Recent Advances in Hydrometallation of Alkenes and Alkynes via the First Row Transition Metal Catalysis

Asymmetric Synthesis of Silicon-Stereogenic Vinylhydrosilanes by Cobalt-Catalyzed Regio- and Enantioselective Alkyne Hydrosilylation with Dihydrosilanes

(2018) Huanan Wen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

(NHC)NiH-Catalyzed Regiodivergent Cross-Hydroalkenylation of Vinyl Ethers with α-Olefins: Syntheses of 1,2- and 1,3-Disubstituted Allyl Ethers

(2018) Weihao Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

NiH-Catalyzed Reductive Relay Hydroalkylation: A Strategy for the Remote C(sp3 )−H Alkylation of Alkenes

(2018) Fang Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Diborylation of 1,1-disubstituted Vinylarenes: A Practical Route to Branched gem -Bis(boryl)alkanes

(2018) Wei Jie Teo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective Markovnikov Protoboration of α-Olefins Enabled by a Buttressed N-Heterocyclic Carbene Ligand

(2018) Yuan Cai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CuH-Catalyzed Asymmetric Hydroamidation of Vinylarenes

(2018) Yujing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Photocatalytic CO2 Reduction Using Earth-Abundant Metal Complexes-Derived Photocatalysts

(2018) Yanfei Zhao et al.   CHINESE JOURNAL OF CHEMISTRY

Asymmetric Transfer and Pressure Hydrogenation with Earth-Abundant Transition Metal Catalysts

(2018) Zhenfeng Zhang et al.   CHINESE JOURNAL OF CHEMISTRY

Enantioselective Ni–Al Bimetallic Catalyzed exo-Selective C–H Cyclization of Imidazoles with Alkenes

(2018) Yin-Xia Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Enantioselective Pyridone C–H Functionalizations Enabled by a Bulky N-Heterocyclic Carbene Ligand

(2018) Johannes Diesel et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Regioselective Olefin Isomerization Under Kinetic Control

(2018) Xufang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Highly Regioselective Hydrocyanation of Terminal Alkynes with Zn(CN)2 Using Water as the Hydrogen Source

(2018) Xingjie Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Nickel-Catalyzed Intramolecular Hydroalkenylation of N- and O-Tethered 1,6-Dienes To Form Six-Membered Heterocycles

(2018) Ke Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Highly Enantioselective Hydrosilylation of Unactivated Terminal Alkenes

(2018) Biao Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Trisubstituted Allenyl–B(pin) Compounds by Phosphine–Cu-Catalyzed 1,3-Enyne Hydroboration. Insights Regarding Stereochemical Integrity of Cu–Allenyl Intermediates

(2018) Youming Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-catalyzed asymmetric hydrogenation of enamides enabled by single-electron reduction

(2018) Max R. Friedfeld et al.   SCIENCE

Advances in chemoselective and/or stereoselective semihydrogenation of alkynes

(2018) K.C. Kumara Swamy et al.   TETRAHEDRON LETTERS

Cobalt-catalyzed regioselective stereoconvergent Markovnikov 1,2-hydrosilylation of conjugated dienes

(2018) Hui Leng Sang et al.   Chemical Science

Ligands with 1,10-phenanthroline scaffold for highly regioselective iron-catalyzed alkene hydrosilylation

(2018) Meng-Yang Hu et al.   Nature Communications

Highly Chemo- and Stereoselective Transfer Semihydrogenation of Alkynes Catalyzed by a Stable, Well-Defined Manganese(II) Complex

(2018) Aleksandra Brzozowska et al.   ACS Catalysis

10 gram-scale synthesis of a chiral oxazoline iminopyridine ligand and its applications

(2018) Jianhui Chen et al.   Organic Chemistry Frontiers

Cp2TiCl2-catalyzed highly regioselective hydroamination of styrenes with hydroxylamines

(2018) Xuewei Luo et al.   Organic Chemistry Frontiers

Asymmetric hydrofunctionalization of minimally functionalized alkenes via earth abundant transition metal catalysis

(2018) Jianhui Chen et al.   Organic Chemistry Frontiers

Earth-abundant transition metal catalysts for alkene hydrosilylation and hydroboration

(2018) Jennifer V. Obligacion et al.   Nature Reviews Chemistry

Base-free nickel-catalyzed hydroboration of simple alkenes with bis(pinacolato)diboron in an alcoholic solvent

(2017) Jiang-Fei Li et al.   GREEN CHEMISTRY

Enantioselective CuH-Catalyzed Hydroacylation Employing Unsaturated Carboxylic Acids as Aldehyde Surrogates

(2017) Yujing Zhou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of Copper-Catalyzed Asymmetric Hydroboration of Alkenes

(2017) Yumeng Xi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Divalent Silicon-Assisted Activation of Dihydrogen in a Bis(N-heterocyclic silylene)xanthene Nickel(0) Complex for Efficient Catalytic Hydrogenation of Olefins

(2017) Yuwen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Hydroboration of Unactivated 1,1-Disubstituted Alkenes

(2017) Won Jun Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand–Substrate Dispersion Facilitates the Copper-Catalyzed Hydroamination of Unactivated Olefins

(2017) Gang Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Cobalt-Catalyzed Hydrosilylation of Alkenes

(2017) Biao Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stable, Yet Highly Reactive Nonclassical Iron(II) Polyhydride Pincer Complexes: Z-Selective Dimerization and Hydroboration of Terminal Alkynes

(2017) Nikolaus Gorgas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Asymmetric Hydroboration/Cyclization of 1,6-Enynes with Pinacolborane

(2017) Songjie Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mild and Regioselective Benzylic C–H Functionalization: Ni-Catalyzed Reductive Arylation of Remote and Proximal Olefins

(2017) Yuli He et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles

(2017) Michael W. Gribble et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Hydrocarbonylative C–C Coupling of Terminal Alkynes with Alkyl Iodides

(2017) Li-Jie Cheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed 1,1-Diboration of Terminal Alkynes: Scope, Mechanism, and Synthetic Applications

(2017) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Asymmetric Sequential Hydroboration/Hydrogenation of Internal Alkynes

(2017) Jun Guo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mode of Activation of Cobalt(II) Amides for Catalytic Hydrosilylation of Alkenes with Tertiary Silanes

(2017) Yang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Anti-Markovnikov Hydroallylation of Terminal and Functionalized Internal Alkynes: Synthesis of Skipped Dienes and Trisubstituted Alkenes

(2017) Melrose Mailig et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective Catalytic Carboxylation of Unsaturated Hydrocarbons with CO2 and Water

(2017) Morgane Gaydou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Regio- and Enantioselective Copper-Catalyzed Reductive Hydroxymethylation of Styrenes and 1,3-Dienes with CO2

(2017) Yong-Yuan Gui et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Activation and discovery of earth-abundant metal catalysts using sodium tert-butoxide

(2017) Jamie H. Docherty et al.   Nature Chemistry

The mechanism and regioselectivities of (NHC)nickel(ii)hydride-catalyzed cycloisomerization of dienes: a computational study

(2017) Yuan Gao et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Asymmetric Hydroboration of 1,1-Disubstituted Alkenes

(2017) Zining Wang et al.   ORGANIC LETTERS

Hydroboration of Alkynes Catalyzed by Pyrrolide-Based PNP Pincer–Iron Complexes

(2017) Kazunari Nakajima et al.   ORGANIC LETTERS

Iron-Catalyzed, Markovnikov-Selective Hydroboration of Styrenes

(2017) Xu Chen et al.   ORGANIC LETTERS

Iron-Catalyzed Hydroboration of Vinylcyclopropanes

(2017) Chenhui Chen et al.   ORGANIC LETTERS

Copper-Mediated C–X Functionalization of Aryl Halides

(2017) P. J. Amal Joseph et al.   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Hydrosilylation of Olefins Catalyzed by Iron Complexes Bearing Ketimine-Type Iminobipyridine Ligands

(2017) Yuki Toya et al.   ORGANOMETALLICS

Copper(I)-catalyzed stereoselective hydrogenation of 1,3-diynes and enynes

(2017) Niklas O. Thiel et al.   TETRAHEDRON

Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes

(2017) Lei Li et al.   Nature Communications

Access to stereodefined (Z)-allylsilanes and (Z)-allylic alcohols via cobalt-catalyzed regioselective hydrosilylation of allenes

(2017) Chao Wang et al.   Nature Communications

Air-Stable α-Diimine Nickel Precatalysts for the Hydrogenation of Hindered, Unactivated Alkenes

(2017) Nadia G. Léonard et al.   ACS Catalysis

Stereoselective Synthesis of Trisubstituted Alkenes via Cobalt-Catalyzed Double Dehydrogenative Borylations of 1-Alkenes

(2017) Huanan Wen et al.   ACS Catalysis

Control of Selectivity through Synergy between Catalysts, Silanes, and Reaction Conditions in Cobalt-Catalyzed Hydrosilylation of Dienes and Terminal Alkenes

(2017) Balaram Raya et al.   ACS Catalysis

Copper-Catalyzed Hydroarylation of Internal Alkynes: Highly Regio- and Diastereoselective Synthesis of 1,1-Diaryl, Trisubstituted Olefins

(2017) Gregory D. Kortman et al.   ACS Catalysis

Cobalt-Catalyzed Ligand-Controlled Regioselective Hydroboration/Cyclization of 1,6-Enynes

(2017) Tuo Xi et al.   ACS Catalysis

Advances in Base-Metal-Catalyzed Alkene Hydrosilylation

(2017) Xiaoyong Du et al.   ACS Catalysis

Insights into a Chemoselective Cobalt Catalyst for the Hydroboration of Alkenes and Nitriles

(2017) Abdulrahman D. Ibrahim et al.   ACS Catalysis

Cp2TiCl2-catalyzed hydrocarboxylation of alkynes with CO2: formation of α,β-unsaturated carboxylic acids

(2017) Peng Shao et al.   RSC Advances

Identifying a cobalt catalyst for highly selective hydrosilylation of allenes

(2017) Zheng Yang et al.   Organic Chemistry Frontiers

Copper-catalyzed highly selective approach to 2-boroallylic silanes from allenylsilanes

(2017) Liu Song et al.   Organic Chemistry Frontiers

Pincer cobalt complex-catalyzed Z-selective hydrosilylation of terminal alkynes

(2017) Xiaoyong Du et al.   Organic Chemistry Frontiers

Amine-Activated Iron Catalysis: Air- and Moisture-Stable Alkene and Alkyne Hydrofunctionalization

(2016) Amy J. Challinor et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Selective Hydroboration of Alkenes, Ketones and Aldehydes Catalyzed by a Well-Defined Manganese Complex

(2016) Guoqi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regio- and Enantioselective Cobalt-Catalyzed Sequential Hydrosilylation/Hydrogenation of Terminal Alkynes

(2016) Jun Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity

(2016) Ziqing Zuo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Chemo-, Regio-, and Stereoselective Cobalt-Catalyzed Markovnikov Hydrosilylation of Alkynes

(2016) Jun Guo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Easily Accessed Nickel Nanoparticle Catalyst for Alkene Hydrosilylation with Tertiary Silanes

(2016) Ivan Buslov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Base-Metal-Catalyzed Regiodivergent Alkene Hydrosilylations

(2016) Xiaoyong Du et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Homoallylic Boronates by Chemo-, SN2′-, Diastereo- and Enantioselective Catalytic Sequence of Cu−H Addition to Vinyl-B(pin)/Allylic Substitution

(2016) Jaehee Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The cobalt(II) complex of a new tridentate Schiff-base ligand as a catalyst for hydrosilylation of olefins

(2016) Adam Gorczyński et al.   CATALYSIS COMMUNICATIONS

Highly selective Markovnikov hydroboration of alkyl-substituted terminal alkenes with a phosphine–copper(i) catalyst

(2016) Hiroaki Iwamoto et al.   CHEMICAL COMMUNICATIONS

Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

(2016) Steven W. M. Crossley et al.   CHEMICAL REVIEWS

Low-Pressure Cobalt-Catalyzed Enantioselective Hydrovinylation of Vinylarenes

(2016) Sohajl Movahhed et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Hydroboration: Unlocking Reactivity through Ligand Modulation

(2016) Maialen Espinal-Viguri et al.   CHEMISTRY-A EUROPEAN JOURNAL

Development of Cu-Catalyzed Asymmetric Addition of Boron to Olefin

(2016) Yuanyuan Liu et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Manganese organometallic compounds in homogeneous catalysis: Past, present, and prospects

(2016) Dmitry A. Valyaev et al.   COORDINATION CHEMISTRY REVIEWS

Transmetallation from CCC-NHC pincer Zr complexes in the synthesis of air-stable CCC-NHC pincer Co(iii) complexes and initial hydroboration trials

(2016) Sean W. Reilly et al.   DALTON TRANSACTIONS

Nickel-catalyzed hydrocarboxylation of alkynes with formic acid

(2016) Jing Hou et al.   GREEN CHEMISTRY

Cobalt-Catalyzed Hydrosilylation/Cyclization of 1,6-Enynes

(2016) Tuo Xi et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed Enantioselective Hydrogenation of Minimally Functionalized Alkenes: Isotopic Labeling Provides Insight into the Origin of Stereoselectivity and Alkene Insertion Preferences

(2016) Max R. Friedfeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective CuH-Catalyzed Reductive Coupling of Aryl Alkenes and Activated Carboxylic Acids

(2016) Jeffrey S. Bandar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Non-Precious-Metal Catalytic Systems Involving Iron or Cobalt Carboxylates and Alkyl Isocyanides for Hydrosilylation of Alkenes with Hydrosiloxanes

(2016) Daisuke Noda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Addition of Styrene-Derived Nucleophiles to Imines Enabled by Ligand-Controlled Chemoselective Hydrocupration

(2016) Yang Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diverse Asymmetric Hydrofunctionalization of Aliphatic Internal Alkenes through Catalytic Regioselective Hydroboration

(2016) Yumeng Xi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Cobalt-Catalyzed Transfer Hydrogenation of Alkynes: Stereodivergent Synthesis of Z- and E-Alkenes

(2016) Shaomin Fu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective CuH-Catalyzed Hydroallylation of Vinylarenes

(2016) Yi-Ming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Borylalkanes via Copper-Catalyzed Enantioselective Hydroallylation

(2016) Jung Tae Han et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cascade Copper-Catalyzed 1,2,3-Trifunctionalization of Terminal Allenes

(2016) Wanxiang Zhao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal–Organic Frameworks Stabilize Solution-Inaccessible Cobalt Catalysts for Highly Efficient Broad-Scope Organic Transformations

(2016) Teng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

para-Selective Alkylation of Benzamides and Aromatic Ketones by Cooperative Nickel/Aluminum Catalysis

(2016) Shogo Okumura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A direct approach to amines with remote stereocentres by enantioselective CuH-catalysed reductive relay hydroamination

(2016) Shaolin Zhu et al.   Nature Chemistry

Cobalt-Catalyzed Asymmetric Hydrogenation of 1,1-Diarylethenes

(2016) Jianhui Chen et al.   ORGANIC LETTERS

Regio- and Stereoselective Hydrosilylation of Unsymmetrical Alkynes Catalyzed by a Well-Defined, Low-Valent Cobalt Catalyst

(2016) Alejandro Rivera-Hernández et al.   ORGANIC LETTERS

Synthesis of Secondary and Tertiary Alkylboranes via Formal Hydroboration of Terminal and 1,1-Disubstituted Alkenes

(2016) Hilary A. Kerchner et al.   ORGANIC LETTERS

Cp2TiCl2-Catalyzed Regioselective Hydrocarboxylation of Alkenes with CO2

(2016) Peng Shao et al.   ORGANIC LETTERS

Copper-Catalyzed trans-Hydroboration of Terminal Aryl Alkynes: Stereodivergent Synthesis of Alkenylboron Compounds

(2016) Won Jun Jang et al.   ORGANIC LETTERS

Cobalt Phosphino-α-Iminopyridine-Catalyzed Hydrofunctionalization of Alkenes: Catalyst Development and Mechanistic Analysis

(2016) Wan-Yi Chu et al.   ORGANOMETALLICS

DFT Study of the Mechanisms of Iron-Catalyzed Regioselective Synthesis of α-Aryl Carboxylic Acids from Styrene Derivatives and CO2

(2016) Qinghua Ren et al.   ORGANOMETALLICS

Heteroleptic Nickel Complexes for the Markovnikov-Selective Hydroboration of Styrenes

(2016) Eric E. Touney et al.   ORGANOMETALLICS

Cobalt- and Iron-Catalyzed Isomerization–Hydroboration of Branched Alkenes: Terminal Hydroboration with Pinacolborane and 1,3,2-Diazaborolanes

(2016) Takahiko Ogawa et al.   ORGANOMETALLICS

Copper-catalyzed asymmetric addition of olefin-derived nucleophiles to ketones

(2016) Y. Yang et al.   SCIENCE

Catalytic reversible alkene-nitrile interconversion through controllable transfer hydrocyanation

(2016) X. Fang et al.   SCIENCE

Copper-Catalyzed Hydrofunctionalization of Alkynes

(2016) Gojko Lalic et al.   SYNLETT

Practical carbon–carbon bond formation from olefins through nickel-catalyzed reductive olefin hydrocarbonation

(2016) Xi Lu et al.   Nature Communications

Selective Cobalt-Catalyzed Reduction of Terminal Alkenes and Alkynes Using (EtO)2Si(Me)H as a Stoichiometric Reductant

(2016) Balaram Raya et al.   ACS Catalysis

Nickel-Catalyzed Regio- and Stereoselective Hydrocarboxylation of Alkynes with Formic Acid through Catalytic CO Recycling

(2016) Ming-Chen Fu et al.   ACS Catalysis

Bench-Stable, Substrate-Activated Cobalt Carboxylate Pre-Catalysts for Alkene Hydrosilylation with Tertiary Silanes

(2016) Christopher H. Schuster et al.   ACS Catalysis

A Highly Chemoselective Cobalt Catalyst for the Hydrosilylation of Alkenes using Tertiary Silanes and Hydrosiloxanes

(2016) Abdulrahman D. Ibrahim et al.   ACS Catalysis

Iron-Catalyzed Homogeneous Hydrogenation of Alkenes under Mild Conditions by a Stepwise, Bifunctional Mechanism

(2016) Ruibo Xu et al.   ACS Catalysis

Cobalt-Catalyzed Regiodivergent Hydrosilylation of Vinylarenes and Aliphatic Alkenes: Ligand- and Silane-Dependent Regioselectivities

(2016) Chao Wang et al.   ACS Catalysis

Alkene Hydrosilylation Using Tertiary Silanes with α-Diimine Nickel Catalysts. Redox-Active Ligands Promote a Distinct Mechanistic Pathway from Platinum Catalysts

(2016) Iraklis Pappas et al.   ACS Catalysis

Markovnikov-Selective, Activator-Free Iron-Catalyzed Vinylarene Hydroboration

(2016) Alistair J. MacNair et al.   ACS Catalysis

Dual-Stereocontrol Asymmetric Cobalt-Catalyzed Hydroboration of Sterically Hindered Styrenes

(2016) Heyi Zhang et al.   ACS Catalysis

Manganese-Catalyzed C–H Activation

(2016) Weiping Liu et al.   ACS Catalysis

Electrons, Photons, Protons and Earth-Abundant Metal Complexes for Molecular Catalysis of CO2 Reduction

(2016) Hiroyuki Takeda et al.   ACS Catalysis

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Synthesis of 1,1-diboronate esters by cobalt-catalyzed sequential hydroboration of terminal alkynes

(2016) Ziqing Zuo et al.   Organic Chemistry Frontiers

Knocking on Wood: Base Metal Complexes as Catalysts for Selective Oxidation of Lignin Models and Extracts

(2015) Susan K. Hanson et al.   ACCOUNTS OF CHEMICAL RESEARCH

Getting Down to Earth: The Renaissance of Catalysis with Abundant Metals

(2015) Paul Chirik et al.   ACCOUNTS OF CHEMICAL RESEARCH

Manganese Catalyzed C–H Halogenation

(2015) Wei Liu et al.   ACCOUNTS OF CHEMICAL RESEARCH

Hydrogenation and Dehydrogenation Iron Pincer Catalysts Capable of Metal–Ligand Cooperation by Aromatization/Dearomatization

(2015) Thomas Zell et al.   ACCOUNTS OF CHEMICAL RESEARCH

Copper-Catalyzed Aerobic Oxidations of Organic Molecules: Pathways for Two-Electron Oxidation with a Four-Electron Oxidant and a One-Electron Redox-Active Catalyst

(2015) Scott D. McCann et al.   ACCOUNTS OF CHEMICAL RESEARCH

Regiodivergent and Stereoselective Hydrosilylation of 1,3-Disubstituted Allenes

(2015) Zachary D. Miller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal Catalysis and Organocatalysis: Where Can Progress Be Expected?

(2015) Qi-Lin Zhou   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemoselective Alkene Hydrosilylation Catalyzed by Nickel Pincer Complexes

(2015) Ivan Buslov et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Regioselective, Asymmetric Formal Hydroamination of Unactivated Internal Alkenes

(2015) Yumeng Xi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Asymmetric Hydrosilylation of 1,1-Disubstituted Alkenes

(2015) Jianhui Chen et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper Hydride Catalyzed Hydroamination of Alkenes and Alkynes

(2015) Michael T. Pirnot et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Asymmetric Hydroalkenylation of Vinylarenes: Electronic Effects of Substrates and Chiral N-Heterocyclic Carbene Ligands

(2015) Chun-Yu Ho et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cp2TiCl2-catalyzed cis-hydroalumination of propargylic amines with Red-Al: stereoselective synthesis of Z-configured allylic amines

(2015) Renhong Sun et al.   CHEMICAL COMMUNICATIONS

Copper-catalyzed C–C bond-forming transformation of CO2 to alcohol oxidation level: selective synthesis of homoallylic alcohols from allenes, CO2, and hydrosilanes

(2015) Yosuke Tani et al.   CHEMICAL COMMUNICATIONS

Late Transition Metal-Catalyzed Hydroamination and Hydroamidation

(2015) Liangbin Huang et al.   CHEMICAL REVIEWS

Iron Catalysis in Organic Synthesis

(2015) Ingmar Bauer et al.   CHEMICAL REVIEWS

Enantioselective and Enantiospecific Transition-Metal-Catalyzed Cross-Coupling Reactions of Organometallic Reagents To Construct C–C Bonds

(2015) Alan H. Cherney et al.   CHEMICAL REVIEWS

Z-Selective Copper(I)-Catalyzed Alkyne Semihydrogenation with Tethered Cu-Alkoxide Complexes

(2015) Felix Pape et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Hydrogenation Reactions

(2015) Na Guo et al.   CHINESE JOURNAL OF ORGANIC CHEMISTRY

Visible-Light-Sensitive Photocatalysts: Nanocluster-Grafted Titanium Dioxide for Indoor Environmental Remediation

(2015) Masahiro Miyauchi et al.   Journal of Physical Chemistry Letters

Synthesis of 1,1,1-Tris(boronates) from Vinylarenes by Co-Catalyzed Dehydrogenative Borylations–Hydroboration

(2015) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanism of Copper-Catalyzed Hydroalkylation of Alkynes: An Unexpected Role of Dinuclear Copper Complexes

(2015) Alison M. Suess et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rapid, Regioconvergent, Solvent-Free Alkene Hydrosilylation with a Cobalt Catalyst

(2015) Chi Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies of Copper(I)-Catalyzed 1,3-Halogen Migration

(2015) Ryan Van Hoveln et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ni-Catalyzed Regioselective Hydrocarboxylation of Alkynes with CO2 by Using Simple Alcohols as Proton Sources

(2015) Xueqiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Silylation of Alkynes: A Traceless 2-Pyridylsulfonyl Controller Allows Access to Either Regioisomer on Demand

(2015) Alfonso García-Rubia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Hydroalkylation of Terminal Alkynes

(2015) Mycah R. Uehling et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Studies Lead to Dramatically Improved Reaction Conditions for the Cu-Catalyzed Asymmetric Hydroamination of Olefins

(2015) Jeffrey S. Bandar et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Tuning Nickel with Lewis Acidic Group 13 Metalloligands for Catalytic Olefin Hydrogenation

(2015) Ryan C. Cammarota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Carbo- and Heterocycles through a CuH-Catalyzed Hydroalkylation Approach

(2015) Yi-Ming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of α-Aminoboronic Acid Derivatives by Copper-Catalyzed Enantioselective Hydroamination

(2015) Daiki Nishikawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Design of Modified Amine Transfer Reagents Allows the Synthesis of α-Chiral Secondary Amines via CuH-Catalyzed Hydroamination

(2015) Dawen Niu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Diastereo- and Enantioselective CuH-Catalyzed Synthesis of 2,3-Disubstituted Indolines

(2015) Erhad Ascic et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt Catalyzed Z-Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity

(2015) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Conversion of alkanes to linear alkylsilanes using an iridium–iron-catalysed tandem dehydrogenation–isomerization–hydrosilylation

(2015) Xiangqing Jia et al.   Nature Chemistry

Copper(ii)-catalyzed highly regio- and stereo-selective hydrosilylation of unactivated internal alkynes with silylborate in water

(2015) Qing-Qing Xuan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Palladium-Catalyzed C-2 C–H Heteroarylation of Chiral Oxazolines: Diverse Synthesis of Chiral Oxazoline Ligands

(2015) Tuo Xi et al.   ORGANIC LETTERS

Highly Regio- and Stereoselective Synthesis of Boron-Substituted Enynes via Copper-Catalyzed Borylation of Conjugated Diynes

(2015) DingXi Li et al.   ORGANIC LETTERS

Copper(I)–Taniaphos Catalyzed Enantiodivergent Hydroboration of Bicyclic Alkenes

(2015) Hyesu Lee et al.   ORGANIC LETTERS

Alkene Isomerization–Hydroboration Promoted by Phosphine-Ligated Cobalt Catalysts

(2015) Margaret L. Scheuermann et al.   ORGANIC LETTERS

Combinatorial Approach to the Catalytic Hydrosilylation of Styrene Derivatives: Catalyst Systems Composed of Organoiron(0) or (II) Precursors and Isocyanides

(2015) Yusuke Sunada et al.   ORGANOMETALLICS

Origin of Regioselectivity in the Copper-Catalyzed Borylation Reactions of Internal Aryl Alkynes with Bis(pinacolato)diboron

(2015) Jong Hun Moon et al.   ORGANOMETALLICS

Catalytic Asymmetric Hydrosilylation of 1,1-Disubstituted Alkenes

(2015) Zhan Lu et al.   SYNLETT

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

Diastereoselective Ni-catalyzed 1,4-hydroboration of chiral dienols

(2015) Robert J. Ely et al.   TETRAHEDRON LETTERS

Cobalt Complex-Catalyzed Hydrosilylation of Alkenes and Alkynes

(2015) Jian Sun et al.   ACS Catalysis

Computational Exploration of Mechanism and Selectivities of (NHC)Nickel(II)hydride-Catalyzed Hydroalkenylations of Styrene with α-Olefins

(2015) Xin Hong et al.   ACS Catalysis

Recent advances in metal free- and late transition metal-catalysed hydroamination of unactivated alkenes

(2015) Elise Bernoud et al.   Catalysis Science & Technology

Titanium Dioxide Microsphere-Derived Materials for Solar Fuel Hydrogen Generation

(2015) Kai Yan et al.   ACS Sustainable Chemistry & Engineering

Highly efficient and practical hydrogenation of olefins catalyzed by in situ generated iron complex catalysts

(2015) Na Guo et al.   Organic Chemistry Frontiers

Triarylphosphine Ligands with Hemilabile Alkoxy Groups: Ligands for Nickel(II)-Catalyzed Olefin Dimerization Reactions. Hydrovinylation of Vinylarenes, 1,3-Dienes, and Cycloisomerization of 1,6-Dienes

(2014) Souvagya Biswas et al.   ADVANCED SYNTHESIS & CATALYSIS

Iron-Catalysed Chemo-, Regio-, and Stereoselective Hydrosilylation of Alkenes and Alkynes using a Bench-Stable Iron(II) Pre-Catalyst

(2014) Mark D. Greenhalgh et al.   ADVANCED SYNTHESIS & CATALYSIS

A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane

(2014) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Synthesis of α-Aminosilanes by Copper-Catalyzed Hydroamination of Vinylsilanes

(2014) Nootaree Niljianskul et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalysed Hydrofunctionalisation of Alkenes and Alkynes

(2014) Mark D. Greenhalgh et al.   ChemCatChem

[(NHC)Fe(CO)4] Efficient Pre-catalyst for Selective Hydroboration of Alkenes

(2014) Jianxia Zheng et al.   ChemCatChem

Copper(I)-Catalyzed Highly Regio- and Stereoselective Hydrosilylation of Terminal Alkynes with Boryldisiloxane

(2014) Hui Zhou et al.   ChemCatChem

A masked diboron in Cu-catalysed borylation reaction: highly regioselective formal hydroboration of alkynes for synthesis of branched alkenylborons

(2014) Hiroto Yoshida et al.   CHEMICAL COMMUNICATIONS

Copper-Catalyzed C–H Functionalization Reactions: Efficient Synthesis of Heterocycles

(2014) Xun-Xiang Guo et al.   CHEMICAL REVIEWS

Enantioselective Cobalt-Catalyzed Transformations

(2014) Hélène Pellissier et al.   CHEMICAL REVIEWS

Titanium Dioxide (Anatase and Rutile): Surface Chemistry, Liquid–Solid Interface Chemistry, and Scientific Synthesis of Supported Catalysts

(2014) Kyriakos Bourikas et al.   CHEMICAL REVIEWS

Titanium Dioxide Nanomaterials for Photovoltaic Applications

(2014) Yu Bai et al.   CHEMICAL REVIEWS

Nitrogen-Doped Titanium Dioxide as Visible-Light-Sensitive Photocatalyst: Designs, Developments, and Prospects

(2014) Ryoji Asahi et al.   CHEMICAL REVIEWS

Titanium Dioxide-Based Nanomaterials for Photocatalytic Fuel Generations

(2014) Yi Ma et al.   CHEMICAL REVIEWS

Titanium-Catalyzed Hydroalumination of Conjugated Dienes: Access to Fulvene-Derived Allylaluminium Reagents and Their Diastereoselective Reactions with Carbonyl Compounds

(2014) Jomy Joseph et al.   CHEMISTRY-A EUROPEAN JOURNAL

Cu(I)-NHC-Catalyzed Silylation of Allenes: Diastereoselective Three-Component Coupling with Aldehydes

(2014) James Rae et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper(I)-Catalyzed Regioselective Addition of Nucleophilic Silicon Across Terminal and Internal Carbon-Carbon Triple Bonds

(2014) Chinmoy K. Hazra et al.   Chemistry-An Asian Journal

Immobilization of Chiral Manganese(III)-salen Complexes for Enantioselective Epoxidation of Unfunctionalised Olefins

(2014) Zhi-Hao Shi et al.   CURRENT ORGANIC SYNTHESIS

Medium-Sized Heterocycle Synthesis by the Use of Synergistic Effects of Ni-NHC and γ-Coordination in Cycloisomerization

(2014) Chun-Yu Ho et al.   JOURNAL OF ORGANIC CHEMISTRY

Synthesis of (Z)-1-Thio- and (Z)-2-Thio-1-alkenyl Boronates via Copper-Catalyzed Regiodivergent Hydroboration of Thioacetylenes: An Experimental and Theoretical Study

(2014) Gangguo Zhu et al.   JOURNAL OF ORGANIC CHEMISTRY

Z-Selective Alkene Isomerization by High-Spin Cobalt(II) Complexes

(2014) Chi Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Enantioselective Hydroboration of 1,1-Disubstituted Aryl Alkenes

(2014) Lei Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Anti-Markovnikov Hydrobromination of Alkynes

(2014) Mycah R. Uehling et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis(imino)pyridine Cobalt-Catalyzed Dehydrogenative Silylation of Alkenes: Scope, Mechanism, and Origins of Selective Allylsilane Formation

(2014) Crisita Carmen Hojilla Atienza et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Stereoselective Hydrosilylation of Alkynes Catalyzed by Three-Coordinate Cobalt(I) Alkyl and Silyl Complexes

(2014) Zhenbo Mo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective CuH-Catalyzed Anti-Markovnikov Hydroamination of 1,1-Disubstituted Alkenes

(2014) Shaolin Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boryl–Metal Bonds Facilitate Cobalt/Nickel-Catalyzed Olefin Hydrogenation

(2014) Tzu-Pin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Enantioselective Intramolecular Hydroacylation of Ketones and Olefins

(2014) Junfeng Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Bis(phosphine)cobalt Dialkyl Complexes for Directed Catalytic Alkene Hydrogenation

(2014) Max R. Friedfeld et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Diastereo- and Enantioselective Desymmetrization of Cyclopropenes: Synthesis of Cyclopropylboronates

(2014) Alejandro Parra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Copper-catalysed selective hydroamination reactions of alkynes

(2014) Shi-Liang Shi et al.   Nature Chemistry

Iron-catalysed, general and operationally simple formal hydrogenation using Fe(OTf)3 and NaBH4

(2014) Alistair J. MacNair et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Catalytic Enantioselective Protoboration of Disubstituted Allenes. Access to Alkenylboron Compounds in High Enantiomeric Purity

(2014) Hwanjong Jang et al.   ORGANIC LETTERS

Copper-Catalyzed Enantioselective Formal Hydroamination of Oxa- and Azabicyclic Alkenes with Hydrosilanes and Hydroxylamines

(2014) Yuya Miki et al.   ORGANIC LETTERS

Broad Scope Hydrofunctionalization of Styrene Derivatives Using Iron-Catalyzed Hydromagnesiation

(2014) Alison S. Jones et al.   ORGANIC LETTERS

Iminopyridine Oxazoline Iron Catalyst for Asymmetric Hydroboration of 1,1-Disubtituted Aryl Alkenes

(2014) Jianhui Chen et al.   ORGANIC LETTERS

Synthesis and Hydrogenation Activity of Iron Dialkyl Complexes with Chiral Bidentate Phosphines

(2014) Jordan M. Hoyt et al.   ORGANOMETALLICS

Iron-Catalyzed Hydromagnesiation: Synthesis and Characterization of Benzylic Grignard Reagent Intermediate and Application in the Synthesis of Ibuprofen

(2014) Mark D. Greenhalgh et al.   ORGANOMETALLICS

Nitrate-Enhanced NHC-NiH Catalyzed Tail-to-Tail Vinyl Ether Dimerization

(2014) Chun-Yu Ho et al.   SYNLETT

Regulation of Iron-Catalyzed Olefin Hydroboration by Ligand Modifications at a Remote Site

(2014) Kuei-Nin T. Tseng et al.   ACS Catalysis

Copper-Catalyzed Regioselective Formation of Tri- and Tetrasubstituted Vinylboronates in Air

(2014) Yannick D. Bidal et al.   ACS Catalysis

High-Activity Cobalt Catalysts for Alkene Hydroboration with Electronically Responsive Terpyridine and α-Diimine Ligands

(2014) W. Neil Palmer et al.   ACS Catalysis

Selective synthesis of secondary benzylic (Z)-allylboronates by Fe-catalyzed 1,4-hydroboration of 1-aryl-substituted 1,3-dienes

(2014) Yanchun Cao et al.   Organic Chemistry Frontiers

Asymmetric cobalt catalysts for hydroboration of 1,1-disubstituted alkenes

(2014) Jianhui Chen et al.   Organic Chemistry Frontiers

Regio- and Enantioselective Monoborylation of Alkenylsilanes Catalyzed by an Electron-Donating Chiral Phosphine-Copper(I) Complex

(2013) Koji Kubota et al.   ADVANCED SYNTHESIS & CATALYSIS

Iron-Catalysed Reduction of Olefins using a Borohydride Reagent

(2013) Tom S. Carter et al.   ADVANCED SYNTHESIS & CATALYSIS

Regio- and Enantioselective Copper(I)-Catalyzed Hydroboration of Borylalkenes: Asymmetric Synthesis of 1,1-Diborylalkanes

(2013) Xinhui Feng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Intermolecular Regioselective Hydroamination of Styrenes with Polymethylhydrosiloxane and Hydroxylamines

(2013) Yuya Miki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane

(2013) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anchoring of Silyl Donors on a N-Heterocyclic Carbene through the Cobalt-Mediated Silylation of Benzylic CH Bonds

(2013) Zhenbo Mo et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-Metal-Catalyzed Laboratory-Scale Carbon-Carbon Bond-Forming Reactions of Ethylene

(2013) Vaneet Saini et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron Pincer Complex Catalyzed, Environmentally Benign,E-Selective Semi-Hydrogenation of Alkynes

(2013) Dipankar Srimani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chemo-, regio-, and stereoselective iron-catalysed hydroboration of alkenes and alkynes

(2013) Mark D. Greenhalgh et al.   CHEMICAL COMMUNICATIONS

Chemicals from Alkynes with Palladium Catalysts

(2013) Rafael Chinchilla et al.   CHEMICAL REVIEWS

Aerobic Copper-Catalyzed Organic Reactions

(2013) Scott E. Allen et al.   CHEMICAL REVIEWS

Chiral Iron Catalysts for Asymmetric Synthesis

(2013) Kovuru Gopalaiah   CHEMICAL REVIEWS

Highly Selective Copper-Catalyzed Hydroboration of Allenes and 1,3-Dienes

(2013) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

ExceptionallyE- and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes

(2013) Fanke Meng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Asymmetric Hydroamination: A Survey of the Most Recent Developments

(2013) Jérôme Hannedouche et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalyst design for iron-promoted reductions: an iron disilyl-dicarbonyl complex bearing weakly coordinating η2-(H–Si) moieties

(2013) Yusuke Sunada et al.   DALTON TRANSACTIONS

Bis(imino)pyridine Cobalt-Catalyzed Alkene Isomerization–Hydroboration: A Strategy for Remote Hydrofunctionalization with Terminal Selectivity

(2013) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Borylative exo-Cyclization of Alkenyl Halides Containing Unactivated Double Bond

(2013) Koji Kubota et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrocarbon-Soluble Nanocatalysts with No Bulk Phase: Coplanar, Two-Coordinate Arrays of the Base Metals

(2013) Jeffrey Camacho-Bunquin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantio- and Regioselective CuH-Catalyzed Hydroamination of Alkenes

(2013) Shaolin Zhu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Diaminophosphine Oxide Ligand Enabled Asymmetric Nickel-Catalyzed Hydrocarbamoylations of Alkenes

(2013) Pavel A. Donets et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation

(2013) Dongjie Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Hydrogenation Activity and Electronic Structure Determination of Bis(arylimidazol-2-ylidene)pyridine Cobalt Alkyl and Hydride Complexes

(2013) Renyuan Pony Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Understanding the Mechanisms of Cobalt-Catalyzed Hydrogenation and Dehydrogenation Reactions

(2013) Guoqi Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Boryl-Mediated Reversible H2 Activation at Cobalt: Catalytic Hydrogenation, Dehydrogenation, and Transfer Hydrogenation

(2013) Tzu-Pin Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Formal Regiocontrolled Hydroboration of Unbiased Internal Alkynes via Borylation/Allylic Alkylation of Terminal Alkynes

(2013) Abraham L. Moure et al.   ORGANIC LETTERS

NHC–Cu-Catalyzed Protoboration of Monosubstituted Allenes. Ligand-Controlled Site Selectivity, Application to Synthesis and Mechanism

(2013) Fanke Meng et al.   ORGANIC LETTERS

Highly Selective Bis(imino)pyridine Iron-Catalyzed Alkene Hydroboration

(2013) Jennifer V. Obligacion et al.   ORGANIC LETTERS

Monophasic Catalytic System for the Selective Semireduction of Alkynes

(2013) Aaron M Whittaker et al.   ORGANIC LETTERS

Heterolytic H2 Cleavage and Catalytic Hydrogenation by an Iron Metallaboratrane

(2013) Henry Fong et al.   ORGANOMETALLICS

Cobalt Precursors for High-Throughput Discovery of Base Metal Asymmetric Alkene Hydrogenation Catalysts

(2013) M. R. Friedfeld et al.   SCIENCE

Iron-Catalyzed Hydromagnesiation of Olefins

(2013) Stephen Thomas et al.   SYNLETT

Iron-Catalyzed Alkene Hydroboration with Pinacolborane

(2013) Zheng Huang et al.   SYNLETT

Rise of the Zinc Age in Homogeneous Catalysis?

(2013) Stephan Enthaler   ACS Catalysis

Iron-catalysed alkene hydrogenation and reductive cross-coupling using a bench-stable iron(ii) pre-catalyst

(2013) Dominik J. Frank et al.   RSC Advances

Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron

(2012) Weiming Yuan et al.   ADVANCED SYNTHESIS & CATALYSIS

Copper-Catalyzed Highly Selective Semihydrogenation of Non-Polar Carbon-Carbon Multiple Bonds using a Silane and an Alcohol

(2012) Kazuhiko Semba et al.   ADVANCED SYNTHESIS & CATALYSIS

Zinc-Catalyzed Organic Synthesis: CC, CN, CO Bond Formation Reactions

(2012) Xiao-Feng Wu et al.   ADVANCED SYNTHESIS & CATALYSIS

Mild and Homogeneous Cobalt-Catalyzed Hydrogenation of CC, CO, and CN Bonds

(2012) Guoqi Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkylation of Pyridone Derivatives By Nickel/Lewis Acid Catalysis

(2012) Ryuichi Tamura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aryl–aryl interactions as directing motifs in the stereodivergent iron-catalyzed hydrosilylation of internal alkynes

(2012) Christian Belger et al.   CHEMICAL COMMUNICATIONS

Are Alkyne Reductions Chemo-, Regio-, and Stereoselective Enough To Provide Pure (Z)-Olefins in Polyfunctionalized Bioactive Molecules?

(2012) Camille Oger et al.   CHEMICAL REVIEWS

Recent advances in copper-catalyzed dehydrogenative functionalization via a single electron transfer (SET) process

(2012) Chun Zhang et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Highly Regio- and Stereoselective Directed Hydroboration of Unsymmetrical Internal Alkynes: Controlling Regioselectivity by Choice of Catalytic Species

(2012) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Non-Redox-Metal-Catalyzed Redox Reactions: Zinc Catalysts

(2012) Xiao-Feng Wu   Chemistry-An Asian Journal

Straightforward Iron-Catalyzed Synthesis of Vinylboronates by the Hydroboration of Alkynes

(2012) Michael Haberberger et al.   Chemistry-An Asian Journal

Site- and Enantioselective Formation of Allene-Bearing Tertiary or Quaternary Carbon Stereogenic Centers through NHC–Cu-Catalyzed Allylic Substitution

(2012) Byunghyuck Jung et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regiocontrolled CuI-Catalyzed Borylation of Propargylic-Functionalized Internal Alkynes

(2012) Abraham L. Moure et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Hydrovinylation of 1-Vinylcycloalkenes. Reagent Control of Regio- and Stereoselectivity

(2012) Jordan P. Page et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed Chemo- and Stereoselective Hydromagnesiation of Diarylalkynes and Diynes

(2012) Laurean Ilies et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Recycling of Halogen Activating Groups via 1,3-Halogen Migration

(2012) R. David Grigg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantiopure C1-Symmetric Bis(imino)pyridine Cobalt Complexes for Asymmetric Alkene Hydrogenation

(2012) Sebastien Monfette et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed, Highly Regioselective Synthesis of α-Aryl Carboxylic Acids from Styrene Derivatives and CO2

(2012) Mark D. Greenhalgh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reversible H2 Addition across a Nickel–Borane Unit as a Promising Strategy for Catalysis

(2012) W. Hill Harman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CuCl–K2CO3-catalyzed highly selective borylcupration of internal alkynes – ligand effect

(2012) Weiming Yuan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Regioselective Catalytic Hydroboration of Propargylic Species Using Cu(I)-NHC Complexes

(2012) Jin Kyoon Park et al.   ORGANIC LETTERS

Copper-Catalyzed Double Borylation of Silylacetylenes: Highly Regio- and Stereoselective Synthesis of Syn-Vicinal Diboronates

(2012) Ho-Young Jung et al.   ORGANIC LETTERS

Synthesis, Electronic Structure, and Alkene Hydrosilylation Activity of Terpyridine and Bis(imino)pyridine Iron Dialkyl Complexes

(2012) Aaron M. Tondreau et al.   ORGANOMETALLICS

Catalytic Hydrosilylation of Alkenes by Iron Complexes Containing Terpyridine Derivatives as Ancillary Ligands

(2012) Kouji Kamata et al.   ORGANOMETALLICS

Iron Catalysts for Selective Anti-Markovnikov Alkene Hydrosilylation Using Tertiary Silanes

(2012) A. M. Tondreau et al.   SCIENCE

High-Activity Iron Catalysts for the Hydrogenation of Hindered, Unfunctionalized Alkenes

(2012) Renyuan Pony Yu et al.   ACS Catalysis

High-Selectivity Bis(imino)pyridine Iron Catalysts for the Hydrosilylation of 1,2,4-Trivinylcyclohexane

(2012) Crisita Carmen Hojilla Atienza et al.   ACS Catalysis

Rhodium Catalyzed Chelation-Assisted C–H Bond Functionalization Reactions

(2011) Denise A. Colby et al.   ACCOUNTS OF CHEMICAL RESEARCH

NHC-Cu-Catalyzed Enantioselective Hydroboration of Acyclic and Exocyclic 1,1-Disubstituted Aryl Alkenes

(2011) Rosa Corberán et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed 1,4-Hydrobutadienylation of 1-Aryl-1,3-dienes with 2,3-Dimethyl-1,3-butadiene

(2011) Martin A. Bohn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates

(2011) Yusuke Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Regio- and Stereoselective Three-Component Nickel-Catalyzed syn-Hydrocarboxylation of Alkynes with Diethyl Zinc and Carbon Dioxide

(2011) Suhua Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Aerobic Oxidative CH Functionalizations: Trends and Mechanistic Insights

(2011) Alison E. Wendlandt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly regio- and stereoselective synthesis of alkenylboronic esters by copper-catalyzed boron additions to disubstituted alkynes

(2011) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Homogeneous catalysis using iron complexes: recent developments in selective reductions

(2011) Kathrin Junge et al.   CHEMICAL COMMUNICATIONS

Shuffle off the classic β-Si elimination by Ni-NHC cooperation: implication for C–C forming reactions involving Ni-alkyl-β-silanes

(2011) Chun-Yu Ho et al.   CHEMICAL COMMUNICATIONS

Iron-catalysed, hydride-mediated reductive cross-coupling of vinyl halides and Grignard reagents

(2011) Bryden A. F. Le Bailly et al.   CHEMICAL COMMUNICATIONS

Advances in Transition Metal (Pd,Ni,Fe)-Catalyzed Cross-Coupling Reactions Using Alkyl-organometallics as Reaction Partners

(2011) Ranjan Jana et al.   CHEMICAL REVIEWS

Highly Enantioselective Synthesis of Tertiary Boronic Esters and their Stereospecific Conversion to other Functional Groups and Quaternary Stereocentres

(2011) Helen K. Scott et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Efficient Copper(I)-Catalyst System for the Asymmetric Hydroboration of β-Substituted Vinylarenes with Pinacolborane

(2011) Dongwan Noh et al.   Chemistry-An Asian Journal

Highly Selective Iron-Catalyzed Synthesis of Alkenes by the Reduction of Alkynes

(2011) Stephan Enthaler et al.   Chemistry-An Asian Journal

Recent advances and actual challenges in late transition metal catalyzed hydrosilylation of olefins from an industrial point of view

(2011) Dennis Troegel et al.   COORDINATION CHEMISTRY REVIEWS

Cationic Ethylzinc Compound: A Benzene Complex with Catalytic Activity in Hydroamination and Hydrosilylation Reactions

(2011) Rudolf J. Wehmschulte et al.   INORGANIC CHEMISTRY

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Highly Regioselective Silylcupration of Terminal Alkynes to Form α-Vinylsilanes

(2011) Peng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron–Copper Cooperative Catalysis in the Reactions of Alkyl Grignard Reagents: Exchange Reaction with Alkenes and Carbometalation of Alkynes

(2011) Eiji Shirakawa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective Dehydrogenative Silylation–Hydrogenation Reaction of Divinyldisiloxane with Hydrosilane Catalyzed by an Iron Complex

(2011) Roman N. Naumov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gaining Absolute Control of the Regiochemistry in the Cobalt-Catalyzed 1,4-Hydrovinylation Reaction

(2011) Marion Arndt et al.   ORGANIC LETTERS

A Simple, Multidimensional Approach to High-Throughput Discovery of Catalytic Reactions

(2011) D. W. Robbins et al.   SCIENCE

Iron-catalysed reduction of carbonyls and olefins

(2011) Bryden A. F. Le Bailly et al.   RSC Advances

Copper-Catalyzed SiB Bond Activation in Branched-Selective Allylic Substitution of Linear Allylic Chlorides

(2010) Devendra J. Vyas et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Intermolecular Tail-to-Tail Hydroalkenylation of Styrenes with α Olefins: Regioselective Migratory Insertion Controlled by a Nickel/N-Heterocyclic Carbene

(2010) Chun-Yu Ho et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Hydrocarboxylation of Alkynes Using Carbon Dioxide and Hydrosilanes

(2010) Tetsuaki Fujihara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct C−H Transformation via Iron Catalysis

(2010) Chang-Liang Sun et al.   CHEMICAL REVIEWS

Synthesis of 2-Boryl- and Silylindoles by Copper-Catalyzed Borylative and Silylative Cyclization of 2-Alkenylaryl Isocyanides

(2010) Mamoru Tobisu et al.   JOURNAL OF ORGANIC CHEMISTRY

Reactivity and Selectivity in Hydrovinylation of Strained Alkenes

(2010) Wang Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed 1,4-Hydrovinylation of Allylsilane and Allylboronic Esters for the Synthesis of Hydroxy-Functionalized 1,4-Dienes

(2010) Marion Arndt et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Conjugate Silyl Additions to Cyclic and Acyclic Unsaturated Carbonyls Catalyzed by Cu Complexes of Chiral N-Heterocyclic Carbenes

(2010) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

α-Selective Ni-Catalyzed Hydroalumination of Aryl- and Alkyl-Substituted Terminal Alkynes: Practical Syntheses of Internal Vinyl Aluminums, Halides, or Boronates

(2010) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Hydrovinylation of Unactivated Linear 1,3-Dienes

(2010) Rakesh K. Sharma et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Stereoselective Ni-Catalyzed 1,4-Hydroboration of 1,3-Dienes: Access to Stereodefined (Z)-Allylboron Reagents and Derived Allylic Alcohols

(2010) Robert J. Ely et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Strategy for the Synthesis of Well-Defined Iron Catalysts and Application to Regioselective Diene Hydrosilylation

(2010) Jessica Y. Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Asymmetric Monoborylation of 1,3-Dienes: Synthesis of Enantioenriched Cyclic Homoallyl- and Allylboronates

(2010) Yusuke Sasaki et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Hydrosilylation/Cyclization of Difluoro-Substituted 1,6-Enynes

(2010) Manabu Takachi et al.   ORGANIC LETTERS

Green Chemistry: Cresting a Summit toward Sustainability

(2010) John L. Tucker   ORGANIC PROCESS RESEARCH & DEVELOPMENT

Highly Selective Cobalt-Catalyzed Hydrovinylation of Styrene

(2009) Michiel M. P. Grutters et al.   ADVANCED SYNTHESIS & CATALYSIS

Room Temperature Highly Enantioselective Nickel-Catalyzed Hydrovinylation

(2009) Nicolas Lassauque et al.   ADVANCED SYNTHESIS & CATALYSIS

Highly Regio- and Enantioselective Copper-Catalyzed Hydroboration of Styrenes

(2009) Dongwan Noh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-catalysed hydrovinylation as the key step in a short synthesis of moenocinol

(2009) Gerhard Hilt et al.   CHEMICAL COMMUNICATIONS

Bis(imidazoline-2-thione)–copper(i) catalyzed regioselective boron addition to internal alkynes

(2009) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Chemistry of Organomanganese(II) Compounds

(2009) Gérard Cahiez et al.   CHEMICAL REVIEWS

Recent advances in enantioselective copper-catalyzed 1,4-addition

(2009) Thomas Jerphagnon et al.   CHEMICAL SOCIETY REVIEWS

Catalytic Asymmetric Synthesis Using Feedstocks: An Enantioselective Route to 2-Arylpropionic Acids and 1-Arylethyl Amines via Hydrovinylation of Vinyl Arenes

(2009) Craig R. Smith et al.   JOURNAL OF ORGANIC CHEMISTRY

Efficient Boron−Copper Additions to Aryl-Substituted Alkenes Promoted by NHC−Based Catalysts. Enantioselective Cu-Catalyzed Hydroboration Reactions

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Iron-Catalyzed 1,4-Hydroboration of 1,3-Dienes

(2009) Jessica Y. Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Vicinal Diboronates in High Enantiomeric Purity through Tandem Site-Selective NHC−Cu-Catalyzed Boron−Copper Additions to Terminal Alkynes

(2009) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct Alkenylation and Alkylation of Pyridone Derivatives by Ni/AlMe3Catalysis

(2009) Yoshiaki Nakao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A new iron age

(2009) Carsten Bolm   Nature Chemistry

Cobalt-Catalyzed 1,4-Hydrovinylation of Styrenes and 1-Aryl-1,3-butadienes

(2009) Gerhard Hilt et al.   ORGANIC LETTERS

In Pursuit of an Ideal Carbon-Carbon Bond-Forming Reaction: Development and Applications of the Hydrovinylation of Olefins

(2009) T. RajanBabu   SYNLETT

Nickel‐Catalyzed Highly Selective Hydrovinylation of α‐Ketals of Vinylarenes

(2008) Qi Zhang et al.   ADVANCED SYNTHESIS & CATALYSIS

Stereoselective Nickel-Catalyzed Cycloisomerization of 1,6-Dienes

(2008) Christian Böing et al.   ADVANCED SYNTHESIS & CATALYSIS

Sustainable Metal Catalysis with Iron: From Rust to a Rising Star?

(2008) Stephan Enthaler et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

CuH-Catalyzed Reactions

(2008) Carl Deutsch et al.   CHEMICAL REVIEWS

Copper-Catalyzed Diels−Alder Reactions

(2008) Sébastien Reymond et al.   CHEMICAL REVIEWS

Hydroamination: Direct Addition of Amines to Alkenes and Alkynes

(2008) Thomas E. Müller et al.   CHEMICAL REVIEWS

Iron-catalysed carbon–heteroatom and heteroatom–heteroatom bond forming processes

(2008) Arkaitz Correa et al.   CHEMICAL SOCIETY REVIEWS

Suzuki–Miyaura Cross-Coupling Reactions of Alkylboronic Acid Derivatives or Alkyltrifluoroborates with Aryl, Alkenyl or Alkyl Halides and Triflates

(2008) Henri Doucet   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Reductive Carboxylation of Styrenes Using CO2

(2008) Catherine M. Williams et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic Annulation of Heterocycles via a Novel Redox Process Involving the Imidazolium Salt N-Heterocyclic Carbene Couple

(2008) Adrien T. Normand et al.   ORGANOMETALLICS

Functional Group Tolerance and Substrate Scope in Bis(imino)pyridine Iron Catalyzed Alkene Hydrogenation

(2008) Ryan J. Trovitch et al.   ORGANOMETALLICS