Direct C–H alkylation and indole formation of anilines with diazo compounds under rhodium catalysis

Synthesis of Heterocycle-fused PyridineN-Oxides from Oximes and Diazo CompoundsviaRhIII-Catalyzed CH Activation and Annulation

(2015) Peng Sun et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium(III)-Catalyzed Selective CH Cyanation of Indolines and Indoles with an Easily Accessible Cyano Source

(2015) Neeraj Kumar Mishra et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper(I)-Catalyzed Alkylation of Polyfluoroarenes through Direct CH Bond Functionalization

(2015) Shuai Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Redox-Neutral Rhodium-Catalyzed CH Functionalization of ArylamineN-Oxides with Diazo Compounds: Primary C(sp3)H/C(sp2)H Activation and Oxygen-Atom Transfer

(2015) Bing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt(III)-Catalyzed Directed CH Coupling with Diazo Compounds: Straightforward Access towards Extended π-Systems

(2015) Dongbing Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective Syntheses of 1,2-Benzothiazines by Rhodium-Catalyzed Annulation Reactions

(2015) Ying Cheng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-pot cascade synthesis of N-methoxyisoquinolinediones via Rh(iii)-catalyzed carbenoid insertion C–H activation/cyclization

(2015) Jingjing Shi et al.   CHEMICAL COMMUNICATIONS

Synthesis of N-Sulfonylamidated and Amidated Azobenzenes under Rhodium Catalysis

(2015) Sangil Han et al.   JOURNAL OF ORGANIC CHEMISTRY

Mild Rh(III)-Catalyzed C7-Allylation of Indolines with Allylic Carbonates

(2015) Jihye Park et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed C–H Amidation of Indoles with Isocyanates

(2015) Taejoo Jeong et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium-Catalyzed C–H Activation of Phenacyl Ammonium Salts Assisted by an Oxidizing C–N Bond: A Combination of Experimental and Theoretical Studies

(2015) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(III)-Catalyzed Direct Coupling of Azobenzenes with α-Diazo Esters: Facile Synthesis of Cinnolin-3(2H)-ones

(2015) Satyasheel Sharma et al.   ORGANIC LETTERS

Synthesis of Cinnolin-3(2H)-one Derivatives from Rh-Catalyzed Reaction of Azobenzenes with Diazotized Meldrum’s Acid

(2015) Jeong-Yu Son et al.   ORGANIC LETTERS

Realized C–H Functionalization of Aryldiazo Compounds via Rhodium Relay Catalysis

(2015) Lin Qiu et al.   ORGANIC LETTERS

Ruthenium-Catalyzed Heteroatom-Directed Regioselective C–H Arylation of Indoles Using a Removable Tether

(2015) Virendra Kumar Tiwari et al.   ORGANIC LETTERS

Indole synthesis through transition metal-catalyzed C–H activation

(2015) Tenglong Guo et al.   TETRAHEDRON LETTERS

Direct access to isoindolines through tandem Rh(iii)-catalyzed alkenylation and cyclization of N-benzyltriflamides

(2014) Neeraj Kumar Mishra et al.   CHEMICAL COMMUNICATIONS

Rh(iii)-catalyzed synthesis of 1-aminoindole derivatives from 2-acetyl-1-arylhydrazines and diazo compounds in water

(2014) Yujie Liang et al.   CHEMICAL COMMUNICATIONS

Rhodium(III)- and Iridium(III)-Catalyzed C7 Alkylation of Indolines with Diazo Compounds

(2014) Wen Ai  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rh(III)-Catalyzed C–H Activation/Cyclization of Indoles and Pyrroles: Divergent Synthesis of Heterocycles

(2014) Yan Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Rhodium(iii)-catalyzed formal oxidative [4 + 1] cycloaddition of benzohydroxamic acids and α-diazoesters. A facile synthesis of functionalized benzolactams

(2014) Hon-Wah Lam et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rh-catalyzed oxidative C–C bond formation and C–N bond cleavage: direct access to C2-olefinated free (NH)-indoles and pyrroles

(2014) Satyasheel Sharma et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Rhodium(III)-Catalyzed C–C Bond Formation of Quinoline N-Oxides at the C-8 Position under Mild Conditions

(2014) Jisu Jeong et al.   ORGANIC LETTERS

Rh(III)-Catalyzed Oxidative Coupling of 1,2-Disubstituted Arylhydrazines and Olefins: A New Strategy for 2,3-Dihydro-1H-Indazoles

(2014) Sangil Han et al.   ORGANIC LETTERS

Rhodium(III)-CatalyzedorthoAlkenylation ofN-Phenoxyacetamides withN-Tosylhydrazones or Diazoesters through CH Activation

(2013) Fangdong Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium(III)-Catalyzed Azacycle-Directed Intermolecular Insertion of Arene C–H Bonds into α-Diazocarbonyl Compounds

(2013) Xinzhang Yu et al.   JOURNAL OF ORGANIC CHEMISTRY

Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinoline and Pyridine N-Oxides from Oximes and Diazo Compounds

(2013) Zhuangzhi Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Directed C–H Cyanation of Arenes with N-Cyano-N-phenyl-p-toluenesulfonamide

(2013) Tian-Jun Gong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Coupling of Benzamides and Donor/Acceptor Diazo Compounds To Form γ-Lactams via Rh(III)-Catalyzed C–H Activation

(2013) Todd K. Hyster et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium Catalyzed Cyanation of Chelation Assisted C–H Bonds

(2013) Manthena Chaitanya et al.   ORGANIC LETTERS

Rh(iii)-catalyzed C–H activation/[4 + 3] cycloaddition of benzamides and vinylcarbenoids: facile synthesis of azepinones

(2013) Sunliang Cui et al.   Chemical Science

Direct Functionalization Processes: A Journey from Palladium to Copper to Iron to Nickel to Metal-Free Coupling Reactions

(2012) James J. Mousseau et al.   ACCOUNTS OF CHEMICAL RESEARCH

On the Interpretation of Deuterium Kinetic Isotope Effects in CH Bond Functionalizations by Transition-Metal Complexes

(2012) Eric M. Simmons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Beyond Directing Groups: Transition-Metal-Catalyzed CH Activation of Simple Arenes

(2012) Nadine Kuhl et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rh-Catalyzed Intermolecular Carbenoid Functionalization of Aromatic C–H Bonds by α-Diazomalonates

(2012) Wai-Wing Chan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ru(II)-Catalyzed Amidation of 2-Arylpyridines with Isocyanates via C–H Activation

(2012) Krishnamoorthy Muralirajan et al.   ORGANIC LETTERS

Nickel- and Cobalt-Catalyzed Direct Alkylation of Azoles with N-Tosylhydrazones Bearing Unactivated Alkyl Groups

(2011) Tomoyuki Yao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylate-Assisted Transition-Metal-Catalyzed C−H Bond Functionalizations: Mechanism and Scope

(2011) Lutz Ackermann   CHEMICAL REVIEWS

Transition metal-catalyzed arylation of unactivated C(sp3)–H bonds

(2011) Olivier Baudoin   CHEMICAL SOCIETY REVIEWS

Towards mild metal-catalyzed C–H bond activation

(2011) Joanna Wencel-Delord et al.   CHEMICAL SOCIETY REVIEWS

Expedient Synthesis ofN-Acyl Anthranilamides and β-Enamine Amides by the Rh(III)-Catalyzed Amidation of Aryl and Vinyl C–H Bonds with Isocyanates

(2011) Kevin D. Hesp et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Nitroso-Diels-Alder Reaction and Its Application for the Synthesis of (−)-Peracetylated Conduramine A-1

(2009) Chandan Kumar Jana et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Indoles via Domino Reaction ofN-Aryl Amides and Ethyl Diazoacetate

(2008) Sun-Liang Cui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY