RhIII -Catalyzed Direct C8-Arylation of Quinoline N -Oxides using Diazonaphthalen-2(1H )-ones: A Practical Approach towards 8-aza BINOL

Increasing Catalyst Efficiency in C−H Activation Catalysis

(2018) Tobias Gensch et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

RhII -Catalyzed Intermolecular C−H Arylation of Aromatics with Diazo Quinones

(2018) Kai Wu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium(III)-Catalyzed Regioselective Direct C4-Alkylation and C2-Annulation of Indoles: Straightforward Access to Indolopyridone

(2018) Aniruddha Biswas et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

C-Glycosylation of Substituted β-Naphthols with Trichloroacet­imidate Glycosyl Donors

(2018) Dipakranjan Mal et al.   SYNTHESIS-STUTTGART

Regioselective Construction of Functionalized Biarylols by Fe(OTf)3 -Catalyzed Direct Arylation of 1-Diazonaphthalen-2(1H )-ones and Their Fluorescence Properties

(2017) Krishna Bahadur Somai Magar et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Metal-Catalyzed Direct C-H Fluoroalkenylation of Pyridine N -Oxides and Related Derivatives

(2017) Alexis Lehecq et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Iridium-Catalysed Cascade Synthesis of Oxindoles Using Diazo Compounds: A Quick Entry to C-7-Functionalized Oxindoles

(2017) Ujjwal Karmakar et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Direct, Regioselective Arylamination of N-Oxides: Studies To Access Conjugated π-Systems

(2017) Aniruddha Biswas et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(III)-Catalyzed C6-Selective Arylation of 2-Pyridones and Related Heterocycles Using Quinone Diazides: Syntheses of Heteroarylated Phenols

(2017) Debapratim Das et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Regio- and Chemoselective [4 + 1]-Annulation of Azoxy Compounds with Diazoesters for the Synthesis of 2H-Indazoles: Roles of the Azoxy Oxygen Atom

(2017) Zhen Long et al.   ORGANIC LETTERS

Rh(III)-Catalyzed C–H Activation/Cyclization of Benzamides and Diazonaphthalen-2(1H)-ones for Synthesis of Lactones

(2017) Renjie Chen et al.   ORGANIC LETTERS

Direct C–H Cyanoalkylation of Heteroaromatic N-Oxides and Quinones via C–C Bond Cleavage of Cyclobutanone Oximes

(2017) Yu-Rui Gu et al.   ORGANIC LETTERS

Ir(III)-Catalyzed Direct C–H Functionalization of Arylphosphine Oxides: A Strategy for MOP-Type Ligands Synthesis

(2017) Zhong Liu et al.   ORGANIC LETTERS

A C–H Activation-Based Strategy for N-Amino Azaheterocycle Synthesis

(2017) Pengfei Shi et al.   ORGANIC LETTERS

Copper-Catalyzed Remote C−H Nitration of 8-Amidoquinolines

(2017) Bhuttu Khan et al.   ChemistrySelect

Palladium-Catalyzed Selective CH Activation: A Simple Method to Synthesize C-3 Site Arylated Quinoline Derivatives

(2016) Yongqin He et al.   ADVANCED SYNTHESIS & CATALYSIS

Cooperative Lewis Acid/Cp*CoIIICatalyzed C−H Bond Activation for the Synthesis of Isoquinolin-3-ones

(2016) Ju Hyun Kim et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-catalyzed C–H activation of 3-(indolin-1-yl)-3-oxopropanenitriles with diazo compounds and tandem cyclization leading to hydrogenated azepino[3,2,1-hi]indoles

(2016) Tao Zhou et al.   CHEMICAL COMMUNICATIONS

The microwave-assisted ortho-alkylation of azine N-oxides with N-tosylhydrazones catalyzed by copper(i) iodide

(2016) Abadh Kishor Jha et al.   CHEMICAL COMMUNICATIONS

Cobalt(iii) catalyzed C-8 selective C–H and C–O coupling of quinoline N-oxide with internal alkynes via C–H activation and oxygen atom transfer

(2016) Nagaraju Barsu et al.   CHEMICAL COMMUNICATIONS

Transition-Metal-Catalyzed C–H Bond Addition to Carbonyls, Imines, and Related Polarized π Bonds

(2016) Joshua R. Hummel et al.   CHEMICAL REVIEWS

Catalytic asymmetric dearomatization (CADA) reactions of phenol and aniline derivatives

(2016) Wen-Ting Wu et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Regioselective Cascade Alkylation and Cyclocondensation of Quinoline N -Oxides with Diazo Esters: Direct Access to Conjugated π-Systems

(2016) Aniruddha Biswas et al.   CHEMISTRY-A EUROPEAN JOURNAL

C6-Selective Direct Alkylation of Pyridones with Diazo Compounds under Rh(III)-Catalyzed Mild Conditions

(2016) Debapratim Das et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Synthesis of N-Unprotected Indoles from Imidamides and Diazo Ketoesters via C–H Activation and C–C/C–N Bond Cleavage

(2016) Zisong Qi et al.   ORGANIC LETTERS

C-8-Selective Allylation of Quinoline: A Case Study of β-Hydride vs β-Hydroxy Elimination

(2016) Deepti Kalsi et al.   ORGANIC LETTERS

C8-Selective Acylation of Quinoline N-Oxides with α-Oxocarboxylic Acids via Palladium-Catalyzed Regioselective C–H Bond Activation

(2016) Xiaopei Chen et al.   ORGANIC LETTERS

“One-Pot” Approach to 8-Acylated 2-Quinolinones via Palladium-Catalyzed Regioselective Acylation of Quinoline N-Oxides

(2016) Xiaopei Chen et al.   ORGANIC LETTERS

3-Naphthylindole Construction by Rhodium(II)-Catalyzed Regioselective Direct Arylation of Indoles with 1-Diazonaphthalen-2-(1H)-ones

(2015) Ek Raj Baral et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct Asymmetric Dearomatization of 2-Naphthols by Scandium-Catalyzed Electrophilic Amination

(2015) Jiang Nan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Neutral Rhodium-Catalyzed CH Functionalization of ArylamineN-Oxides with Diazo Compounds: Primary C(sp3)H/C(sp2)H Activation and Oxygen-Atom Transfer

(2015) Bing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Intermolecular Enantioselective Dearomatization Reaction of β-Naphthol Usingmeso-Aziridine: A Bifunctional In Situ Generated Magnesium Catalyst

(2015) Dongxu Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A [4+1] Cyclative Capture Approach to 3H-Indole-N-oxides at Room Temperature by Rhodium(III)-Catalyzed CH Activation

(2015) Yaxi Yang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C–H bond functionalization based on metal carbene migratory insertion

(2015) Fangdong Hu et al.   CHEMICAL COMMUNICATIONS

One-pot cascade synthesis of N-methoxyisoquinolinediones via Rh(iii)-catalyzed carbenoid insertion C–H activation/cyclization

(2015) Jingjing Shi et al.   CHEMICAL COMMUNICATIONS

Experimental and mechanistic analysis of the palladium-catalyzed oxidative C8-selective C–H homocoupling of quinoline N-oxides

(2015) David E. Stephens et al.   CHEMICAL COMMUNICATIONS

Cp*Rh(iii) and Cp*Ir(iii)-catalysed redox-neutral C–H arylation with quinone diazides: quick and facile synthesis of arylated phenols

(2015) Shang-Shi Zhang et al.   CHEMICAL COMMUNICATIONS

Direct C–H alkylation and indole formation of anilines with diazo compounds under rhodium catalysis

(2015) Neeraj Kumar Mishra et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed Direct Sulfoximination of HeteroaromaticN-Oxides by Dual C−H/N−H Dehydrogenative Cross-Coupling

(2015) Hao Yu et al.   Chemistry-An Asian Journal

RhIII-Catalyzed Dehydrogenative Coupling of QuinolineN-Oxides with Alkenes:N-Oxide as Traceless Directing Group for Remote C-H Activation

(2015) Ritika Sharma et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Copper-Mediated Formally Dehydrative Biaryl Coupling of Azine N-Oxides and Oxazoles

(2015) Riko Odani et al.   JOURNAL OF ORGANIC CHEMISTRY

Cp*Ir(III)-Catalyzed Mild and Broad C−H Arylation of Arenes and Alkenes with Aryldiazonium Salts Leading to the External Oxidant-Free Approach

(2015) Kwangmin Shin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed C–H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and Theoretical Studies

(2015) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(ii)-catalyzed electrophilic amination of quinoline N-oxides with O-benzoyl hydroxylamines

(2015) Gang Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Cinnolin-3(2H)-one Derivatives from Rh-Catalyzed Reaction of Azobenzenes with Diazotized Meldrum’s Acid

(2015) Jeong-Yu Son et al.   ORGANIC LETTERS

Rh(III)-Catalyzed [4 + 2] Annulation of Indoles with Diazo Compounds: Access to Pyrimido[1,6-a]indole-1(2H)-ones

(2015) Xun Chen et al.   ORGANIC LETTERS

Synthesis, Properties, and Enantiomerization Behavior of Axially Chiral Phenolic Derivatives of 8-(Naphth-1-yl)quinoline and Comparison to 7,7′-Dihydroxy-8,8′-biquinolyl and 1,1′-Bi-2-naphthol

(2015) Paul Blakemore et al.   SYNTHESIS-STUTTGART

Recent advances in the C–H-functionalization of the distal positions in pyridines and quinolines

(2015) David E. Stephens et al.   TETRAHEDRON

From Indoles to Carbazoles: Tandem Cp*Rh(III)-Catalyzed C–H Activation/Brønsted Acid-Catalyzed Cyclization Reactions

(2015) Jia-Qiang Wu et al.   ACS Catalysis

Transition-Metal-Catalyzed Site-Selective C–H Functionalization of Quinolines beyond C2 Selectivity

(2015) Tomohiro Iwai et al.   ACS Catalysis

The development of carbene-stabilized N–O radical coupling strategy in metal-free regioselective C–H azidation of quinoline N-oxides

(2015) Pan Li et al.   Organic Chemistry Frontiers

Cobalt-Catalyzed C-4 Selective Alkylation of Quinolines

(2014) Shohei Yamamoto et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent Advances in Catalytic Functionalization ofN-Oxide CompoundsviaCH Bond Activation

(2014) Guobing Yan et al.   ADVANCED SYNTHESIS & CATALYSIS

Formal SN-Type Reactions in Rhodium(III)-Catalyzed CH Bond Activation

(2014) Nadine Kuhl et al.   ADVANCED SYNTHESIS & CATALYSIS

Quinone Diazides for Olefin Functionalization

(2014) Hai T. Dao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed CC and CO Coupling of QuinolineN-Oxides with Alkynes: Combination of CH Activation with O-Atom Transfer

(2014) Xueyun Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)- and Iridium(III)-Catalyzed C7 Alkylation of Indolines with Diazo Compounds

(2014) Wen Ai  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh(III)-Catalyzed Traceless Coupling of Quinoline N-Oxides with Internal Diarylalkynes

(2014) Upendra Sharma et al.   JOURNAL OF ORGANIC CHEMISTRY

Regioselective Introduction of Heteroatoms at the C-8 Position of Quinoline N-Oxides: Remote C–H Activation Using N-Oxide as a Stepping Stone

(2014) Heejun Hwang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd(OAc)2-Catalyzed Macrocyclization of 1,2-Diazonaphthoquinones with Cyclic Ethers

(2014) Mitsuru Kitamura et al.   ORGANIC LETTERS

Rhodium(III)-Catalyzed C–C Bond Formation of Quinoline N-Oxides at the C-8 Position under Mild Conditions

(2014) Jisu Jeong et al.   ORGANIC LETTERS

Copper-Catalyzed Direct Amination of Quinoline N-Oxides via C–H Bond Activation under Mild Conditions

(2014) Chongwei Zhu et al.   ORGANIC LETTERS

A Facile Route to H-Pyrazolo[5,1-a]isoquinolines through a Multicomponent Reaction of 2-Alkynylbenzaldehyde, Sulfonylhydrazine, and Benzyne

(2014) Jie Wu et al.   SYNTHESIS-STUTTGART

Palladium-Catalyzed C8-Selective C–H Arylation of Quinoline N-Oxides: Insights into the Electronic, Steric, and Solvation Effects on the Site Selectivity by Mechanistic and DFT Computational Studies

(2014) David E. Stephens et al.   ACS Catalysis

Direct C-2 Alkylation of QuinolineN-Oxides with EthersviaPalladium-Catalyzed Dehydrogenative Cross-Coupling Reaction

(2013) Zhiyong Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-CatalyzedorthoAlkenylation ofN-Phenoxyacetamides withN-Tosylhydrazones or Diazoesters through CH Activation

(2013) Fangdong Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct 2-acetoxylation of quinoline N-oxides via copper catalyzed C–H bond activation

(2013) Xuan Chen et al.   CHEMICAL COMMUNICATIONS

C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

(2013) Joanna Wencel-Delord et al.   Nature Chemistry

Synthesis of Diverse Indene Derivatives from 1-Diazonaphthalen-2(1H)-ones via Thermal Cascade Reactions

(2013) Krishna Bahadur Somai Magar et al.   ORGANIC LETTERS

Copper-Catalyzed Intermolecular Dehydrogenative Amidation/Amination of Quinoline N-Oxides with Lactams/Cyclamines

(2013) Gang Li et al.   ORGANIC LETTERS

Sulfonylation of Quinoline N-Oxides with Aryl Sulfonyl Chlorides via Copper-Catalyzed C–H Bonds Activation

(2013) Zhiyong Wu et al.   ORGANIC LETTERS

A Versatile Rhodium(I) Catalyst System for the Addition of Heteroarenes to both Alkenes and Alkynes by a CH Bond Activation

(2012) Jaeyune Ryu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CH Bond Functionalization: Emerging Synthetic Tools for Natural Products and Pharmaceuticals

(2012) Junichiro Yamaguchi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

From C(sp2)–H to C(sp3)–H: systematic studies on transition metal-catalyzed oxidative C–C formation

(2012) Bi-Jie Li et al.   CHEMICAL SOCIETY REVIEWS

C–C, C–O and C–N bond formation via rhodium(iii)-catalyzed oxidative C–H activation

(2012) Guoyong Song et al.   CHEMICAL SOCIETY REVIEWS

Elements of Regiocontrol in the Direct Heteroarylation of Indoles/Pyrroles: Synthesis of Bi- and Fused Polycyclic Heteroarenes by Twofold or Tandem Fourfold CH Activation

(2012) Zhen Wang et al.   CHEMISTRY-A EUROPEAN JOURNAL

Discovery of a Full-Color-Tunable Fluorescent Core Framework through Direct CH (Hetero)arylation of N-Heterocycles

(2012) Bo Liu et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silylcyanation of Aldehydes, Ketones, and Imines Catalyzed by a 6,6′-Bis-sulfonamide Derivative of 7,7′-Dihydroxy-8,8′-biquinolyl (azaBINOL)

(2012) Selena Milicevic Sephton et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Heteroarylation of Azine N-Oxides

(2012) Francis Gosselin et al.   ORGANIC LETTERS

Palladium-Catalyzed Oxidative CH/CH Cross-Coupling of Indoles and Pyrroles with Heteroarenes

(2011) Zhen Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Benzannulation for the Regiodefined Synthesis of 2-Alkyl/Aryl-1-naphthols: Total Synthesis of Arnottin I

(2011) Dipakranjan Mal et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(NHC)-Catalyzed Direct and Selective Arylation of Quinolines at the 8-Position

(2011) Jaesung Kwak et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of 7,7′-Dihydroxy-8,8′-biquinolyl (azaBINOL) via Pd-Catalyzed Directed Double C–H Functionalization of 8,8′-Biquinolyl: Emergence of anAtroposfrom aTroposState

(2011) Chao Wang et al.   ORGANIC LETTERS

Palladium-Catalyzed Oxidative Cross-Coupling between PyridineN-Oxides and Indoles

(2011) Xue Gong et al.   ORGANIC LETTERS

Transition-Metal-Catalyzed C-H Functionalization for the Synthesis of Substituted Pyridines

(2011) Yoshiaki Nakao   SYNTHESIS-STUTTGART

Direct arylations of electron-deficient (hetero)arenes with aryl or alkenyl tosylates and mesylates

(2010) Lutz Ackermann et al.   CHEMICAL COMMUNICATIONS

Synthesis of Multicyclic Pyridine and Quinoline Derivatives via Intramolecular C−H Bond Functionalization

(2010) Sirilata Yotphan et al.   ORGANIC LETTERS

Copper-Catalyzed Direct C Arylation of Heterocycles with Aryl Bromides: Discovery of Fluorescent Core Frameworks

(2009) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium(II)-Catalyzed CH Activation/CC Cross-Coupling Reactions: Versatility and Practicality

(2009) Xiao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed C3 or C4 Direct Arylation of Heteroaromatic Compounds with Aryl Halides by CH Bond Activation

(2009) Julien Roger et al.   ChemCatChem

Rhodium-Catalyzed C−C Bond Formation via Heteroatom-Directed C−H Bond Activation

(2009) Denise A. Colby et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Direct Arylation of Azine and AzoleN-Oxides: Reaction Development, Scope and Applications in Synthesis

(2009) Louis-Charles Campeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design, Synthesis and Optical Resolution of New Bifunctional Ligand: 1,1′-Dimethyl-octahydro-8,8′-Biquinoline-7,7′-diol

(2009) Jian Xiao et al.   ORGANIC LETTERS

Palladium-Catalyzed C−H Functionalization of PyridineN-Oxides: Highly Selective Alkenylation and Direct Arylation with Unactivated Arenes

(2008) Seung Hwan Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic C–H functionalization by metal carbenoid and nitrenoid insertion

(2008) Huw M. L. Davies et al.   NATURE