Copper-Catalyzed Enantioselective Allylboration of Alkynes: Synthesis of Highly Versatile Multifunctional Building Blocks

Synthesis of Stereodefined Borylated Dendralenes through Copper-Catalyzed Allylboration of Alkynes

(2018) Eva Rivera-Chao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper(I)-Catalyzed Enantio- and Diastereodivergent Borylative Coupling of Styrenes and Imines

(2018) Taisuke Itoh et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Efficient and stereodivergent synthesis of unsaturated acyclic fragments bearing contiguous stereogenic elements

(2018) Jeffrey Bruffaerts et al.   Nature Chemistry

Alkenylboronates: synthesis and applications

(2018) Pedro J. Pérez et al.   Chemistry-An Asian Journal

Mechanism-based enhancement of scope and enantioselectivity for reactions involving a copper-substituted stereogenic carbon centre

(2017) Jaehee Lee et al.   Nature Chemistry

Synthetic applications of vinyl cyclopropane opening

(2017) Marta Meazza et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Copper-Catalyzed Asymmetric Borylallylation of Vinyl Arenes

(2017) Namhyeon Kim et al.   ORGANIC LETTERS

Practical, efficient, and broadly applicable synthesis of readily differentiable vicinal diboronate compounds by catalytic three-component reactions

(2017) Suttipol Radomkit et al.   TETRAHEDRON

Asymmetric Suzuki-Miyaura coupling of heterocycles via Rhodium-catalysed allylic arylation of racemates

(2017) Philipp Schäfer et al.   Nature Communications

Synergistic Copper/Palladium Catalysis for the Regio- and Stereoselective Synthesis of Borylated Skipped Dienes

(2017) Jaime Mateos et al.   ACS Catalysis

Enantioselective Generation of Adjacent Stereocenters in a Copper-Catalyzed Three-Component Coupling of Imines, Allenes, and Diboranes

(2016) Kay Yeung et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic Enantioselective Arylboration of Alkenylarenes

(2016) Kaitlyn M. Logan et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Versatile Homoallylic Boronates by Chemo-, SN2′-, Diastereo- and Enantioselective Catalytic Sequence of Cu−H Addition to Vinyl-B(pin)/Allylic Substitution

(2016) Jaehee Lee et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

(2016) Emily C. Neeve et al.   CHEMICAL REVIEWS

The “Cyclopropyl Fragment” is a Versatile Player that Frequently Appears in Preclinical/Clinical Drug Molecules

(2016) Tanaji T. Talele   JOURNAL OF MEDICINAL CHEMISTRY

Catalytic enantioselective 1,6-conjugate additions of propargyl and allyl groups

(2016) Fanke Meng et al.   NATURE

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Stereocontrolled Formation of Several Carbon–Carbon Bonds in Acyclic Systems

(2015) Guillaume Eppe et al.   CHEMICAL REVIEWS

Catalytic C–C Bond Activations via Oxidative Addition to Transition Metals

(2015) Laetitia Souillart et al.   CHEMICAL REVIEWS

A Cu/Pd Cooperative Catalysis for Enantioselective Allylboration of Alkenes

(2015) Tao Jia et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

N-Heterocyclic Carbene–Copper-Catalyzed Group-, Site-, and Enantioselective Allylic Substitution with a Readily Accessible Propargyl(pinacolato)boron Reagent: Utility in Stereoselective Synthesis and Mechanistic Attributes

(2015) Ying Shi et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-catalyzed borylative transformations of non-polar carbon–carbon unsaturated compounds employing borylcopper as an active catalyst species

(2015) Kazuhiko Semba et al.   TETRAHEDRON

Substrate-Controlled Regio- and Stereoselective Synthesis of Boron-Substituted 1,4-Dienes via Copper-Catalyzed Boryl–Allylation of Alkynes with Allyl Phosphates and Bis(pinacolato)diboron

(2015) Huai-Yu Bin et al.   ACS Catalysis

A Broadly Applicable NHC–Cu-Catalyzed Approach for Efficient, Site-, and Enantioselective Coupling of Readily Accessible (Pinacolato)alkenylboron Compounds to Allylic Phosphates and Applications to Natural Product Synthesis

(2014) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper(I)-Catalyzed Enantioselective Synthesis of α-Chiral Linear or Carbocyclic (E)-(γ-Alkoxyallyl)boronates

(2014) Eiji Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Allylic Alkylation of Terminal Alkyne Pronucleophiles

(2014) Ayumi Harada et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Multifunctional organoboron compounds for scalable natural product synthesis

(2014) Fanke Meng et al.   NATURE

Asymmetric Cyclopropanation Reactions

(2014) Renato Dalpozzo et al.   SYNTHESIS-STUTTGART

Cu-Catalyzed Chemoselective Preparation of 2-(Pinacolato)boron-Substituted Allylcopper Complexes and their In Situ Site-, Diastereo-, and Enantioselective Additions to Aldehydes and Ketones

(2013) Fanke Meng et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A novel catalytic asymmetric route towards skipped dienes with a methyl-substituted central stereogenic carbon

(2013) Yange Huang et al.   CHEMICAL COMMUNICATIONS

Cu-Catalyzed Asymmetric Borylative Cyclization of Cyclohexadienone-Containing 1,6-Enynes

(2013) Ping Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Enantioselective Allylic Substitution with Readily Accessible Carbonyl- and Acetal-Containing Vinylboron Reagents

(2012) Fang Gao et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent developments in asymmetric multicomponent reactions

(2012) Corien de Graaff et al.   CHEMICAL SOCIETY REVIEWS

Iridium-Catalyzed Enantioselective Allylic Vinylation

(2012) James Y. Hamilton et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Aryl- and Alkenylboronates

(2011) Ryo Shintani et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanisms of Nucleophilic Organocopper(I) Reactions

(2011) Naohiko Yoshikai et al.   CHEMICAL REVIEWS

Structure and Biosynthesis of the Marine Streptomycete Ansamycin Ansalactam A and Its Distinctive Branched Chain Polyketide Extender Unit

(2011) Micheal C. Wilson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Selective Methods for Synthesis of Internal (α-) Vinylboronates through Efficient NHC–Cu-Catalyzed Hydroboration of Terminal Alkynes. Utility in Chemical Synthesis and Mechanistic Basis for Selectivity

(2011) Hwanjong Jang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Enantioselective Synthesis of Allylboronates Bearing a Tertiary or Quaternary B-Substituted Stereogenic Carbon by NHC-Cu-Catalyzed Substitution Reactions

(2010) Aikomari Guzman-Martinez et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Quaternary Carbon Stereogenic Centers through Enantioselective Cu-Catalyzed Allylic Substitutions with Vinylaluminum Reagents

(2010) Fang Gao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct enantio-convergent transformation of racemic substrates without racemization or symmetrization

(2010) Hajime Ito et al.   Nature Chemistry

Diversity-oriented synthesis as a tool for the discovery of novel biologically active small molecules

(2010) Warren R.J.D. Galloway et al.   Nature Communications

Stereoisomerically Pure Trisubstituted Vinylaluminum Reagents and their Utility in Copper-Catalyzed Enantioselective Synthesis of 1,4-Dienes Containing Z or E Alkenes

(2009) Katsuhiro Akiyama et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High Diversity on Simple Substrates: 1,4-Dihalo-2-butenes and Other Difunctionalized Allylic Halides for Copper-Catalyzed SN2′ Reactions

(2008) Caroline A. Falciola et al.   CHEMISTRY-A EUROPEAN JOURNAL

Highly Site- and Enantioselective Cu-Catalyzed Allylic Alkylation Reactions with Easily Accessible Vinylaluminum Reagents

(2007) Yunmi Lee et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY