Asymmetric Induction at Remote Quaternary Centers of Cyclohexadienones by Rhodium-Catalyzed Conjugate Hydrosilylation

Catalytic Enantioselective Construction of Quaternary Stereocenters: Assembly of Key Building Blocks for the Synthesis of Biologically Active Molecules

(2015) Yiyang Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Phosphine-Catalyzed β,γ-Umpolung Domino Reaction of Allenic Esters: Facile Synthesis of Tetrahydrobenzofuranones Bearing a Chiral Tetrasubstituted Stereogenic Carbon Center

(2015) Shinobu Takizawa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total syntheses of natural products containing spirocarbocycles

(2015) Laura K. Smith et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Organocatalytic asymmetric desymmetrization of 4,4-disubstituted cyclohexadienones via an intermolecular Diels–Alder reaction

(2015) Ryukichi Takagi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Remote functionalization of hydrocarbons with reversibility enhanced stereocontrol

(2015) Alexandre Vasseur et al.   Chemical Science

Synthetic and Mechanistic Studies on the Rhodium-Catalyzed Redox Isomerization of Cyclohexa-2,5-dienols

(2015) Steffen Kress et al.   ACS Catalysis

Investigating the Nature of Palladium Chain-Walking in the Enantioselective Redox-Relay Heck Reaction of Alkenyl Alcohols

(2014) Margaret J. Hilton et al.   JOURNAL OF ORGANIC CHEMISTRY

Catalytic enantioselective synthesis of quaternary carbon stereocentres

(2014) Kyle W. Quasdorf et al.   NATURE

Enantioselective construction of remote quaternary stereocentres

(2014) Tian-Sheng Mei et al.   NATURE

Asymmetric organocatalytic desymmetrization of 4,4-disubstituted cyclohexadienones at high pressure: a new powerful strategy for the synthesis of highly congested chiral cyclohexenones

(2014) Naomu Miyamae et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric transformations of achiral 2,5-cyclohexadienones

(2014) Kyle A. Kalstabakken et al.   TETRAHEDRON

Foldamer-Mediated Remote Stereocontrol: >1,60 Asymmetric Induction

(2013) Liam Byrne et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic asymmetric desymmetrization: efficient construction of spirocyclic oxindoles bearing a unique all-carbon quaternary stereogenic center via sulfa-Michael addition

(2013) Lu Yao et al.   CHEMICAL COMMUNICATIONS

The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

(2013) Allen Y. Hong et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Redox-Relay Oxidative Heck Arylations of Acyclic Alkenyl Alcohols using Boronic Acids

(2013) Tian-Sheng Mei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Merging allylic carbon–hydrogen and selective carbon–carbon bond activation

(2013) Ahmad Masarwa et al.   NATURE

Enantioselective Rh-Catalyzed Domino Transformations of Alkynylcyclohexadienones with Organoboron Reagents

(2013) Juliane Keilitz et al.   ORGANIC LETTERS

Computational investigations on the phosphine-ligated CuH-catalyzed conjugate reduction of α-β unsaturated ketones: regioselectivity and stereoselectivity

(2013) Hangyu Liu et al.   RSC Advances

Enantioselective Synthesis of Optically Active 3,3-Diarylpropanoates by Conjugate Hydrosilylation with Chiral Rh-bis(oxazolinyl)phenyl Catalysts

(2012) Kengou Itoh et al.   JOURNAL OF ORGANIC CHEMISTRY

Diastereoselective and Enantioselective Desymmetrization of α-Substituted Cyclohexadienones via Intramolecular Stetter Reaction

(2012) Min-Qiang Jia et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Heck Arylations of Acyclic Alkenyl Alcohols Using a Redox-Relay Strategy

(2012) E. W. Werner et al.   SCIENCE

Facile synthesis of α-methylidene-γ-butyrolactones: intramolecular Rauhut–Currier reaction promoted by chiral acid–base organocatalysts

(2012) Shinobu Takizawa et al.   TETRAHEDRON

An enantioselective synthesis of 3-aryl-4-phosphonobutyric acid esters via Cu-catalyzed asymmetric conjugate reduction

(2012) Wei-Lei Guo et al.   TETRAHEDRON-ASYMMETRY

Enantioselective synthesis of all-carbon quaternary stereogenic centers in acyclic systems

(2011) Jaya Prakash Das et al.   CHEMICAL COMMUNICATIONS

Conjugate reduction and reductive aldol cyclization of α,β-unsaturated thioesters catalyzed by (BDP)CuH

(2011) Ninglin Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Theoretical studies on the mechanism and stereoselectivity of Rh(Phebox)-catalyzed asymmetric reductive aldol reaction

(2011) Yun-Fang Yang et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of β-Amino Acid Derivatives via Copper-Catalyzed Asymmetric 1,4-Reduction of β-(Acylamino)acrylates

(2011) Yan Wu et al.   ORGANIC LETTERS

Preparation of chiral secondary boronic esters via copper-catalyzed enantioselective conjugate reduction of β-boronyl-β-alkyl α,β-unsaturated esters

(2011) Jinyue Ding et al.   TETRAHEDRON

Metal-Catalyzed α-Arylation of Carbonyl and Related Molecules: Novel Trends in CC Bond Formation by CH Bond Functionalization

(2010) Carin C. C. Johansson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-catalyzed asymmetric conjugate addition reaction: formation of quaternary stereocenters

(2010) Christine Hawner et al.   CHEMICAL COMMUNICATIONS

A New Powerful Strategy for the Organocatalytic Asymmetric Construction of a Quaternary Carbon Stereogenic Center

(2010) Yogo Inokoishi et al.   ORGANIC LETTERS

Bis(oxazolinyl)phenyl transition-metal complexes: asymmetric catalysis and some reactions of the metals

(2009) Hisao Nishiyama et al.   CHEMICAL COMMUNICATIONS

Transition Metal-Catalyzed Direct Arylation of Substrates with Activated sp3-Hybridized C−H Bonds and Some of Their Synthetic Equivalents with Aryl Halides and Pseudohalides

(2009) Fabio Bellina et al.   CHEMICAL REVIEWS

CuH-Catalyzed Reactions

(2008) Carl Deutsch et al.   CHEMICAL REVIEWS