Stereoselective Base-Catalyzed 1,1-Silaboration of Terminal Alkynes

Photoredox-Catalyzed Cyclobutane Synthesis by a Deboronative Radical Addition-Polar Cyclization Cascade

(2019) Chao Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

An Olefinic 1,2-Boryl-Migration Enabled by Radical Addition: Construction of gem -Bis(boryl)alkanes

(2019) Binlin Zhao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Pyridine‐Based Organocatalysts for Regioselective syn ‐1,2‐Silaboration of Terminal Alkynes and Allenes

(2019) Yohei Morimasa et al.   Asian Journal of Organic Chemistry

Vinylidene Homologation of Boronic Esters and its Application to the Synthesis of the Proposed Structure of Machillene

(2019) Varinder Kumar Aggarwal et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-Catalyzed Regio- and Stereoselective 1,1-Dicarbofunctionalization of Terminal Alkynes

(2019) Yunhe Lv et al.   ORGANIC LETTERS

Ligand-Dependent-Controlled Copper-Catalyzed Regio- and Stereoselective Silaboration of Alkynes

(2019) Meng Zhao et al.   ORGANIC LETTERS

Hydrogen Atom Transfer Induced Boron Retaining Coupling of Organoboronic Esters and Organolithium Reagents

(2019) Dinghai Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

In Situ Generation of Silylzinc by Si−B Bond Activation Enabling Silylzincation and Silaboration of Terminal Alkynes

(2018) Yuki Nagashima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of α-Chiral Ketones and Chiral Alkanes Using Radical Polar Crossover Reactions of Vinyl Boron Ate Complexes

(2018) Carolin Gerleve et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Access to 1,1-Diborylalkenes and Concomitant Stereoselective Reactivity

(2018) Jordi Royes et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Intermediacy of Ni–Ni Species in sp2 C–O Bond Cleavage of Aryl Esters: Relevance in Catalytic C–Si Bond Formation

(2018) Rosie J. Somerville et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereo- and Regiocontrolled Methylboration of Terminal Alkynes

(2018) Oleksandr Zhurakovskyi et al.   ORGANIC LETTERS

Palladium-Catalyzed Regio- and Stereoselective Coupling–Addition of Propiolates with Arylsulfonyl Hydrazides: A Pattern for Difunctionalization of Alkynes

(2018) Lixin Liu et al.   ORGANIC LETTERS

Copper-Catalyzed Double C(sp3)–Si Coupling of Geminal Dibromides: Ionic-to-Radical Switch in the Reaction Mechanism

(2018) Hamideh Hazrati et al.   ORGANIC LETTERS

Copper-Catalyzed Geminal Difunctionalization of Terminal Alkynes by Splitting Sulfonyl Hydrazones into Two Parts

(2018) Qi Sun et al.   ORGANIC LETTERS

Base-Mediated Defluorosilylation of C(sp2 )−F and C(sp3 )−F Bonds

(2018) Xiang-Wie Liu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Vinylidenation of Organoboronic Esters Enabled by a Pd-Catalyzed Metallate Shift

(2018) Mark D. Aparece et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Mild and Direct Site-Selective sp2 C–H Silylation of (Poly)Azines

(2018) Yiting Gu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis

(2018) Lei Guo et al.   Nature Communications

Quest for Novel Chemical Entities through Incorporation of Silicon in Drug Scaffolds

(2017) Remya Ramesh et al.   JOURNAL OF MEDICINAL CHEMISTRY

Ligand Binding Constants to Lithium Hexamethyldisilazide Determined by Diffusion-Ordered NMR Spectroscopy

(2017) Onkei Tai et al.   JOURNAL OF ORGANIC CHEMISTRY

Cobalt-Catalyzed 1,1-Diboration of Terminal Alkynes: Scope, Mechanism, and Synthetic Applications

(2017) Simon Krautwald et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Sodium Diisopropylamide: Aggregation, Solvation, and Stability

(2017) Russell F. Algera et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Alkali Metal-Hydroxide-Catalyzed C(sp)–H Bond silylation

(2017) Anton A. Toutov et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mild and Ligand-Free Ni-Catalyzed Silylation via C–OMe Cleavage

(2017) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-catalyzed synthesis of 1,1-diborylalkanes from terminal alkenes

(2017) Lei Li et al.   Nature Communications

Synthesis of Multisubstituted Olefins through Regio- and Stereoselective Addition of Interelement Compounds Having B-Si, B-B, and Cl-S Bonds to Alkynes, and Subsequent Cross-Couplings

(2016) Masayuki Iwasaki et al.   CHEMICAL RECORD

Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

(2016) Emily C. Neeve et al.   CHEMICAL REVIEWS

Alkenylation of Arenes and Heteroarenes with Alkynes

(2016) Vadim P. Boyarskiy et al.   CHEMICAL REVIEWS

Mn-, Fe-, and Co-Catalyzed Radical Hydrofunctionalizations of Olefins

(2016) Steven W. M. Crossley et al.   CHEMICAL REVIEWS

Opportunegem-Silylborylation of Carbonyl Compounds: A Modular and Stereocontrolled Entry to Tetrasubstituted Olefins

(2016) Enrico La Cascia et al.   CHEMISTRY-A EUROPEAN JOURNAL

Direct and Base-Catalyzed Diboration of Alkynes Using the Unsymmetrical Diborane(4), pinB-BMes2

(2016) Chiemi Kojima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Nickel-Catalyzed anti-Carbometallative Cyclizations of Alkynyl Electrophiles Enabled by Reversible Alkenylnickel E/Z Isomerization

(2016) Christopher Clarke et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Synthesis of 1,1-Diborylalkenes through a Brønsted Base Catalyzed Reaction between Terminal Alkynes and Bis(pinacolato)diboron

(2015) Akira Morinaga et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Boron-selective reactions as powerful tools for modular synthesis of diverse complex molecules

(2015) Liang Xu et al.   CHEMICAL SOCIETY REVIEWS

Organosulfide-Catalyzed Diboration of Terminal Alkynes under Light

(2015) Aya Yoshimura et al.   CHEMISTRY-A EUROPEAN JOURNAL

Iron-Catalyzed Diboration and Carboboration of Alkynes

(2015) Naohisa Nakagawa et al.   CHEMISTRY-A EUROPEAN JOURNAL

Catalytic stereoselective addition to alkynes. Borylation or silylation promoted by magnesia-supported iron oxide and cis-diboronation or silaboration by supported platinum nanoparticles

(2015) Anish Khan et al.   JOURNAL OF CATALYSIS

Ipso-Borylation of Aryl Ethers via Ni-Catalyzed C–OMe Cleavage

(2015) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Nickel-Catalyzed Three-Component Domino Reactions of Aryl Grignard Reagents, Alkynes, and Aryl Halides Producing Tetrasubstituted Alkenes

(2015) Fei Xue et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Anti-Selective Vicinal Silaboration and Diboration of Alkynoates through Phosphine Organocatalysis

(2015) Kazunori Nagao et al.   ORGANIC LETTERS

Catalytic conjunctive cross-coupling enabled by metal-induced metallate rearrangement

(2015) L. Zhang et al.   SCIENCE

Trans-Diborylation of Alkynes: Pseudo-Intramolecular Strategy Utilizing a Propargylic Alcohol Unit

(2014) Yuki Nagashima et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Mild Ni/Cu-Catalyzed Silylation via C–O Cleavage

(2014) Cayetana Zarate et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Assembly-line synthesis of organic molecules with tailored shapes

(2014) Matthew Burns et al.   NATURE

Recent advances in homogeneous nickel catalysis

(2014) Sarah Z. Tasker et al.   NATURE

Activation of the Si–B Interelement Bond: Mechanism, Catalysis, and Synthesis

(2012) Martin Oestreich et al.   CHEMICAL REVIEWS

Radical Cascades Initiated by Intermolecular Radical Addition to Alkynes and Related Triple Bond Systems

(2012) Uta Wille   CHEMICAL REVIEWS

Pd-Catalyzed β-Selective Direct C–H Bond Arylation of Thiophenes with Aryltrimethylsilanes

(2012) Kenji Funaki et al.   ORGANIC LETTERS

(E)- and (Z)-β-Borylallylsilanes by Alkyne Silaboration Followed by Regio- and Stereoselective Double-Bond Migration

(2011) Toshimichi Ohmura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Pyridine-N-oxide–Borane Intramolecular Complexes by Palladium-Catalyzed Reaction of 2-Bromopyridine-N-oxides with Alkynyltriarylborates

(2011) Naoki Ishida et al.   ORGANIC LETTERS

Switch of Regioselectivity in Palladium-Catalyzed Silaboration of Terminal Alkynes by Ligand-Dependent Control of Reductive Elimination

(2010) Toshimichi Ohmura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Stereoselective Synthesis of (E)-(Trisubstituted alkenyl)borinic Esters: Stereochemistry Reversed by Ligand in the Palladium-Catalyzed Reaction of Alkynylborates with Aryl Halides

(2009) Naoki Ishida et al.   ORGANIC LETTERS

Palladium-Catalyzed Suzuki−Miyaura Cross-Coupling Reactions Employing Dialkylbiaryl Phosphine Ligands

(2008) Ruben Martin et al.   ACCOUNTS OF CHEMICAL RESEARCH

Palladium-catalysed cis- and trans-silaboration of terminal alkynes: complementary access to stereo-defined trisubstituted alkenes

(2008) Toshimichi Ohmura et al.   CHEMICAL COMMUNICATIONS

Iridium-Catalyzed Preparation of Silylboranes by Silane Borylation and Their Use in the Catalytic Borylation of Arenes

(2008) Timothy A. Boebel et al.   ORGANOMETALLICS

Polyborylated reagents for modern organic synthesis

(2008) Masaki SHIMIZU et al.   PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES

Tamoxifen: Catalyst for the change to targeted therapy

(2007) V. Craig Jordan   EUROPEAN JOURNAL OF CANCER