Pincer Iron Hydride Complexes for Alkene Isomerization: Catalytic Approach to Trisubstituted (Z)-Alkenyl Boronates

Highly Z-Selective Double Bond Transposition in Simple Alkenes and Allylarenes through a Spin-Accelerated Allyl Mechanism

(2021) Daniel Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An Amine-Assisted Ionic Monohydride Mechanism Enables Selective Alkyne cis-Semihydrogenation with Ethanol: From Elementary Steps to Catalysis

(2021) Zhidao Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Regio- and Stereoselective Hydroboration of Allenes

(2020) Can Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cobalt-Catalyzed Migrational Isomerization of Styrenes

(2020) Jiajin Zhao et al.   ORGANIC LETTERS

A Pd-Catalyzed Site-Controlled Isomerization of Terminal Olefins

(2020) Wenlong Ren et al.   ORGANIC LETTERS

Cobalt(II)-Catalyzed Stereoselective Olefin Isomerization: Facile Access to Acyclic Trisubstituted Alkenes

(2020) Sheng Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkene Isomerization through Allylmetals as a Strategic Tool in Stereoselective Synthesis

(2020) Itai Massad et al.   ACS Catalysis

Cobalt-Catalyzed E-Selective Isomerization of Alkenes with a Phosphine-Amido-Oxazoline Ligand

(2020) Hongmei Liu et al.   ACS Omega

Iron Catalyzed Isomerization of α‐Alkyl Styrenes to Access Trisubstituted Alkenes

(2020) Songgen Xu et al.   CHINESE JOURNAL OF CHEMISTRY

Chiral imidazoline ligands and their applications in metal‐catalyzed asymmmetric synthesis

(2020) Jiajing Li et al.   CHINESE JOURNAL OF CHEMISTRY

Iron-Catalyzed Tunable and Site-Selective Olefin Transposition

(2020) Xiaolong Yu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base-Metal-Catalyzed Olefin Isomerization Reactions

(2019) Qiang Liu et al.   SYNTHESIS-STUTTGART

E-Olefins through intramolecular radical relocation

(2019) Ajoy Kapat et al.   SCIENCE

Magnesium-Catalyzed Hydroboration of Terminal and Internal Alkynes

(2019) Marc Magre et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent advances in tridentate iron and cobalt complexes for alkene and alkyne hydrofunctionalizations

(2019) Huanan Wen et al.   COORDINATION CHEMISTRY REVIEWS

Isolation, Structure, and Total Synthesis of the Marine Macrolide Mangrolide D

(2019) Junyu Gong et al.   ORGANIC LETTERS

Positional and Geometrical Isomerisation of Alkenes: The Pinnacle of Atom Economy

(2019) John James Molloy et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Synthesis of 1,4-Keto-Alkenylboronate Esters and 1,4-Dicarbonyls

(2019) Simon John Meek et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dynamic π-Bonding of Imidazolyl Substituent in a Formally 16-Electron Cp*Ru(κ2-P,N)+ Catalyst Allows Dramatic Rate Increases in (E)-Selective Monoisomerization of Alkenes

(2019) Erik R. Paulson et al.   ACS Catalysis

Cobalt-Catalyzed Regiodivergent Stereoselective Hydroboration of 1,3-Diynes To Access Boryl-Functionalized Enynes

(2019) Hui Leng Sang et al.   ACS Catalysis

Total Synthesis and Biological Evaluation of the Glycosylated Macrocyclic Antibiotic Mangrolide A

(2018) Hiromu Hattori et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

First-Row Transition-Metal-Catalyzed Carbonylative Transformations of Carbon Electrophiles

(2018) Jin-Bao Peng et al.   CHEMICAL REVIEWS

Cobalt-Catalyzed Regioselective Olefin Isomerization Under Kinetic Control

(2018) Xufang Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereo- and Regiocontrolled Methylboration of Terminal Alkynes

(2018) Oleksandr Zhurakovskyi et al.   ORGANIC LETTERS

Selective Isomerization of Terminal Alkenes to (Z)-2-Alkenes Catalyzed by an Air-Stable Molybdenum(0) Complex

(2018) Joseph Becica et al.   ORGANOMETALLICS

Hydride Transfer Reactions Catalyzed by Cobalt Complexes

(2018) Wenying Ai et al.   CHEMICAL REVIEWS

Rhodium-Catalyzed Enantioconvergent Isomerization of Homoallylic and Bishomoallylic Secondary Alcohols

(2018) Rui-Zhi Huang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isomerization of N-Allyl Amides To Form Geometrically Defined Di-, Tri-, and Tetrasubstituted Enamides

(2017) Barry M. Trost et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Vinyl-, Allyl-, and 2-Boryl Allylboronates via a Highly Selective Copper-Catalyzed Borylation of Propargylic Alcohols

(2017) Lujia Mao et al.   ORGANIC LETTERS

Advances in Base-Metal-Catalyzed Alkene Hydrosilylation

(2017) Xiaoyong Du et al.   ACS Catalysis

Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

(2016) Steven W. M. Crossley et al.   CHEMICAL REVIEWS

Radical Isomerization and Cycloisomerization Initiated by H• Transfer

(2016) Gang Li et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isomerization of Allylbenzenes

(2015) Mohammad Hassam et al.   CHEMICAL REVIEWS

Iron Catalysis in Organic Synthesis

(2015) Ingmar Bauer et al.   CHEMICAL REVIEWS

Mechanistic Understanding of Transition-Metal-Catalyzed Olefin Isomerization: Metal-Hydride Insertion-Elimination vs. π-Allyl Pathways

(2015) Soumik Biswas   COMMENTS ON INORGANIC CHEMISTRY

Green and Efficient: Iron-Catalyzed Selective Oxidation of Olefins to Carbonyls with O2

(2015) Angela Gonzalez-de-Castro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Double-Bond Isomerization: Highly Reactive Nickel Catalyst Applied in the Synthesis of the Pheromone (9Z,12Z)-Tetradeca-9,12-dienyl Acetate

(2015) Felicia Weber et al.   ORGANIC LETTERS

Synthetic Studies toward the C32–C46 Segment of Hemicalide. Assignment of the Relative Configuration of the C36–C42 Subunit

(2015) Simon Specklin et al.   ORGANIC LETTERS

Synthesis of Vinyl Boronates from Aldehydes by a Practical Boron–Wittig Reaction

(2015) John R. Coombs et al.   ORGANIC LETTERS

Solvent-Assisted Electrospray Ionization for Direct Analysis of Various Compounds (Complex) from Low/Nonpolar Solvents and Eluents

(2014) Jun-Ting Zhang et al.   ANALYTICAL CHEMISTRY

Double Bond Isomerisation and Migration-New Playgrounds for Transition Metal-Catalysis

(2014) Gerhard Hilt   ChemCatChem

Well-defined transition metal hydrides in catalytic isomerizations

(2014) Evgeny Larionov et al.   CHEMICAL COMMUNICATIONS

Transition-metal-free C–C bond forming reactions of aryl, alkenyl and alkynylboronic acids and their derivatives

(2014) S. Roscales et al.   CHEMICAL SOCIETY REVIEWS

Stereoselective Formation of Trisubstituted Vinyl Boronate Esters by the Acid-Mediated Elimination of α-Hydroxyboronate Esters

(2014) Weiye Guan et al.   JOURNAL OF ORGANIC CHEMISTRY

Simple, Chemoselective, Catalytic Olefin Isomerization

(2014) Steven W. M. Crossley et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Z-Selective Alkene Isomerization by High-Spin Cobalt(II) Complexes

(2014) Chi Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

General Catalyst Control of the Monoisomerization of 1-Alkenes to trans-2-Alkenes

(2014) Casey R. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones

(2013) Fanke Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Atrans-Selective Hydroboration of Internal Alkynes

(2013) Basker Sundararaju et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane

(2013) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Highly Selective Copper-Catalyzed Hydroboration of Allenes and 1,3-Dienes

(2013) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Phosphinite-Iminopyridine Iron Catalysts for Chemoselective Alkene Hydrosilylation

(2013) Dongjie Peng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand Controlled Highly Selective Copper-Catalyzed Borylcuprations of Allenes with Bis(pinacolato)diboron

(2012) Weiming Yuan et al.   ADVANCED SYNTHESIS & CATALYSIS

Diastereodivergent Synthesis of Trisubstituted Alkenes through Protodeboronation of Allylic Boronic Esters: Application to the Synthesis of the Californian Red Scale Beetle Pheromone

(2012) Matthew J. Hesse et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Benign Catalysis with Iron: Unique Selectivity in Catalytic Isomerization Reactions of Olefins

(2012) Reiko Jennerjahn et al.   ChemSusChem

Olefin Isomerization by Iridium Pincer Catalysts. Experimental Evidence for an η3-Allyl Pathway and an Unconventional Mechanism Predicted by DFT Calculations

(2012) Soumik Biswas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regiocontrolled CuI-Catalyzed Borylation of Propargylic-Functionalized Internal Alkynes

(2012) Abraham L. Moure et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Alkene Isomerization over One Position

(2012) Casey R. Larsen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

CuCl–K2CO3-catalyzed highly selective borylcupration of internal alkynes – ligand effect

(2012) Weiming Yuan et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper(I)-Catalyzed Regioselective Monoborylation of 1,3-Enynes with an Internal Triple Bond: Selective Synthesis of 1,3-Dienylboronates and 3-Alkynylboronates

(2011) Yusuke Sasaki et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed Isomerizations of Olefins

(2011) Matthias Mayer et al.   ChemCatChem

Highly regio- and stereoselective synthesis of alkenylboronic esters by copper-catalyzed boron additions to disubstituted alkynes

(2011) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Boronic Acids and Esters in the Petasis-Borono Mannich Multicomponent Reaction

(2010) Nuno R. Candeias et al.   CHEMICAL REVIEWS

Copper-Promoted Coupling of Vinyl Boronates and Alcohols: A Mild Synthesis of Allyl Vinyl Ethers

(2010) Ryan E. Shade et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of cis-β-Methyl- and Phenyl-Substituted Alkenylboronates by Platinum-Catalyzed Dehydrogenative Borylation

(2009) Toshimichi Ohmura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Bis(imidazoline-2-thione)–copper(i) catalyzed regioselective boron addition to internal alkynes

(2009) Hye Ryung Kim et al.   CHEMICAL COMMUNICATIONS

Facile Pd(II)- and Ni(II)-Catalyzed Isomerization of Terminal Alkenes into 2-Alkenes

(2009) Hwan Jung Lim et al.   JOURNAL OF ORGANIC CHEMISTRY

Mild and Selective Deuteration and Isomerization of Alkenes by a Bifunctional Catalyst and Deuterium Oxide

(2009) Gülin Erdogan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Activated Alkenylboronates from Acetylenic Esters by CuH-Catalyzed 1,2-Addition/Transmetalation

(2008) Bruce H. Lipshutz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Double bond migration in N-allylic systems catalyzed by transition metal complexes

(2007) S KROMPIEC et al.   COORDINATION CHEMISTRY REVIEWS