C−Boron Enolates Enable Palladium Catalyzed Carboboration of Internal 1,3‐Enynes

Synthesis and odour evaluation of double‐bond isomers of DAMASCENOLIDE, 4‐(4‐methylpent‐3‐en‐1‐yl)‐2(5 H )‐furanone, which has a citrus‐like odour

(2020) Yamato Miyazawa et al.   FLAVOUR AND FRAGRANCE JOURNAL

Highly Chemoselective Hydroboration of Alkynes and Nitriles Catalyzed by Group 4 Metal Amidophosphine–Borane Complexes

(2020) Jayeeta Bhattacharjee et al.   ACS Omega

Pd‐Senphos Catalyzed trans ‐Selective Cyanoboration of 1,3‐Enynes

(2020) Yuanzhe Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Stereodefined 1,1-Diborylalkenes via Copper-Catalyzed Diboration of Terminal Alkynes

(2020) Yang Gao et al.   ORGANIC LETTERS

Streamlined Catalytic Enantioselective Synthesis of α-Substituted β,γ-Unsaturated Ketones and Either of the Corresponding Tertiary Homoallylic Alcohol Diastereomers

(2020) Juan del Pozo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Cyanoborylation of Allenes by N-Heterocyclic Carbene-Copper Catalysts

(2020) Zhenghua Li et al.   ACS Catalysis

Copper-Catalyzed Borylative Difunctionalization of π-Systems

(2020) Andrew Whyte et al.   ACS Catalysis

Selective Dehydrogenative Mono- or Diborylation of Styrenes by Supported Copper Catalysts

(2019) Daichi Yoshii et al.   ACS Catalysis

Divergent Protosilylation and Protoborylation of Polar Enynes

(2019) Fei-Fan Meng et al.   ORGANIC LETTERS

Alkynylboration Reaction Leading to Boron-Containing π-Extended cis-Stilbenes as a Highly Tunable Fluorophore

(2019) Marina Nogami et al.   ORGANIC LETTERS

Silver-Catalyzed anti-Markovnikov Hydroboration of C–C Multiple Bonds

(2019) Yan Wang et al.   ORGANIC LETTERS

Insights into the chemistry and therapeutic potential of furanones: A versatile pharmacophore

(2019) Asif Husain et al.   EUROPEAN JOURNAL OF MEDICINAL CHEMISTRY

Atom-Economical Ni-Catalyzed Diborylative Cyclization of Enynes: Preparation of Unsymmetrical Diboronates

(2019) Natalia Cabrera-Lobera et al.   ORGANIC LETTERS

trans-Hydroboration of Propiolamides: Access to Primary and Secondary (E)-β-Borylacrylamides

(2019) R. Justin Grams et al.   ORGANIC LETTERS

Copper-Catalyzed Triboration of Terminal Alkynes Using B2 pin2 : Efficient Synthesis of 1,1,2-Triborylalkenes

(2019) Xiaocui Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Enantioselective Allylboration of Alkynes: Synthesis of Highly Versatile Multifunctional Building Blocks

(2019) Eva Rivera-Chao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Stereodefined Borylated Dendralenes through Copper-Catalyzed Allylboration of Alkynes

(2018) Eva Rivera-Chao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to 1,1-Diborylalkenes and Concomitant Stereoselective Reactivity

(2018) Jordi Royes et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Synthesis and Applications of Unquaternized C-Bound Boron Enolates

(2018) Elvis Wang Hei Ng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Electrophilic Borylation of Terminal Alkenes with BBr3/2,6-Disubstituted Pyridines

(2018) Shinya Tanaka et al.   ORGANIC LETTERS

Copper-boryl mediated organic synthesis

(2018) David Hemming et al.   CHEMICAL SOCIETY REVIEWS

Base-Catalyzed Borylation/B–O Elimination of Propynols and B2pin2 Delivering Tetrasubstituted Alkenylboronates

(2018) Zhijie Kuang et al.   ORGANIC LETTERS

Vinylidenation of Organoboronic Esters Enabled by a Pd-Catalyzed Metallate Shift

(2018) Mark D. Aparece et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Alkenylboronates: synthesis and applications

(2018) Pedro J. Pérez et al.   Chemistry-An Asian Journal

Carbopalladation of C–C σ-bonds enabled by strained boronate complexes

(2018) Alexander Fawcett et al.   Nature Chemistry

Direct Synthesis of Alkenylboronates from Alkenes and Pinacol Diboron via Copper Catalysis

(2018) Wenkui Lu et al.   ORGANIC LETTERS

Fluoroalkylation–Borylation of Alkynes: An Efficient Method To Obtain (Z)-Tri- and Tetrasubstituted Fluoroalkylated Alkenylboronates

(2018) Wen-Hao Guo et al.   ACS Catalysis

Total Synthesis of Isohericerin, Isohericenone, and Erinacerin A: Development of a Copper-Catalyzed Methylboronation of Terminal Alkynes

(2017) Bohyun Mun et al.   JOURNAL OF ORGANIC CHEMISTRY

Transition Metal-Free trans-Selective Alkynylboration of Alkynes

(2017) Marina Nogami et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Acyl Fluorides as Efficient Electrophiles for the Copper-Catalyzed Boroacylation of Allenes

(2017) Arnaud Boreux et al.   ACS Catalysis

Synergistic Copper/Palladium Catalysis for the Regio- and Stereoselective Synthesis of Borylated Skipped Dienes

(2017) Jaime Mateos et al.   ACS Catalysis

Stereoselective Synthesis of Trisubstituted Alkenes via Cobalt-Catalyzed Double Dehydrogenative Borylations of 1-Alkenes

(2017) Huanan Wen et al.   ACS Catalysis

Direct Synthesis of Alkenyl Boronic Esters from Unfunctionalized Alkenes: A Boryl-Heck Reaction

(2016) William B. Reid et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Enabled, Copper-Catalyzed Regio- and Stereoselective Synthesis of Trialkylsubstituted Alkenylboronates from Unactivated Internal Alkynes

(2016) Taisuke Itoh et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Site-Selective and Stereoselective trans-Hydroboration of 1,3-Enynes Catalyzed by 1,4-Azaborine-Based Phosphine–Pd Complex

(2016) Senmiao Xu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Hydroborylation of Alkynes: A Ligand Controlled Regioselectivity Switch for the Synthesis of α- or β-Vinylboronates

(2016) Devi Prasan Ojha et al.   ORGANIC LETTERS

Ligand-Controlled Regiodivergent Copper-Catalyzed Alkylboration of Unactivated Terminal Alkynes

(2016) Wei Su et al.   ACS Catalysis

Iron-Catalyzed E-Selective Dehydrogenative Borylation of Vinylarenes with Pinacolborane

(2016) Chao Wang et al.   ACS Catalysis

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Catalytic Borylative Opening of Propargyl Cyclopropane, Epoxide, Aziridine, and Oxetane Substrates: Ligand Controlled Synthesis of Allenyl Boronates and Alkenyl Diboronates

(2015) Jian Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis

(2015) Kazunori Nagao et al.   ORGANIC LETTERS

Transition-Metal-Free Direct anti-Carboboration of Alkynes with Boronic Acids To Produce Alkenylheteroarenes

(2015) Silvia Roscales et al.   ORGANIC LETTERS

Substrate-Controlled Regio- and Stereoselective Synthesis of Boron-Substituted 1,4-Dienes via Copper-Catalyzed Boryl–Allylation of Alkynes with Allyl Phosphates and Bis(pinacolato)diboron

(2015) Huai-Yu Bin et al.   ACS Catalysis

Monobenzofused 1,4-Azaborines: Synthesis, Characterization, and Discovery of a Unique Coordination Mode

(2014) Senmiao Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Cross-Coupling of Boronic Esters with Aryl Iodides and Application to the Carboboration of Alkynes and Allenes

(2014) Yiqing Zhou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

α-Borylcarbonyl compounds: from transient intermediates to robust building blocks

(2014) Zhi He et al.   DALTON TRANSACTIONS

Copper-Catalyzed Three-Component Carboboration of Alkynes and Alkenes

(2013) Hiroto Yoshida et al.   ORGANIC LETTERS

Copper(I)-Catalyzed Formal Carboboration of Alkynes: Synthesis of Tri- and Tetrasubstituted Vinylboronates

(2012) Ricardo Alfaro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Catalytic, Direct Synthesis of Bis(boronate) Compounds

(2012) Jun Takaya et al.   ACS Catalysis

Stereoselective Synthesis of Tetrasubstituted Alkenylboronates via 1,1-Organodiboronates

(2010) Kohei Endo et al.   JOURNAL OF ORGANIC CHEMISTRY

Nickel-Catalyzed Borylative Coupling of Alkynes, Enones, and Bis(pinacolato)diboron as a Route to Substituted Alkenyl Boronates

(2009) Subramaniyan Mannathan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Universal Solvation Model Based on Solute Electron Density and on a Continuum Model of the Solvent Defined by the Bulk Dielectric Constant and Atomic Surface Tensions

(2009) Aleksandr V. Marenich et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Biaryl Phosphane Ligands in Palladium-Catalyzed Amination

(2008) David S. Surry et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-catalyzed carboboration of alkynes using chloroborane and organozirconium reagents

(2008) Masaki Daini et al.   CHEMICAL COMMUNICATIONS

Palladium-Catalyzedtrans- andcis-Carboboration of Alkynes Tethered to Chloroborane with Organozirconium Reagents:  Ligand-Dependent Complementary Stereoselectivity

(2008) Masaki Daini et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Long-range corrected hybrid density functionals with damped atom–atom dispersion corrections

(2008) Jeng-Da Chai et al.   PHYSICAL CHEMISTRY CHEMICAL PHYSICS