Pyridine‐Based Organocatalysts for Regioselective syn ‐1,2‐Silaboration of Terminal Alkynes and Allenes

In Situ Generation of Silylzinc by Si−B Bond Activation Enabling Silylzincation and Silaboration of Terminal Alkynes

(2018) Yuki Nagashima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic reductive coupling of aldehydes with 1,1-diarylethylenes using an in situ generated pyridine-boryl radical

(2018) Jia Cao et al.   Chemical Science

Super electron donors derived from diboron

(2018) Li Zhang et al.   Chemical Science

Lewis Base Promoted Selective C-N Borylation of Alkyl Amines

(2018) Zhuangzhi Shi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Organocatalytic decarboxylative alkylation of N-hydroxy-phthalimide esters enabled by pyridine-boryl radicals

(2018) Liuzhou Gao et al.   CHEMICAL COMMUNICATIONS

Photoinduced Deaminative Borylation of Alkylamines

(2018) Jingjing Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

4-Cyanopyridine-catalyzed anti-Markovnikov selective hydroboration of alkenes

(2018) Rui Xu et al.   NEW JOURNAL OF CHEMISTRY

Metal-Free Synthesis of C-4 Substituted Pyridine Derivatives Using Pyridine-boryl Radicals via a Radical Addition/Coupling Mechanism: A Combined Computational and Experimental Study

(2017) Guoqiang Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

C–O Functionalization of α-Oxyboronates: A Deoxygenative gem-Diborylation and gem-Silylborylation of Aldehydes and Ketones

(2017) Lu Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Practical and Asymmetric Reductive Coupling of Isoquinolines Templated by Chiral Diborons

(2017) Dongping Chen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Transition-Metal-Free, Visible-Light-Enabled Decarboxylative Borylation of Aryl N-Hydroxyphthalimide Esters

(2017) Lisa Candish et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Isonicotinate Ester Catalyzed Decarboxylative Borylation of (Hetero)Aryl and Alkenyl Carboxylic Acids through N-Hydroxyphthalimide Esters

(2017) Wan-Min Cheng et al.   ORGANIC LETTERS

Tris(trimethylsilyl)silylboronate Esters: Novel Bulky, Air- and Moisture-Stable Silylboronate Ester Reagents for Boryl Substitution and Silaboration Reactions

(2017) Eiji Yamamoto et al.   ORGANOMETALLICS

Photoinduced decarboxylative borylation of carboxylic acids

(2017) Alexander Fawcett et al.   SCIENCE

Radical Metal-Free Borylation of Aryl Iodides

(2017) Sandra Pinet et al.   SYNTHESIS-STUTTGART

Transition-Metal-Free Borylation of Allylic and Propargylic Alcohols

(2016) Núria Miralles et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Homolytic Cleavage of a B−B Bond by the Cooperative Catalysis of Two Lewis Bases: Computational Design and Experimental Verification

(2016) Guoqiang Wang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pyridine-Catalyzed Radical Borylation of Aryl Halides

(2016) Li Zhang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Photoinduced metal-free diboration of alkynes in the presence of organophosphine catalysts

(2016) Aya Yoshimura et al.   TETRAHEDRON

Synthesis of 1,1-Diborylalkenes through a Brønsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron

(2015) Akira Morinaga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mixed diboration of alkenes in a metal-free context

(2015) Nuria Miralles et al.   CHEMICAL COMMUNICATIONS

sp2–sp3 diboranes: astounding structural variability and mild sources of nucleophilic boron for organic synthesis

(2015) Rian D. Dewhurst et al.   CHEMICAL COMMUNICATIONS

Organosulfide-Catalyzed Diboration of Terminal Alkynes under Light

(2015) Aya Yoshimura et al.   CHEMISTRY-A EUROPEAN JOURNAL

Organocatalytic Diboration Involving “Reductive Addition” of a Boron–Boron σ-Bond to 4,4′-Bipyridine

(2015) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis

(2015) Kazunori Nagao et al.   ORGANIC LETTERS

Hydroxyl-Directed Stereoselective Diboration of Alkenes

(2014) Thomas P. Blaisdell et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-free borylative ring-opening of vinyl epoxides and aziridines

(2013) Xavier Sanz et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Metal free catalytic hydroboration of multiple bonds in methanol using N-heterocyclic carbenes under open atmosphere

(2013) Kun Wen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Dearomatizing conversion of pyrazines to 1,4-dihydropyrazine derivatives via transition-metal-free diboration, silaboration, and hydroboration

(2012) Kazuyuki Oshima et al.   CHEMICAL COMMUNICATIONS

Potassium tert-butoxide-mediated regioselective silaboration of aromatic alkenes

(2012) Hajime Ito et al.   CHEMICAL COMMUNICATIONS

Asymmetric synthesis of α-amino boronate esters via organocatalytic pinacolboryl addition to tosylaldimines

(2012) Cristina Solé et al.   CHEMICAL COMMUNICATIONS

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Trivalent boron nucleophile as a new tool in organic synthesis: reactivity and asymmetric induction

(2012) Jessica Cid et al.   CHEMICAL SOCIETY REVIEWS

Metal-Free Catalytic Enantioselective C–B Bond Formation: (Pinacolato)boron Conjugate Additions to α,β-Unsaturated Ketones, Esters, Weinreb Amides, and Aldehydes Promoted by Chiral N-Heterocyclic Carbenes

(2012) Hao Wu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anomalous Reactivity of Silylborane: Transition-Metal-Free Boryl Substitution of Aryl, Alkenyl, and Alkyl Halides with Silylborane/Alkoxy Base Systems

(2012) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric organocatalytic diboration of alkenes

(2012) Amadeu Bonet et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Essential role of phosphines in organocatalytic β-boration reaction

(2012) Cristina Pubill-Ulldemolins et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transition-Metal-Free Diboration Reaction by Activation of Diboron Compounds with Simple Lewis Bases

(2011) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Activation of Diboron Reagents with Brønsted Bases and Alcohols: An Experimental and Theoretical Perspective of the Organocatalytic Boron Conjugate Addition Reaction

(2011) Cristina Pubill-Ulldemolins  et al.   CHEMISTRY-A EUROPEAN JOURNAL

Palladium-Catalyzed Regioselective Silaboration of Pyridines Leading to the Synthesis of Silylated Dihydropyridines

(2011) Kazuyuki Oshima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Catalytic C–Si Bond Formation in an Aqueous Medium. Enantioselective NHC-Catalyzed Silyl Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2011) Jeannette M. O’Brien et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Catalytic Boration at the β-Position of α,β-Unsaturated Compounds: A Challenging Asymmetric Induction

(2010) Amadeu Bonet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silylboranes as New Tools in Organic Synthesis

(2009) Toshimichi Ohmura et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Efficient C−B Bond Formation Promoted by N-Heterocyclic Carbenes: Synthesis of Tertiary and Quaternary B-Substituted Carbons through Metal-Free Catalytic Boron Conjugate Additions to Cyclic and Acyclic α,β-Unsaturated Carbonyls

(2009) Kang-sang Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY