Synthesis of Tri‐ and Tetrasubstituted Alkenyl Boronates from Alkynes

Hydroboration and Diboration of Internal Alkynes under Iridium Catalysis

(2022) Huan Ding et al.   JOURNAL OF ORGANIC CHEMISTRY

Hexamethyldisilazane Lithium (LiHMDS)-Promoted Hydroboration of Alkynes and Alkenes with Pinacolborane

(2022) Jichao Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

anti ‐Selective Borylstannylation of Alkynes with ( o ‐Phenylenediaminato)borylstannanes by a Radical Mechanism

(2022) Kensuke Suzuki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

One-Metal/Two-Ligand for Dual Activation Tandem Catalysis: Photoinduced Cu-Catalyzed Anti-hydroboration of Alkynes

(2022) Javier Corpas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper‐Photocatalyzed Hydroboration of Alkynes and Alkenes

(2021) Mingbing Zhong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper‐Catalyzed Synthesis of Tetrasubstituted Alkenes via Regio‐ and anti ‐Selective Addition of Silylboronates to Internal Alkynes

(2021) Hirokazu Moniwa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed 1,1-Boroalkylation of Terminal Alkynes: Access to Alkenylboronates via a Three-Component Reaction

(2021) Ziyong Li et al.   ORGANIC LETTERS

Overview of Regioselective and Stereoselective Catalytic Hydroboration of Alkynes

(2021) Tarun Kanti Panda et al.   ADVANCED SYNTHESIS & CATALYSIS

Regio‐ and Stereoselective 1,2‐Carboboration of Ynamides with Aryldichloroboranes

(2021) Cai You et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C−Boron Enolates Enable Palladium Catalyzed Carboboration of Internal 1,3‐Enynes

(2021) Ziyong Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective trans ‐Hydrostannation of Boron‐Capped Alkynes

(2021) Romain Melot et al.   CHEMISTRY-A EUROPEAN JOURNAL

Photocatalyzed E → Z Contra‐thermodynamic Isomerization of Vinyl Boronates with Binaphthol

(2021) Thibaud Brégent et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tropylium-Promoted Hydroboration Reactions: Mechanistic Insights Via Experimental and Computational Studies

(2021) Nhan N. H. Ton et al.   JOURNAL OF ORGANIC CHEMISTRY

Photocatalyzed Radical Relayed Regio- and Stereoselective Trifluoromethylthiolation–Boration

(2021) Qiang Zhang et al.   ORGANIC LETTERS

Pincer Iron Hydride Complexes for Alkene Isomerization: Catalytic Approach to Trisubstituted (Z)-Alkenyl Boronates

(2021) Songgen Xu et al.   ACS Catalysis

Dynamic multiligand catalysis: A polar to radical crossover strategy expands alkyne carboboration to unactivated secondary alkyl halides

(2021) Shin-Ho Kim-Lee et al.   Chem

Copper‐Catalyzed Preparation of Alkenylboronates and Arylboronates

(2021) Safiul Alam et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Borylative Cyclization of 1,6-Allenynes Driven by BCl3

(2021) Chun-Hua Yang et al.   ORGANIC LETTERS

Cobalt-Catalyzed Hydroboration of Terminal and Internal Alkynes

(2021) María J. González et al.   ORGANIC LETTERS

Stereodivergent Access to Trisubstituted Alkenylboronate Esters through Alkene Isomerization

(2021) Lucas Segura et al.   ORGANIC LETTERS

Transmetalation as Key Step in the Diastereo- and Enantioselective Synergistic Cu/Pd-Catalyzed Allylboration of Alkynes with Racemic Allylic Carbonates

(2020) Jaime Mateos et al.   ORGANOMETALLICS

Modular Synthesis of Furans with up to Four Different Substituents by a trans‐Carboboration Strategy

(2020) Alois Fürstner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stereo‐ and Regioselective Cu‐Catalyzed Hydroboration of Alkynyl Chalcogenoethers

(2020) Isadora M. Oliveira et al.   ChemCatChem

Three-Component Borylallenylation of Alkynes: Access to Densely Boryl-Substituted Ene-allenes

(2020) Shang-Hai Yu et al.   ORGANIC LETTERS

Chemoselective Hydroboration of Propargylic Alcohols and Amines Using a Manganese(II) Catalyst

(2020) Aleksandra Brzozowska et al.   ORGANIC LETTERS

Pd‐Senphos Catalyzed trans ‐Selective Cyanoboration of 1,3‐Enynes

(2020) Yuanzhe Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ru-Catalyzed Geminal Hydroboration of Silyl Alkynes via a New gem-Addition Mechanism

(2020) Qiang Feng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed C–H Alkenylation of Benzoic Acid and Acrylic Acid Derivatives with Vinyl Boronates

(2020) Jian-Jun Li et al.   ORGANIC LETTERS

Cycloadditions of Alkenylboronic Derivatives

(2020) Oleksandr O. Grygorenko et al.   SYNTHESIS-STUTTGART

Reaction Pathways and Redox States in α‐Selective Cobalt‐Catalyzed Hydroborations of Alkynes

(2020) Clemens K. Blasius et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst Development in the Dehydrogenative Borylation of Alkenes for the Synthesis Vinylboronate Esters

(2020) Lipeng Wu et al.   SYNLETT

Copper-Catalyzed Borylative Difunctionalization of π-Systems

(2020) Andrew Whyte et al.   ACS Catalysis

Zwitterion‐Initiated Hydroboration of Alkynes and Styrene

(2020) Alessandro Bismuto et al.   ADVANCED SYNTHESIS & CATALYSIS

Direct Synthesis of Multi(boronate) Esters from Alkenes and Alkynes via Hydroboration and Boration Reactions

(2020) Xianjin Wang et al.   ACS Catalysis

Copper-Catalyzed Aminoboration from Hydrazones To Generate Borylated Pyrazoles

(2019) Kim N. Tu et al.   ORGANIC LETTERS

Carboboration of Alkynes with Cyclodextrin-Encapsulated N-Heterocyclic Carbene Copper Complexes

(2019) Zhonghang Wen et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis of Conjugated Boron‐Enynes via cis‐Alkynylboration of Terminal Alkynes

(2019) Kuan Li et al.   ADVANCED SYNTHESIS & CATALYSIS

Magnesium-Catalyzed Hydroboration of Terminal and Internal Alkynes

(2019) Marc Magre et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanism of Brønsted-Base-Mediated Borylation of Propynols: A DFT Study

(2019) Haohua Chen et al.   ORGANIC LETTERS

Regioselective trans-Carboboration of Propargyl Alcohols

(2019) Hongming Jin et al.   ORGANIC LETTERS

Pyridine‐Based Organocatalysts for Regioselective syn ‐1,2‐Silaboration of Terminal Alkynes and Allenes

(2019) Yohei Morimasa et al.   Asian Journal of Organic Chemistry

trans ‐Hydroboration of Propargyl Alcohol Derivatives and Related Substrates

(2019) Lauren E. Longobardi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Zinc Catalysed Hydroboration of Terminal and Internal Alkynes

(2019) Souvik Mandal et al.   Chemistry-An Asian Journal

Atom-Economical Ni-Catalyzed Diborylative Cyclization of Enynes: Preparation of Unsymmetrical Diboronates

(2019) Natalia Cabrera-Lobera et al.   ORGANIC LETTERS

Pd-Catalyzed Boroperfluoroalkylation of Alkynes Opens a Route to One-Pot Reductive Carboperfluoroalkylation of Alkynes with Perfluoroalkyl and Aryl Iodides

(2019) Sylwester Domański et al.   ORGANIC LETTERS

Ligand-Dependent-Controlled Copper-Catalyzed Regio- and Stereoselective Silaboration of Alkynes

(2019) Meng Zhao et al.   ORGANIC LETTERS

Aluminum-Catalyzed Selective Hydroboration of Alkenes and Alkynylsilanes

(2019) Feng Li et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Reactivity and Synthetic Applications of Multicomponent Petasis Reactions

(2019) Peng Wu et al.   CHEMICAL REVIEWS

Ni‐catalyzed Cyclization of Enynes and Alkynylboronates: Atom‐economical Synthesis of Boryl‐1,4‐dienes

(2019) Diego J. Cardenas et al.   CHEMISTRY-A EUROPEAN JOURNAL

trans-Hydroboration of Propiolamides: Access to Primary and Secondary (E)-β-Borylacrylamides

(2019) R. Justin Grams et al.   ORGANIC LETTERS

Cobalt-Catalyzed Cyclization/Hydroboration of 1,6-Diynes with Pinacolborane

(2019) Qiang Huang et al.   ORGANIC LETTERS

Regio‐ and Stereoselective Synthesis of Enynyl Boronates via Ruthenium‐Catalyzed Hydroboration of 1,4‐Diaryl‐Substituted 1,3‐Diynes

(2019) Tomasz Sokolnicki et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Enantioselective Allylboration of Alkynes: Synthesis of Highly Versatile Multifunctional Building Blocks

(2019) Eva Rivera-Chao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Regiodivergent Stereoselective Hydroboration of 1,3-Diynes To Access Boryl-Functionalized Enynes

(2019) Hui Leng Sang et al.   ACS Catalysis

Hydroboration of Alkenes and Alkynes Employing Earth‐Abundant Metal Catalysts

(2019) Arpita Singh et al.   Asian Journal of Organic Chemistry

Stereoselective Base-Catalyzed 1,1-Silaboration of Terminal Alkynes

(2019) Yiting Gu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Stereodefined Borylated Dendralenes through Copper-Catalyzed Allylboration of Alkynes

(2018) Eva Rivera-Chao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

In Situ Generation of Silylzinc by Si−B Bond Activation Enabling Silylzincation and Silaboration of Terminal Alkynes

(2018) Yuki Nagashima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Phosphine-Catalyzed anti -Carboboration of Alkynoates with 9-BBN-Based 1,1-Diborylalkanes: Synthesis and Use of Multisubstituted γ-Borylallylboranes

(2018) Ayaka Yamazaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Metal-Free Acetylene Coupling by the (C6 F5 )2 B−X 1,2-Halogenoboration Reaction

(2018) Atsushi Ueno et al.   CHEMISTRY-A EUROPEAN JOURNAL

Access to 1,1-Diborylalkenes and Concomitant Stereoselective Reactivity

(2018) Jordi Royes et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Transition Metal-Free Trans Hydroboration of Alkynoic Acid Derivatives: Experimental and Theoretical Studies

(2018) Russell Fritzemeier et al.   JOURNAL OF ORGANIC CHEMISTRY

Copper-Catalyzed Synthesis of Tetrasubstituted Enynylboronates via Chemo-, Regio-, and Stereoselective Borylalkynylation

(2018) Jung Tae Han et al.   ORGANIC LETTERS

Phosphine-Catalyzed Anti-Hydroboration of Internal Alkynes

(2018) Kazunori Nagao et al.   ORGANIC LETTERS

Boron Trichloride-Mediated Synthesis of Indoles via the Aminoboration of Alkynes

(2018) Jiahang Lv et al.   ADVANCED SYNTHESIS & CATALYSIS

A recyclable Ru(CO)Cl(H)(PPh3 )3 /PEG catalytic system for regio- and stereoselective hydroboration of terminal and internal alkynes

(2018) Jakub Szyling et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis

(2018) Jianhui Chen et al.   CHINESE JOURNAL OF CHEMISTRY

An Oxyboration Route to a Single Regioisomer of Borylated Dihydrofurans and Isochromenes

(2018) Kim N. Tu et al.   JOURNAL OF ORGANIC CHEMISTRY

trans-Hydroboration vs. 1,2-reduction: divergent reactivity of ynones and ynoates in Lewis-base-catalyzed reactions with pinacolborane

(2018) You Zi et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper(I)-Mediated Borofluorination of Alkynes

(2018) Abraham J. Jordan et al.   ORGANIC LETTERS

Synthesis of α-Borylated Ketones by Regioselective Wacker Oxidation of Alkenylboronates

(2018) Victoria B. Corless et al.   ORGANIC LETTERS

Base-Catalyzed Borylation/B–O Elimination of Propynols and B2pin2 Delivering Tetrasubstituted Alkenylboronates

(2018) Zhijie Kuang et al.   ORGANIC LETTERS

Palladium-Catalyzed anti-Selective Fluoroalkylboration of Internal and Terminal Alkynes

(2018) Shuaifeng Wang et al.   ORGANIC LETTERS

Copper-NHC-Mediated Semihydrogenation and Hydroboration of Alkynes: Enhanced Catalytic Activity Using Ring-Expanded Carbenes

(2018) Jonathan W. Hall et al.   ORGANOMETALLICS

Rationalizing the Role of NaOtBu in Copper-Catalyzed Carboboration of Alkynes: Assembly of Allylic All-Carbon Quaternary Stereocenters

(2018) Shin-Ho Kim-Lee et al.   ACS Catalysis

PdII -Catalyzed Enantioselective C(sp3 )−H Activation/Cross-Coupling Reactions of Free Carboxylic Acids

(2018) Liang Hu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkenylboronates: synthesis and applications

(2018) Pedro J. Pérez et al.   Chemistry-An Asian Journal

Switchable Synthetic Strategy toward Trisubstituted and Tetrasubstituted Exocyclic Alkenes

(2018) Sen Zhou et al.   ORGANIC LETTERS

Transition-Metal-Free Synthesis of Borylated Thiophenes via Formal Thioboration

(2018) Hassen Bel Abed et al.   ORGANIC LETTERS

Fluoroalkylation–Borylation of Alkynes: An Efficient Method To Obtain (Z)-Tri- and Tetrasubstituted Fluoroalkylated Alkenylboronates

(2018) Wen-Hao Guo et al.   ACS Catalysis

Gold-Nanoparticle-Catalyzed Mild Diboration and Indirect Silaboration of Alkynes without the Use of Silylboranes

(2017) Marios Kidonakis et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Transition Metal-Free trans-Selective Alkynylboration of Alkynes

(2017) Marina Nogami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Borylstannylation of Alkynes with Tin Fluorides

(2017) Hiroto Yoshida et al.   ORGANOMETALLICS

Borane-Catalysed Hydroboration of Alkynes and Alkenes

(2017) Stephen Thomas et al.   SYNTHESIS-STUTTGART

Hydroboration and Diboration of Internal Alkynes Catalyzed by a Well-Defined Low-Valent Cobalt Catalyst

(2017) Marc Petit et al.   SYNTHESIS-STUTTGART

A modular route to boron doped PAHs by combining borylative cyclisation and electrophilic C–H borylation

(2017) D. L. Crossley et al.   Chemical Science

Synergistic Copper/Palladium Catalysis for the Regio- and Stereoselective Synthesis of Borylated Skipped Dienes

(2017) Jaime Mateos et al.   ACS Catalysis

Cobalt-Catalyzed Ligand-Controlled Regioselective Hydroboration/Cyclization of 1,6-Enynes

(2017) Tuo Xi et al.   ACS Catalysis

A Combined DFT/IM-MS Study on the Reaction Mechanism of Cationic Ru(II)-Catalyzed Hydroboration of Alkynes

(2017) Li-Juan Song et al.   ACS Catalysis

Aluminum Hydride Catalyzed Hydroboration of Alkynes

(2016) Alessandro Bismuto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalyst-Free Formal Thioboration to Synthesize Borylated Benzothiophenes and Dihydrothiophenes

(2016) Darius J. Faizi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

BCl3 -Induced Annulative Oxo- and Thioboration for the Formation of C3-Borylated Benzofurans and Benzothiophenes

(2016) Andrew J. Warner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis acid catalysis: catalytic hydroboration of alkynes initiated by Piers' borane

(2016) Mirco Fleige et al.   CHEMICAL COMMUNICATIONS

Iron-Catalyzed Hydroboration: Unlocking Reactivity through Ligand Modulation

(2016) Maialen Espinal-Viguri et al.   CHEMISTRY-A EUROPEAN JOURNAL

The carboboration of Me3Si-substituted alkynes and allenes with boranes and borocations

(2016) James R. Lawson et al.   DALTON TRANSACTIONS

Borylative Cyclization Reactions

(2016) Elena Buñuel et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Catalyst-Free Synthesis of Borylated Lactones from Esters via Electrophilic Oxyboration

(2016) Darius J. Faizi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Enabled, Copper-Catalyzed Regio- and Stereoselective Synthesis of Trialkylsubstituted Alkenylboronates from Unactivated Internal Alkynes

(2016) Taisuke Itoh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective and Stereoselective trans-Hydroboration of 1,3-Enynes Catalyzed by 1,4-Azaborine-Based Phosphine–Pd Complex

(2016) Senmiao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silaborative Carbocyclizations of 1,7-Enynes. Diastereoselective Preparation of Chromane Derivatives

(2016) You-Cai Xiao et al.   ORGANIC LETTERS

Oxyboration with and without a Catalyst: Borylated Isoxazoles via B–O σ-Bond Addition

(2016) Kim N. Tu et al.   ORGANIC LETTERS

Efficient Modular Synthesis of Substituted Borazaronaphthalene

(2016) Fang-Dong Zhuang et al.   ORGANOMETALLICS

Chemo-, regio-, and stereoselective hydroboration of conjugated enyne alcohol/amine: facile synthesis of Z , Z -/ Z , E -1,3-dien-1/2-ylboronic ester bearing hydroxyl/amino group

(2016) Hua-Dong Xu et al.   TETRAHEDRON LETTERS

(N-Heterocyclic Carbene)2-Pd(0)-Catalyzed Silaboration of Internal and Terminal Alkynes: Scope and Mechanistic Studies

(2016) Melvyn B. Ansell et al.   ACS Catalysis

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Formation of C(sp2)Boronate Esters by Borylative Cyclization of Alkynes Using BCl3

(2015) Andrew J. Warner et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Relay and Cooperative Palladium(0)N-Heterocyclic Carbene/Copper(I)N-Heterocyclic Carbene Catalysis for the Synthesis of Tri- and Tetrasubstituted Alkenes

(2015) Mathieu Lesieur et al.   ChemCatChem

Borylstannylation of alkynes with inverse regioselectivity: copper-catalyzed three-component coupling using a masked diboron

(2015) H. Yoshida et al.   CHEMICAL COMMUNICATIONS

Iron-Catalyzed Diboration and Carboboration of Alkynes

(2015) Naohisa Nakagawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

1,1-Carboboration through Activation of Silicon-Carbon and Tin-Carbon Bonds

(2015) Bernd Wrackmeyer et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Catalytic stereoselective addition to alkynes. Borylation or silylation promoted by magnesia-supported iron oxide and cis-diboronation or silaboration by supported platinum nanoparticles

(2015) Anish Khan et al.   JOURNAL OF CATALYSIS

Aminoboration: Addition of B–N σ Bonds across C–C π Bonds

(2015) Eugene Chong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis

(2015) Kazunori Nagao et al.   ORGANIC LETTERS

Transition-Metal-Free Direct anti-Carboboration of Alkynes with Boronic Acids To Produce Alkenylheteroarenes

(2015) Silvia Roscales et al.   ORGANIC LETTERS

Silicon-Tethered Strategy for Copper(I)-Catalyzed Stereo- and Regioselective Alkylboration of Alkynes

(2015) Koji Kubota et al.   ORGANIC LETTERS

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

Substrate-Controlled Regio- and Stereoselective Synthesis of Boron-Substituted 1,4-Dienes via Copper-Catalyzed Boryl–Allylation of Alkynes with Allyl Phosphates and Bis(pinacolato)diboron

(2015) Huai-Yu Bin et al.   ACS Catalysis

Copper-Catalyzed β-Selective Hydroborylation of Ynamides: A Facile Access to (E)-β-Alkenylamide Boronates

(2015) Yihui Bai et al.   Asian Journal of Organic Chemistry

Copper-Catalyzed Monoborylation of Silylalkynes; Regio- and Stereoselective Synthesis of (Z)-β-(Borylvinyl)silanes

(2014) Yeong Mi Chae et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Cross-Coupling of Boronic Esters with Aryl Iodides and Application to the Carboboration of Alkynes and Allenes

(2014) Yiqing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-controlled divergent formation of alkenyl- or allylboronates catalyzed by Pd, and synthetic applications

(2014) Alicia Martos-Redruejo et al.   CHEMICAL COMMUNICATIONS

Synthesis of a guanidine NHC complex and its application in borylation reactions

(2014) Chia-Cheng Tai et al.   CHEMICAL COMMUNICATIONS

Synthesis of (Z)-1-Thio- and (Z)-2-Thio-1-alkenyl Boronates via Copper-Catalyzed Regiodivergent Hydroboration of Thioacetylenes: An Experimental and Theoretical Study

(2014) Gangguo Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

Alkoxyboration: Ring-Closing Addition of B–O σ Bonds across Alkynes

(2014) Joshua J. Hirner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphine-Catalyzed Anti-Carboboration of Alkynoates with Alkyl-, Alkenyl-, and Arylboranes

(2014) Kazunori Nagao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Studies on copper(i)-catalyzed highly regio- and stereo-selective hydroboration of alkynamides

(2014) Guangke He et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Nanogold-Catalyzed cis-Silaboration of Alkynes with Abnormal Regioselectivity

(2014) Charis Gryparis et al.   ORGANIC LETTERS

Carboxylic Acid-Catalyzed Highly Efficient and Selective Hydroboration of Alkynes with Pinacolborane

(2014) Hon Eong Ho et al.   ORGANIC LETTERS

Copper-Catalyzed Regioselective Formation of Tri- and Tetrasubstituted Vinylboronates in Air

(2014) Yannick D. Bidal et al.   ACS Catalysis

Control of Selectivity in Palladium-Catalyzed Oxidative Carbocyclization/Borylation of Allenynes

(2013) Youqian Deng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atrans-Selective Hydroboration of Internal Alkynes

(2013) Basker Sundararaju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Haloboration of Internal Alkynes with Boronium and Borenium Cations as a Route to Tetrasubstituted Alkenes

(2013) James R. Lawson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-free hydroboration of alkynes catalyzed by heterogeneous copper powder with high efficiency

(2013) Jie Zhao et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed Carboboration: Borylative Coupling of Alkynes with Alkenes through Activation of Boron–Chlorine Bonds

(2013) Kanayo Nakada et al.   CHEMISTRY LETTERS

Regioselective and Stereoselective Entry to β,β-Disubstituted Vinyl Ethers via the Sequential Hydroboration/Suzuki–Miyaura Coupling of Ynol Ethers

(2013) Weijian Cui et al.   JOURNAL OF ORGANIC CHEMISTRY

Cu-Catalyzed Asymmetric Borylative Cyclization of Cyclohexadienone-Containing 1,6-Enynes

(2013) Ping Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes

(2013) Hiroto Yoshida et al.   ORGANIC LETTERS

Synthesis and demethylation of 4,22-dimethoxy[2.10]metacyclophan-1-yne with BBr3 to afford a novel [10](2,9)-5a,11a-benzofuro-5a-bora-11-bromochromenophane

(2012) Yuki Uchikawa et al.   CANADIAN JOURNAL OF CHEMISTRY

Copper-Catalyzed Highly Regio- and Stereoselective Directed Hydroboration of Unsymmetrical Internal Alkynes: Controlling Regioselectivity by Choice of Catalytic Species

(2012) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Three-Component Borylstannylation of Alkynes

(2012) Yuki Takemoto et al.   CHEMISTRY-A EUROPEAN JOURNAL

Regiocontrolled CuI-Catalyzed Borylation of Propargylic-Functionalized Internal Alkynes

(2012) Abraham L. Moure et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates

(2012) Ricardo Alfaro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Boracarboxylation of Alkynes with Diborane and Carbon Dioxide by an N-Heterocyclic Carbene Copper Catalyst

(2012) Liang Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regioselective Catalytic Hydroboration of Propargylic Species Using Cu(I)-NHC Complexes

(2012) Jin Kyoon Park et al.   ORGANIC LETTERS

Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates

(2011) Yusuke Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly regio- and stereoselective synthesis of alkenylboronic esters by copper-catalyzed boron additions to disubstituted alkynes

(2011) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

One-Pot Carboboration of Alkynes Using Lithium Borylcyanocuprate and the Subsequent Suzuki-Miyaura Cross-Coupling of the Resulting Tetrasubstituted Alkenylborane

(2011) Yuri Okuno et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Regioselective Preparation of Functionalized exo-Methylene- cyclopentanes and exo-Methylenepyrrolidines via Silaborative Carbocyclization of 1,6-Enynes

(2010) Martin Gerdin et al.   ADVANCED SYNTHESIS & CATALYSIS

Borylcyanocuprate in a One-Pot Carboboration by a Sequential Reaction with an Electron-Deficient Alkyne and an Organic Carbon Electrophile

(2010) Yuri Okuno et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A borylative cyclisation towards indole boronic esters

(2010) Jianhui Huang et al.   CHEMICAL COMMUNICATIONS

Boronic Acids and Esters in the Petasis-Borono Mannich Multicomponent Reaction

(2010) Nuno R. Candeias et al.   CHEMICAL REVIEWS

Synthesis of 2-Boryl- and Silylindoles by Copper-Catalyzed Borylative and Silylative Cyclization of 2-Alkenylaryl Isocyanides

(2010) Mamoru Tobisu et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Cyclization of Functionalized 1,n-Diynes Mediated by [X−Y] Reagents [X−Y = R3Si−SnR′3or (R2N)2B−SnR′3]: Synthesis and Properties of Atropisomeric 1,3-Dienes

(2010) Ramakrishna Reddy Singidi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borostannylation of Alkynes and Enynes. Scope and Limitations of the Reaction and Utility of the Adducts

(2010) Ramakrishna Reddy Singidi et al.   ORGANIC LETTERS

Nickel-Catalyzed Borylative Coupling of Alkynes, Enones, and Bis(pinacolato)diboron as a Route to Substituted Alkenyl Boronates

(2009) Subramaniyan Mannathan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bis(imidazoline-2-thione)–copper(i) catalyzed regioselective boron addition to internal alkynes

(2009) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Synthesis of B-Protected β-Styrylboronic Acids via Iridium-Catalyzed Hydroboration of Alkynes with 1,8-Naphthalenediaminatoborane Leading to Iterative Synthesis of Oligo(phenylenevinylene)s

(2009) Noriyuki Iwadate et al.   ORGANIC LETTERS

Synthesis of Activated Alkenylboronates from Acetylenic Esters by CuH-Catalyzed 1,2-Addition/Transmetalation

(2008) Bruce H. Lipshutz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes

(2008) Toshimichi Ohmura et al.   CHEMICAL COMMUNICATIONS

Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents

(2008) Masaki Daini et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzedtrans- andcis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents:  Ligand-Dependent Complementary Stereoselectivity

(2008) Masaki Daini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rhodium-Catalyzed Borylative Cyclization of 2-Alkynylaryl Isocyanates with Bis(pinacolato)diboron

(2008) Tomoya Miura et al.   ORGANIC LETTERS