Journal
ORGANIC LETTERS
Volume 19, Issue 15, Pages 4002-4005Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.7b01728
Keywords
-
Categories
Funding
- National Natural Science Foundation of China [21472163]
Ask authors/readers for more resources
A Rh(III)-catalyzed C-H activation/cyclization of benzamides and diazonaphthalen-2(1H)-ones for synthesis of lactones has been developed. In the presence of Rh(III) catalysis, the benzamides would form rhodacycle species and could be trapped by diazonaphthalen-2(1H)-ones for arylation, and the following intramolecular lactonization would rapidly furnish the products.. Thus, the diazonaphthalen-2(1H)-ones were first revealed as a lactonization component in Rh(III)-catalysis, while the kinetic isotope effect study was conducted and a plausible reaction mechanism was proposed.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available