catalysis

(2011) Spencer B. Jones et al.   NATURE

Kopsihainanines A and B, two unusual alkaloids from Kopsia hainanensis

(2011) Jia Chen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Decarboxylative Allylation of Oxindoles

(2011) Vilius Franckevičius et al.   ORGANIC LETTERS

Catalytic Selective Cyclizations of Aminocyclopropanes: Formal Synthesis of Aspidospermidine and Total Synthesis of Goniomitine

(2010) Filippo De Simone et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total Synthesis of (±)-Aspidospermidine Starting from 3-Ethyl-5-bromo-2-pyrone

(2010) Hyun-Kyu Cho et al.   BULLETIN OF THE KOREAN CHEMICAL SOCIETY

A palladium-catalysed enolate alkylation cascade for the formation of adjacent quaternary and tertiary stereocentres

(2010) Jan Streuff et al.   Nature Chemistry

Concise total synthesis of (±)-aspidospermidine via an oxidative Hosomi–Sakurai process

(2009) Cyrille Sabot et al.   CHEMICAL COMMUNICATIONS

Effect of Fused Benzene Ring on Rotational Barriers of 2,2’-Bifuran, 2-Phenylfuran, Biphenyl, and Their Benzo Analogues

(2009) Naoto Hayashi et al.   HETEROCYCLES

Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation of Enol Carbonates

(2009) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Enantioselective Alkylation of Substituted Dioxanone Enol Ethers: Ready Access to C(α)-Tetrasubstituted Hydroxyketones, Acids, and Esters

(2008) Masaki Seto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cycloisomerization of 1,n-Enynes: Challenging Metal-Catalyzed Rearrangements and Mechanistic Insights

(2008) Véronique Michelet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Discovery of benzamide tetrahydro-4H-carbazol-4-ones as novel small molecule inhibitors of Hsp90

(2008) Thomas E. Barta et al.   BIOORGANIC & MEDICINAL CHEMISTRY LETTERS

Domino Double Michael−Claisen Cyclizations: A Powerful General Tool for Introducing Quaternary Stereocenters at C(4) of Cyclohexane-1,3-diones and Total Synthesis of Diverse Families of Sterically Congested Alkaloids

(2008) Teruhiko Ishikawa et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Formation of Fused Tricyclic Amines from Acyclic Aldehydes by a Cascade Process Involving Condensation, Cyclization, and Dipolar Cycloaddition

(2008) Adam J. M. Burrell et al.   JOURNAL OF ORGANIC CHEMISTRY

The total synthesis of (-)-cyanthiwigin F by means of double catalytic enantioselective alkylation

(2008) John A. Enquist Jr et al.   NATURE

Asymmetric Construction of Quaternary Carbon Centers by Sequential Conjugate Addition of Lithium Amide and in Situ Alkylation: Utility in the Synthesis of (−)-Aspidospermidine

(2008) Mayuko Suzuki et al.   ORGANIC LETTERS

Amidyls in radical cascades. The total synthesis of (±)-aspidospermidine and (±)-13-deoxyserratine

(2008) Anne-Claude Callier-Dublanchet et al.   TETRAHEDRON

The Catalytic Asymmetric Total Synthesis of Elatol

(2007) David E. White et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY