In Situ Generation of Silylzinc by Si−B Bond Activation Enabling Silylzincation and Silaboration of Terminal Alkynes

Isolation of 1,2,4,3-Triazaborol-3-yl-metal (Li, Mg, Al, Au, Zn, Sb, Bi) Derivatives and Reactivity toward CO and Isonitriles

(2016) Wei Lu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereodivergent Silylzincation of α-Heteroatom-Substituted Alkynes

(2016) Carolin Fopp et al.   ORGANIC LETTERS

(N-Heterocyclic Carbene)2-Pd(0)-Catalyzed Silaboration of Internal and Terminal Alkynes: Scope and Mechanistic Studies

(2016) Melvyn B. Ansell et al.   ACS Catalysis

Catalytic Borylation using an Air-Stable Zinc Boryl Reagent: Systematic Access to Elusive Acylboranes

(2015) Jesús Campos et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Inverse regioselectivity in the silylstannylation of alkynes and allenes: copper-catalyzed three-component coupling with a silylborane and a tin alkoxide

(2015) H. Yoshida et al.   CHEMICAL COMMUNICATIONS

Stannyl-Lithium: A Facile and Efficient Synthesis Facilitating Further Applications

(2015) Dong-Yu Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nanogold-Catalyzed cis-Silaboration of Alkynes with Abnormal Regioselectivity

(2014) Charis Gryparis et al.   ORGANIC LETTERS

Recent advances in transition-metal-catalyzed intermolecular carbomagnesiation and carbozincation

(2013) Kei Murakami et al.   Beilstein Journal of Organic Chemistry

Bimetallic Combinations for Dehalogenative Metalation Involving Organic Compounds

(2013) David Tilly et al.   CHEMICAL REVIEWS

ExceptionallyE- and β-Selective NHC-Cu-Catalyzed Proto-Silyl Additions to Terminal Alkynes and Site- and Enantioselective Proto-Boryl Additions to the Resulting Vinylsilanes: Synthesis of Enantiomerically Enriched Vicinal and Geminal Borosilanes

(2013) Fanke Meng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Design, Generation, and Synthetic Application of Borylzincate: Borylation of Aryl Halides and Borylzincation of Benzynes/Terminal Alkyne

(2013) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Silacarboxylation of Internal Alkynes by Employing Carbon Dioxide and Silylboranes

(2012) Tetsuaki Fujihara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Trivalent boron nucleophile as a new tool in organic synthesis: reactivity and asymmetric induction

(2012) Jessica Cid et al.   CHEMICAL SOCIETY REVIEWS

Copper-Catalyzed Highly Regioselective Silylcupration of Terminal Alkynes to Form α-Vinylsilanes

(2011) Peng Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Structural Basis for Regioisomerization in the Alkali-Metal-Mediated Zincation (AMMZn) of Trifluoromethyl Benzene by Isolation of Kinetic and Thermodynamic Intermediates

(2010) David R. Armstrong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Closer Insight into the Reactivity of TMP−Dialkyl Zincates in Directed ortho-Zincation of Anisole: Experimental Evidence of Amido Basicity and Structural Elucidation of Key Reaction Intermediates

(2009) William Clegg et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Syntheses, Structures, and Reactivities of Borylcopper and -zinc Compounds: 1,4-Silaboration of an α,β-Unsaturated Ketone to Form a γ-Siloxyallylborane

(2008) Takashi Kajiwara et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silylboranes Bearing Dialkylamino Groups on Silicon as Silylene Equivalents:  Palladium-Catalyzed Regioselective Synthesis of 2,4-Disubstituted Siloles

(2008) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Organozinc Reagents in DMSO Solvent: Remarkable Promotion of SN2′ Reaction for Allene Synthesis

(2008) Koji Kobayashi et al.   ORGANIC LETTERS

LiCl-Mediated Preparation of Highly Functionalized Benzylic Zinc Chlorides

(2008) Albrecht Metzger et al.   ORGANIC LETTERS