Tropylium-Promoted Hydroboration Reactions: Mechanistic Insights Via Experimental and Computational Studies

Tropylium-Catalyzed O–H Insertion Reactions of Diazoalkanes with Carboxylic Acids

(2021) Claire Empel et al.   ORGANIC LETTERS

Tropylium-promoted prenylation reactions of phenols in continuous flow

(2020) Klaus Omoregbee et al.   Journal of Flow Chemistry

Characterization of the Zwitterionic Intermediate in 1,1‐Carboboration of Alkynes

(2020) Alessandro Bismuto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aluminum-Catalyzed Selective Hydroboration of Nitriles and Alkynes: A Multifunctional Catalyst

(2020) Nabin Sarkar et al.   JOURNAL OF ORGANIC CHEMISTRY

Hidden Boron Catalysis: Nucleophile-Promoted Decomposition of HBpin

(2020) Andrew D. Bage et al.   ORGANIC LETTERS

Regiodivergent Hydroborative Ring Opening of Epoxides via Selective C–O Bond Activation

(2020) Marc Magre et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Reaction Pathways and Redox States in α‐Selective Cobalt‐Catalyzed Hydroborations of Alkynes

(2020) Clemens K. Blasius et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Tropolonate Salts as Acyl-Transfer Catalysts under Thermal and Photochemical Conditions: Reaction Scope and Mechanistic Insights

(2020) Demelza J. M. Lyons et al.   ACS Catalysis

Reactive nitrogen species: Nitrosonium ions in organic synthesis

(2019) Luis Bering et al.   TETRAHEDRON

Earth-Abundant Metal Catalysis Enabled by Counterion Activation

(2019) Riaz Agahi et al.   ORGANIC LETTERS

Magnesium-Catalyzed Hydroboration of Terminal and Internal Alkynes

(2019) Marc Magre et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Silver-Catalyzed anti-Markovnikov Hydroboration of C–C Multiple Bonds

(2019) Yan Wang et al.   ORGANIC LETTERS

trans ‐Hydroboration of Propargyl Alcohol Derivatives and Related Substrates

(2019) Lauren E. Longobardi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Zinc Catalysed Hydroboration of Terminal and Internal Alkynes

(2019) Souvik Mandal et al.   Chemistry-An Asian Journal

Ruthenium-Catalyzed (Z)-Selective Hydroboration of Terminal Alkynes with Naphthalene-1,8-diaminatoborane

(2019) Kensuke Yamamoto et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Cyclization/Hydroboration of 1,6-Diynes with Pinacolborane

(2019) Qiang Huang et al.   ORGANIC LETTERS

Kinetics and Mechanism of the Arase-Hoshi R2BH-Catalyzed Alkyne Hydroboration: Alkenylboronate Generation via B–H/C–B Metathesis

(2019) Eduardo Nieto-Sepulveda et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cobalt-Catalyzed Regiodivergent Stereoselective Hydroboration of 1,3-Diynes To Access Boryl-Functionalized Enynes

(2019) Hui Leng Sang et al.   ACS Catalysis

Halide Anion Triggered Reactions of Michael Acceptors with Tropylium Ion

(2019) Mohanad A. Hussein et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Stimuli-Responsive Organic Dyes with Tropylium Chromophore

(2018) Demelza Josephine Marion Lyons et al.   CHEMISTRY-A EUROPEAN JOURNAL

Tropylium Ion Catalyzes Hydration Reactions of Alkynes

(2018) Giulia Oss et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Tropylium-Promoted Oxidative Functionalization of Tetrahydroisoquinolines

(2018) Giulia Oss et al.   JOURNAL OF ORGANIC CHEMISTRY

Tropylium-promoted carbonyl–olefin metathesis reactions

(2018) Uyen P. N. Tran et al.   Chemical Science

Aluminum-Catalyzed Hydroboration of Alkenes

(2018) Alessandro Bismuto et al.   ACS Catalysis

Efficient Heterogeneous Hydroboration of Alkynes: Enhancing the Catalytic Activity by Cu(0) Incorporated CuFe2O4 Nanoparticles

(2018) Xianghua Zeng et al.   NEW JOURNAL OF CHEMISTRY

Visible-Light-Mediated Aerobic Oxidation of Organoboron Compounds Using in Situ Generated Hydrogen Peroxide

(2018) Wei-Zhi Weng et al.   ORGANIC LETTERS

Alkenylboronates: synthesis and applications

(2018) Pedro J. Pérez et al.   Chemistry-An Asian Journal

Hydroboration of substituted alkynes using a solid polymeric carboxylic acid catalyst

(2018) Caroline B. Hoyt et al.   JOURNAL OF CATALYSIS

Base-free nickel-catalyzed hydroboration of simple alkenes with bis(pinacolato)diboron in an alcoholic solvent

(2017) Jiang-Fei Li et al.   GREEN CHEMISTRY

Catalytic hydroboration of aldehydes, ketones, alkynes and alkenes initiated by NaOH

(2017) Yile Wu et al.   GREEN CHEMISTRY

Tropylium salts as efficient organic Lewis acid catalysts for acetalization and transacetalization reactions in batch and flow

(2017) D. J. M. Lyons et al.   GREEN CHEMISTRY

Tris(pentafluorophenyl)borane and Beyond: Modern Advances in Borylation Chemistry

(2017) James R. Lawson et al.   INORGANIC CHEMISTRY

Stable, Yet Highly Reactive Nonclassical Iron(II) Polyhydride Pincer Complexes: Z-Selective Dimerization and Hydroboration of Terminal Alkynes

(2017) Nikolaus Gorgas et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Conjunctive Cross-Coupling between Grignard-Derived Boron “Ate” Complexes and C(sp2) Halides or Triflates: NaOTf as a Grignard Activator and Halide Scavenger

(2017) Gabriel J. Lovinger et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydroboration of Alkynes Catalyzed by Pyrrolide-Based PNP Pincer–Iron Complexes

(2017) Kazunari Nakajima et al.   ORGANIC LETTERS

Borane-Catalysed Hydroboration of Alkynes and Alkenes

(2017) Stephen Thomas et al.   SYNTHESIS-STUTTGART

Stereoselective Synthesis of Trisubstituted Alkenes via Cobalt-Catalyzed Double Dehydrogenative Borylations of 1-Alkenes

(2017) Huanan Wen et al.   ACS Catalysis

Aluminum Hydride Catalyzed Hydroboration of Alkynes

(2016) Alessandro Bismuto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Promotion of Organic Reactions by Non-Benzenoid Carbocyclic Aromatic Ions

(2016) Demelza J. M. Lyons et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Lewis acid catalysis: catalytic hydroboration of alkynes initiated by Piers' borane

(2016) Mirco Fleige et al.   CHEMICAL COMMUNICATIONS

Alkaline earths as main group reagents in molecular catalysis

(2016) Michael S. Hill et al.   CHEMICAL SOCIETY REVIEWS

Boron Lewis Acid-Catalyzed Hydroboration of Alkenes with Pinacolborane: BArF 3 Does What B(C6 F5 )3 Cannot Do!

(2016) Qin Yin et al.   CHEMISTRY-A EUROPEAN JOURNAL

An Aluminum Dihydride Working as a Catalyst in Hydroboration and Dehydrocoupling

(2016) Zhi Yang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed trans-Hydroboration of Terminal Aryl Alkynes: Stereodivergent Synthesis of Alkenylboron Compounds

(2016) Won Jun Jang et al.   ORGANIC LETTERS

Highly selective catalytic trans-hydroboration of alkynes mediated by borenium cations and B(C6F5)3

(2016) John S. McGough et al.   Chemical Science

Borylation of Alkynes under Base/Coinage Metal Catalysis: Some Recent Developments

(2016) Hiroto Yoshida   ACS Catalysis

Rhodium-Catalyzed Dehydrogenative Borylation of Aliphatic Terminal Alkenes with Pinacolborane

(2015) Masao Morimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unique Chemoselective Hydrogenation using a Palladium Catalyst Immobilized on Ceramic

(2015) Yasunari Monguchi et al.   ChemCatChem

A novel aromatic carbocation-based coupling reagent for esterification and amidation reactions

(2015) Thanh V. Nguyen et al.   CHEMICAL COMMUNICATIONS

A General, Practical Triethylborane-Catalyzed Reduction of Carbonyl Functions to Alcohols

(2015) Dongjie Peng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Main group catalysed reduction of unsaturated bonds

(2015) K. Revunova et al.   DALTON TRANSACTIONS

Cobalt Catalyzed Z-Selective Hydroboration of Terminal Alkynes and Elucidation of the Origin of Selectivity

(2015) Jennifer V. Obligacion et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pinacolatoboron fluoride (pinBF) is an efficient fluoride transfer agent for diastereoselective synthesis of benzylic fluorides

(2015) Alexander J. Cresswell et al.   TETRAHEDRON LETTERS

Catalytic Hydroboration of Carbonyl Derivatives, Imines, and Carbon Dioxide

(2015) Che Chang Chong et al.   ACS Catalysis

Metal-Free σ-Bond Metathesis in 1,3,2-Diazaphospholene-Catalyzed Hydroboration of Carbonyl Compounds

(2014) Che Chang Chong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Cobalt-Catalyzed Alkene Hydroboration with Pinacolborane

(2014) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Carboxylic Acid-Catalyzed Highly Efficient and Selective Hydroboration of Alkynes with Pinacolborane

(2014) Hon Eong Ho et al.   ORGANIC LETTERS

Aromatic Cation Activation: Nucleophilic Substitution of Alcohols and Carboxylic Acids

(2014) Thanh V. Nguyen et al.   ORGANIC LETTERS

Iron-Catalyzed Borylation Reactions of Alkynes: An Efficient Synthesis of E-Vinyl Boronates

(2014) Bojja Sreedhar et al.   SYNLETT

Activation of DMSO for Swern-type oxidation by 1,1-dichlorocycloheptatriene

(2014) Thanh Vinh Nguyen et al.   TETRAHEDRON LETTERS

Haloboration of Internal Alkynes with Boronium and Borenium Cations as a Route to Tetrasubstituted Alkenes

(2013) James R. Lawson et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Iron-Catalyzed, Atom-Economical, Chemo- and Regioselective Alkene Hydroboration with Pinacolborane

(2013) Lei Zhang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Ligand-free hydroboration of alkynes catalyzed by heterogeneous copper powder with high efficiency

(2013) Jie Zhao et al.   CHEMICAL COMMUNICATIONS

Highly Selective Bis(imino)pyridine Iron-Catalyzed Alkene Hydroboration

(2013) Jennifer V. Obligacion et al.   ORGANIC LETTERS

Towards a Comprehensive Hydride Donor Ability Scale

(2012) Markus Horn et al.   CHEMISTRY-A EUROPEAN JOURNAL

Copper-Catalyzed Highly Regio- and Stereoselective Directed Hydroboration of Unsymmetrical Internal Alkynes: Controlling Regioselectivity by Choice of Catalytic Species

(2012) Kazuhiko Semba et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of Tertiary Alkyl Amines from Terminal Alkenes: Copper-Catalyzed Amination of Alkyl Boranes

(2012) Richard P. Rucker et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Borenium Ion Catalyzed Hydroboration of Alkenes with N-Heterocyclic Carbene-Boranes

(2012) Aleksandrs Prokofjevs et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ruthenium Catalyzed Hydroboration of Terminal Alkynes to Z-Vinylboronates

(2012) Chidambaram Gunanathan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydride as a Leaving Group in the Reaction of Pinacolborane with Halides under Ambient Grignard and Barbier Conditions. One-Pot Synthesis of Alkyl, Aryl, Heteroaryl, Vinyl, and Allyl Pinacolboronic Esters

(2011) Jacob W. Clary et al.   JOURNAL OF ORGANIC CHEMISTRY

Tropylium Ion Mediated α-Cyanation of Amines

(2011) Julia M. Allen et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Selective CH Borylation of Alkenes by Palladium Pincer Complex Catalyzed Oxidative Functionalization

(2010) Nicklas Selander et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Dramatic Effect of Lewis Acids on the Rhodium-Catalyzed Hydroboration of Olefins

(2009) Christopher J. Lata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

B–H Activation by frustrated Lewis pairs: borenium or boryl phosphonium cation?

(2008) Meghan A. Dureen et al.   CHEMICAL COMMUNICATIONS